Mo remarkably enhances catalytic activity of CuMoCo core-shell nanoparticles for hydrolytic dehydrogenation of ammonia borane
Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo i...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Wang, Cong [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2018transfer abstract |
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| Umfang: |
9 |
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| Übergeordnetes Werk: |
Enthalten in: External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs - Dedhia, Kavita ELSEVIER, 2018, official journal of the International Association for Hydrogen Energy, New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:43 ; year:2018 ; number:15 ; day:12 ; month:04 ; pages:7347-7355 ; extent:9 |
| Links: |
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| DOI / URN: |
10.1016/j.ijhydene.2018.02.172 |
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| 520 | |a Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. | ||
| 520 | |a Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. | ||
| 650 | 7 | |a Ammonia borane |2 Elsevier | |
| 650 | 7 | |a Hydrogen generation |2 Elsevier | |
| 650 | 7 | |a Core-shell |2 Elsevier | |
| 650 | 7 | |a Catalyst |2 Elsevier | |
| 650 | 7 | |a Cu@MoCo |2 Elsevier | |
| 700 | 1 | |a Wang, Hongli |4 oth | |
| 700 | 1 | |a Wang, Zhili |4 oth | |
| 700 | 1 | |a Li, Xiaoju |4 oth | |
| 700 | 1 | |a Chi, Yue |4 oth | |
| 700 | 1 | |a Wang, Minggang |4 oth | |
| 700 | 1 | |a Gao, Dawei |4 oth | |
| 700 | 1 | |a Zhao, Zhankui |4 oth | |
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10.1016/j.ijhydene.2018.02.172 doi GBV00000000000579.pica (DE-627)ELV042543010 (ELSEVIER)S0360-3199(18)30675-X DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Wang, Cong verfasserin aut Mo remarkably enhances catalytic activity of CuMoCo core-shell nanoparticles for hydrolytic dehydrogenation of ammonia borane 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. Ammonia borane Elsevier Hydrogen generation Elsevier Core-shell Elsevier Catalyst Elsevier Cu@MoCo Elsevier Wang, Hongli oth Wang, Zhili oth Li, Xiaoju oth Chi, Yue oth Wang, Minggang oth Gao, Dawei oth Zhao, Zhankui oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:43 year:2018 number:15 day:12 month:04 pages:7347-7355 extent:9 https://doi.org/10.1016/j.ijhydene.2018.02.172 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 43 2018 15 12 0412 7347-7355 9 |
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10.1016/j.ijhydene.2018.02.172 doi GBV00000000000579.pica (DE-627)ELV042543010 (ELSEVIER)S0360-3199(18)30675-X DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Wang, Cong verfasserin aut Mo remarkably enhances catalytic activity of CuMoCo core-shell nanoparticles for hydrolytic dehydrogenation of ammonia borane 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. Ammonia borane Elsevier Hydrogen generation Elsevier Core-shell Elsevier Catalyst Elsevier Cu@MoCo Elsevier Wang, Hongli oth Wang, Zhili oth Li, Xiaoju oth Chi, Yue oth Wang, Minggang oth Gao, Dawei oth Zhao, Zhankui oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:43 year:2018 number:15 day:12 month:04 pages:7347-7355 extent:9 https://doi.org/10.1016/j.ijhydene.2018.02.172 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 43 2018 15 12 0412 7347-7355 9 |
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10.1016/j.ijhydene.2018.02.172 doi GBV00000000000579.pica (DE-627)ELV042543010 (ELSEVIER)S0360-3199(18)30675-X DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Wang, Cong verfasserin aut Mo remarkably enhances catalytic activity of CuMoCo core-shell nanoparticles for hydrolytic dehydrogenation of ammonia borane 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. Ammonia borane Elsevier Hydrogen generation Elsevier Core-shell Elsevier Catalyst Elsevier Cu@MoCo Elsevier Wang, Hongli oth Wang, Zhili oth Li, Xiaoju oth Chi, Yue oth Wang, Minggang oth Gao, Dawei oth Zhao, Zhankui oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:43 year:2018 number:15 day:12 month:04 pages:7347-7355 extent:9 https://doi.org/10.1016/j.ijhydene.2018.02.172 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 43 2018 15 12 0412 7347-7355 9 |
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10.1016/j.ijhydene.2018.02.172 doi GBV00000000000579.pica (DE-627)ELV042543010 (ELSEVIER)S0360-3199(18)30675-X DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Wang, Cong verfasserin aut Mo remarkably enhances catalytic activity of CuMoCo core-shell nanoparticles for hydrolytic dehydrogenation of ammonia borane 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. Ammonia borane Elsevier Hydrogen generation Elsevier Core-shell Elsevier Catalyst Elsevier Cu@MoCo Elsevier Wang, Hongli oth Wang, Zhili oth Li, Xiaoju oth Chi, Yue oth Wang, Minggang oth Gao, Dawei oth Zhao, Zhankui oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:43 year:2018 number:15 day:12 month:04 pages:7347-7355 extent:9 https://doi.org/10.1016/j.ijhydene.2018.02.172 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 43 2018 15 12 0412 7347-7355 9 |
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10.1016/j.ijhydene.2018.02.172 doi GBV00000000000579.pica (DE-627)ELV042543010 (ELSEVIER)S0360-3199(18)30675-X DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Wang, Cong verfasserin aut Mo remarkably enhances catalytic activity of CuMoCo core-shell nanoparticles for hydrolytic dehydrogenation of ammonia borane 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. Ammonia borane Elsevier Hydrogen generation Elsevier Core-shell Elsevier Catalyst Elsevier Cu@MoCo Elsevier Wang, Hongli oth Wang, Zhili oth Li, Xiaoju oth Chi, Yue oth Wang, Minggang oth Gao, Dawei oth Zhao, Zhankui oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:43 year:2018 number:15 day:12 month:04 pages:7347-7355 extent:9 https://doi.org/10.1016/j.ijhydene.2018.02.172 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 43 2018 15 12 0412 7347-7355 9 |
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Enthalten in External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs New York, NY [u.a.] volume:43 year:2018 number:15 day:12 month:04 pages:7347-7355 extent:9 |
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Enthalten in External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs New York, NY [u.a.] volume:43 year:2018 number:15 day:12 month:04 pages:7347-7355 extent:9 |
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Mo remarkably enhances catalytic activity of CuMoCo core-shell nanoparticles for hydrolytic dehydrogenation of ammonia borane |
| abstract |
Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. |
| abstractGer |
Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. |
| abstract_unstemmed |
Ammonia borane (AB) has been identified as one of the most promising candidates for chemical hydrogen storage. However, the practical application of AB for hydrogen production is hindered by the need of efficient and inexpensive catalysts. For the first time, we report that the incorporation of Mo into CuCo core-shell structure can significantly improve the catalytic efficiency of hydrogen generation from the hydrolysis of AB. The Cu0.81@Mo0.09Co0.10 core-shell catalyst displays high catalytic activity towards the hydrolysis dehydrogenation of AB with a turnover frequency (TOF) value of 49.6 molH2 molcat −1 min−1, which is higher than most of Cu-based catalysts ever reported, and even comparable to those of noble-metal based catalysts. The excellent catalytic performance is attributed to the multi-elements co-deposition effect and electrons transfer effect of Cu, Mo and Co in the tri-metallic core-shell NPs. |
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Mo remarkably enhances catalytic activity of CuMoCo core-shell nanoparticles for hydrolytic dehydrogenation of ammonia borane |
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Wang, Hongli Wang, Zhili Li, Xiaoju Chi, Yue Wang, Minggang Gao, Dawei Zhao, Zhankui |
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