Structural and physical characterization of NpPt<ce:inf loc="post">2</ce:inf>In<ce:inf loc="post">7</ce:inf>
A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice pa...
Ausführliche Beschreibung
Autor*in: |
Klimczuk, T. [verfasserIn] |
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Englisch |
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2018transfer abstract |
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Enthalten in: Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners - Jacobs, Jacquelyn A. ELSEVIER, 2017, JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics, Lausanne |
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Übergeordnetes Werk: |
volume:768 ; year:2018 ; day:5 ; month:11 ; pages:852-858 ; extent:7 |
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DOI / URN: |
10.1016/j.jallcom.2018.07.163 |
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ELV044284888 |
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520 | |a A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. | ||
520 | |a A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. | ||
700 | 1 | |a Shick, A.B. |4 oth | |
700 | 1 | |a Khmelevskyi, S. |4 oth | |
700 | 1 | |a Kozub, A.L. |4 oth | |
700 | 1 | |a Kolincio, K.K. |4 oth | |
700 | 1 | |a Griveau, J.-C. |4 oth | |
700 | 1 | |a Colineau, E. |4 oth | |
700 | 1 | |a Eloirdi, R. |4 oth | |
700 | 1 | |a Caciuffo, R. |4 oth | |
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10.1016/j.jallcom.2018.07.163 doi GBV00000000000672.pica (DE-627)ELV044284888 (ELSEVIER)S0925-8388(18)32664-1 DE-627 ger DE-627 rakwb eng 630 VZ Klimczuk, T. verfasserin aut Structural and physical characterization of NpPt<ce:inf loc="post">2</ce:inf>In<ce:inf loc="post">7</ce:inf> 2018transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. Shick, A.B. oth Khmelevskyi, S. oth Kozub, A.L. oth Kolincio, K.K. oth Griveau, J.-C. oth Colineau, E. oth Eloirdi, R. oth Caciuffo, R. oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:768 year:2018 day:5 month:11 pages:852-858 extent:7 https://doi.org/10.1016/j.jallcom.2018.07.163 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 768 2018 5 1105 852-858 7 |
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10.1016/j.jallcom.2018.07.163 doi GBV00000000000672.pica (DE-627)ELV044284888 (ELSEVIER)S0925-8388(18)32664-1 DE-627 ger DE-627 rakwb eng 630 VZ Klimczuk, T. verfasserin aut Structural and physical characterization of NpPt<ce:inf loc="post">2</ce:inf>In<ce:inf loc="post">7</ce:inf> 2018transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. Shick, A.B. oth Khmelevskyi, S. oth Kozub, A.L. oth Kolincio, K.K. oth Griveau, J.-C. oth Colineau, E. oth Eloirdi, R. oth Caciuffo, R. oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:768 year:2018 day:5 month:11 pages:852-858 extent:7 https://doi.org/10.1016/j.jallcom.2018.07.163 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 768 2018 5 1105 852-858 7 |
allfields_unstemmed |
10.1016/j.jallcom.2018.07.163 doi GBV00000000000672.pica (DE-627)ELV044284888 (ELSEVIER)S0925-8388(18)32664-1 DE-627 ger DE-627 rakwb eng 630 VZ Klimczuk, T. verfasserin aut Structural and physical characterization of NpPt<ce:inf loc="post">2</ce:inf>In<ce:inf loc="post">7</ce:inf> 2018transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. Shick, A.B. oth Khmelevskyi, S. oth Kozub, A.L. oth Kolincio, K.K. oth Griveau, J.-C. oth Colineau, E. oth Eloirdi, R. oth Caciuffo, R. oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:768 year:2018 day:5 month:11 pages:852-858 extent:7 https://doi.org/10.1016/j.jallcom.2018.07.163 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 768 2018 5 1105 852-858 7 |
allfieldsGer |
10.1016/j.jallcom.2018.07.163 doi GBV00000000000672.pica (DE-627)ELV044284888 (ELSEVIER)S0925-8388(18)32664-1 DE-627 ger DE-627 rakwb eng 630 VZ Klimczuk, T. verfasserin aut Structural and physical characterization of NpPt<ce:inf loc="post">2</ce:inf>In<ce:inf loc="post">7</ce:inf> 2018transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. Shick, A.B. oth Khmelevskyi, S. oth Kozub, A.L. oth Kolincio, K.K. oth Griveau, J.-C. oth Colineau, E. oth Eloirdi, R. oth Caciuffo, R. oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:768 year:2018 day:5 month:11 pages:852-858 extent:7 https://doi.org/10.1016/j.jallcom.2018.07.163 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 768 2018 5 1105 852-858 7 |
allfieldsSound |
10.1016/j.jallcom.2018.07.163 doi GBV00000000000672.pica (DE-627)ELV044284888 (ELSEVIER)S0925-8388(18)32664-1 DE-627 ger DE-627 rakwb eng 630 VZ Klimczuk, T. verfasserin aut Structural and physical characterization of NpPt<ce:inf loc="post">2</ce:inf>In<ce:inf loc="post">7</ce:inf> 2018transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. Shick, A.B. oth Khmelevskyi, S. oth Kozub, A.L. oth Kolincio, K.K. oth Griveau, J.-C. oth Colineau, E. oth Eloirdi, R. oth Caciuffo, R. oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:768 year:2018 day:5 month:11 pages:852-858 extent:7 https://doi.org/10.1016/j.jallcom.2018.07.163 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 768 2018 5 1105 852-858 7 |
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A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. 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A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. |
abstractGer |
A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. |
abstract_unstemmed |
A new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder X-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471 ( 3 ) Å, c = 21.5065 ( 3 ) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate a metallic character and the occurrence of antiferromagnetic order below a Néel temperature T N = 23 K. The transition is exceptionally robust and T N decreases by 0.2 K under a magnetic field of 9 T. A modified Curie-Weiss fit of the high-temperature magnetic susceptibility curve χ ( T ) gives an effective magnetic moment μ e f f = 2.54 μ B close to the value expected for trivalent Np. Low temperature heat capacity measurements give a reduced Sommerfeld linear coefficient close to 25 mJ mol−1K−2 and a Debye Temperature Θ D = 181 K. First principles, correlated-band electronic structure calculations suggest that the neptunium magnetic moment in NpPt2In7 is localized and that a quasi-two-dimensional antiferromagnetic structure could result from the competition of very weak interlayer interactions leading to very anisotropic properties. |
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Structural and physical characterization of NpPt<ce:inf loc="post">2</ce:inf>In<ce:inf loc="post">7</ce:inf> |
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