Effects of cerium doping on the performance of LSCF cathodes for intermediate temperature solid oxide fuel cells
In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical...
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Zhou, Feng [verfasserIn] |
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2018transfer abstract |
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Enthalten in: External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs - Dedhia, Kavita ELSEVIER, 2018, official journal of the International Association for Hydrogen Energy, New York, NY [u.a.] |
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volume:43 ; year:2018 ; number:41 ; day:11 ; month:10 ; pages:18946-18954 ; extent:9 |
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DOI / URN: |
10.1016/j.ijhydene.2018.08.041 |
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ELV044309457 |
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520 | |a In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. | ||
520 | |a In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. | ||
650 | 7 | |a Electrocatalytic activity |2 Elsevier | |
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700 | 1 | |a Yang, Shengbing |4 oth | |
700 | 1 | |a Zhong, Shaohua |4 oth | |
700 | 1 | |a Wei, Mingrui |4 oth | |
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10.1016/j.ijhydene.2018.08.041 doi GBV00000000000383.pica (DE-627)ELV044309457 (ELSEVIER)S0360-3199(18)32550-3 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Zhou, Feng verfasserin aut Effects of cerium doping on the performance of LSCF cathodes for intermediate temperature solid oxide fuel cells 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. Electrocatalytic activity Elsevier IT-SOFC Elsevier Cathode Elsevier ECR Elsevier DRT Elsevier Liu, Yihui oth Zhao, Xiaofei oth Tang, Wenxin oth Yang, Shengbing oth Zhong, Shaohua oth Wei, Mingrui oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:43 year:2018 number:41 day:11 month:10 pages:18946-18954 extent:9 https://doi.org/10.1016/j.ijhydene.2018.08.041 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 43 2018 41 11 1011 18946-18954 9 |
spelling |
10.1016/j.ijhydene.2018.08.041 doi GBV00000000000383.pica (DE-627)ELV044309457 (ELSEVIER)S0360-3199(18)32550-3 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Zhou, Feng verfasserin aut Effects of cerium doping on the performance of LSCF cathodes for intermediate temperature solid oxide fuel cells 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. Electrocatalytic activity Elsevier IT-SOFC Elsevier Cathode Elsevier ECR Elsevier DRT Elsevier Liu, Yihui oth Zhao, Xiaofei oth Tang, Wenxin oth Yang, Shengbing oth Zhong, Shaohua oth Wei, Mingrui oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:43 year:2018 number:41 day:11 month:10 pages:18946-18954 extent:9 https://doi.org/10.1016/j.ijhydene.2018.08.041 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 43 2018 41 11 1011 18946-18954 9 |
allfields_unstemmed |
10.1016/j.ijhydene.2018.08.041 doi GBV00000000000383.pica (DE-627)ELV044309457 (ELSEVIER)S0360-3199(18)32550-3 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Zhou, Feng verfasserin aut Effects of cerium doping on the performance of LSCF cathodes for intermediate temperature solid oxide fuel cells 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. Electrocatalytic activity Elsevier IT-SOFC Elsevier Cathode Elsevier ECR Elsevier DRT Elsevier Liu, Yihui oth Zhao, Xiaofei oth Tang, Wenxin oth Yang, Shengbing oth Zhong, Shaohua oth Wei, Mingrui oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:43 year:2018 number:41 day:11 month:10 pages:18946-18954 extent:9 https://doi.org/10.1016/j.ijhydene.2018.08.041 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 43 2018 41 11 1011 18946-18954 9 |
allfieldsGer |
10.1016/j.ijhydene.2018.08.041 doi GBV00000000000383.pica (DE-627)ELV044309457 (ELSEVIER)S0360-3199(18)32550-3 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Zhou, Feng verfasserin aut Effects of cerium doping on the performance of LSCF cathodes for intermediate temperature solid oxide fuel cells 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. Electrocatalytic activity Elsevier IT-SOFC Elsevier Cathode Elsevier ECR Elsevier DRT Elsevier Liu, Yihui oth Zhao, Xiaofei oth Tang, Wenxin oth Yang, Shengbing oth Zhong, Shaohua oth Wei, Mingrui oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:43 year:2018 number:41 day:11 month:10 pages:18946-18954 extent:9 https://doi.org/10.1016/j.ijhydene.2018.08.041 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 43 2018 41 11 1011 18946-18954 9 |
allfieldsSound |
10.1016/j.ijhydene.2018.08.041 doi GBV00000000000383.pica (DE-627)ELV044309457 (ELSEVIER)S0360-3199(18)32550-3 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Zhou, Feng verfasserin aut Effects of cerium doping on the performance of LSCF cathodes for intermediate temperature solid oxide fuel cells 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. Electrocatalytic activity Elsevier IT-SOFC Elsevier Cathode Elsevier ECR Elsevier DRT Elsevier Liu, Yihui oth Zhao, Xiaofei oth Tang, Wenxin oth Yang, Shengbing oth Zhong, Shaohua oth Wei, Mingrui oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:43 year:2018 number:41 day:11 month:10 pages:18946-18954 extent:9 https://doi.org/10.1016/j.ijhydene.2018.08.041 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 43 2018 41 11 1011 18946-18954 9 |
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Enthalten in External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs New York, NY [u.a.] volume:43 year:2018 number:41 day:11 month:10 pages:18946-18954 extent:9 |
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The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. 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The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. 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effects of cerium doping on the performance of lscf cathodes for intermediate temperature solid oxide fuel cells |
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Effects of cerium doping on the performance of LSCF cathodes for intermediate temperature solid oxide fuel cells |
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In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. |
abstractGer |
In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. |
abstract_unstemmed |
In this paper, effects of Ce substitution of La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) on the crystal structure have been investigated by XRD Rietveld refinement and results show that Ce doping at La-sites leads to lattice expansion without changing centrosymmetric cubic space group of LSCF. The electrochemical results suggest that the electrocatalytic activity of LSCF cathodes is enhanced by Ce doping. The values of oxygen surface exchange coefficient of LSCF, LCSCF03, LCSCF06, measured by electrical conductivity relaxation (ECR) method, are 5.6 × 10−4 cm s−1, 1.0 × 10−3 cm s−1, 3 × 10−3 cm s−1 at 750 °C respectively, implying that oxygen surface exchange coefficients are increased by Ce doping compared with that of LSCF. The enhancement of electrochemical performance of LSCF cathodes can be ascribed to the increase of the concentration of oxygen vacancies obtained from the thermogravimetric results, which results in faster kinetics of oxygen transport by Ce doping. |
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Effects of cerium doping on the performance of LSCF cathodes for intermediate temperature solid oxide fuel cells |
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