The role of auxiliaries in the immersion dyeing of textile fibres: Part 9 practical aspects of the role of inorganic electrolytes in dyeing cellulosic fibres with pure reactive dyes
The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in th...
Ausführliche Beschreibung
Autor*in: |
Burkinshaw, Stephen M. [verfasserIn] |
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Englisch |
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2019transfer abstract |
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14 |
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Übergeordnetes Werk: |
Enthalten in: A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells - Haghgoo, M. ELSEVIER, 2020, Amsterdam [u.a.] |
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Übergeordnetes Werk: |
volume:161 ; year:2019 ; pages:628-641 ; extent:14 |
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DOI / URN: |
10.1016/j.dyepig.2017.10.014 |
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ELV044417691 |
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245 | 1 | 4 | |a The role of auxiliaries in the immersion dyeing of textile fibres: Part 9 practical aspects of the role of inorganic electrolytes in dyeing cellulosic fibres with pure reactive dyes |
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520 | |a The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. | ||
520 | |a The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. | ||
650 | 7 | |a Dyeing cotton |2 Elsevier | |
650 | 7 | |a Electrolyte |2 Elsevier | |
650 | 7 | |a Dyeing auxiliaries |2 Elsevier | |
650 | 7 | |a Salt-free dyeing |2 Elsevier | |
650 | 7 | |a Pure reactive dyes |2 Elsevier | |
700 | 1 | |a Salihu, George |4 oth | |
773 | 0 | 8 | |i Enthalten in |n Elsevier Science |a Haghgoo, M. ELSEVIER |t A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells |d 2020 |g Amsterdam [u.a.] |w (DE-627)ELV004269640 |
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10.1016/j.dyepig.2017.10.014 doi GBV00000000000395.pica (DE-627)ELV044417691 (ELSEVIER)S0143-7208(17)31800-4 DE-627 ger DE-627 rakwb eng 690 VZ 50.31 bkl 56.11 bkl Burkinshaw, Stephen M. verfasserin aut The role of auxiliaries in the immersion dyeing of textile fibres: Part 9 practical aspects of the role of inorganic electrolytes in dyeing cellulosic fibres with pure reactive dyes 2019transfer abstract 14 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. Dyeing cotton Elsevier Electrolyte Elsevier Dyeing auxiliaries Elsevier Salt-free dyeing Elsevier Pure reactive dyes Elsevier Salihu, George oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:161 year:2019 pages:628-641 extent:14 https://doi.org/10.1016/j.dyepig.2017.10.014 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 161 2019 628-641 14 |
spelling |
10.1016/j.dyepig.2017.10.014 doi GBV00000000000395.pica (DE-627)ELV044417691 (ELSEVIER)S0143-7208(17)31800-4 DE-627 ger DE-627 rakwb eng 690 VZ 50.31 bkl 56.11 bkl Burkinshaw, Stephen M. verfasserin aut The role of auxiliaries in the immersion dyeing of textile fibres: Part 9 practical aspects of the role of inorganic electrolytes in dyeing cellulosic fibres with pure reactive dyes 2019transfer abstract 14 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. Dyeing cotton Elsevier Electrolyte Elsevier Dyeing auxiliaries Elsevier Salt-free dyeing Elsevier Pure reactive dyes Elsevier Salihu, George oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:161 year:2019 pages:628-641 extent:14 https://doi.org/10.1016/j.dyepig.2017.10.014 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 161 2019 628-641 14 |
allfields_unstemmed |
10.1016/j.dyepig.2017.10.014 doi GBV00000000000395.pica (DE-627)ELV044417691 (ELSEVIER)S0143-7208(17)31800-4 DE-627 ger DE-627 rakwb eng 690 VZ 50.31 bkl 56.11 bkl Burkinshaw, Stephen M. verfasserin aut The role of auxiliaries in the immersion dyeing of textile fibres: Part 9 practical aspects of the role of inorganic electrolytes in dyeing cellulosic fibres with pure reactive dyes 2019transfer abstract 14 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. Dyeing cotton Elsevier Electrolyte Elsevier Dyeing auxiliaries Elsevier Salt-free dyeing Elsevier Pure reactive dyes Elsevier Salihu, George oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:161 year:2019 pages:628-641 extent:14 https://doi.org/10.1016/j.dyepig.2017.10.014 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 161 2019 628-641 14 |
allfieldsGer |
10.1016/j.dyepig.2017.10.014 doi GBV00000000000395.pica (DE-627)ELV044417691 (ELSEVIER)S0143-7208(17)31800-4 DE-627 ger DE-627 rakwb eng 690 VZ 50.31 bkl 56.11 bkl Burkinshaw, Stephen M. verfasserin aut The role of auxiliaries in the immersion dyeing of textile fibres: Part 9 practical aspects of the role of inorganic electrolytes in dyeing cellulosic fibres with pure reactive dyes 2019transfer abstract 14 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. Dyeing cotton Elsevier Electrolyte Elsevier Dyeing auxiliaries Elsevier Salt-free dyeing Elsevier Pure reactive dyes Elsevier Salihu, George oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:161 year:2019 pages:628-641 extent:14 https://doi.org/10.1016/j.dyepig.2017.10.014 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 161 2019 628-641 14 |
allfieldsSound |
10.1016/j.dyepig.2017.10.014 doi GBV00000000000395.pica (DE-627)ELV044417691 (ELSEVIER)S0143-7208(17)31800-4 DE-627 ger DE-627 rakwb eng 690 VZ 50.31 bkl 56.11 bkl Burkinshaw, Stephen M. verfasserin aut The role of auxiliaries in the immersion dyeing of textile fibres: Part 9 practical aspects of the role of inorganic electrolytes in dyeing cellulosic fibres with pure reactive dyes 2019transfer abstract 14 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. Dyeing cotton Elsevier Electrolyte Elsevier Dyeing auxiliaries Elsevier Salt-free dyeing Elsevier Pure reactive dyes Elsevier Salihu, George oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:161 year:2019 pages:628-641 extent:14 https://doi.org/10.1016/j.dyepig.2017.10.014 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 161 2019 628-641 14 |
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Enthalten in A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells Amsterdam [u.a.] volume:161 year:2019 pages:628-641 extent:14 |
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role of auxiliaries in the immersion dyeing of textile fibres: part 9 practical aspects of the role of inorganic electrolytes in dyeing cellulosic fibres with pure reactive dyes |
title_auth |
The role of auxiliaries in the immersion dyeing of textile fibres: Part 9 practical aspects of the role of inorganic electrolytes in dyeing cellulosic fibres with pure reactive dyes |
abstract |
The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. |
abstractGer |
The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. |
abstract_unstemmed |
The colour strength, as well as the extents of both exhaustion and fixation, achieved for three pure reactive dyes on cotton were promoted by the addition of 50 gl-1 NaCl at each of seven liquor ratios employed (1:50, 1:20, 1:10, 1:6, 1:3, 1:2 and 1:1.5). The depth of shade of dyeings obtained in the absence of added electrolyte using a1:1.5 liquor ratio were of similar magnitude to those secured using 1:10–1:20 liquor ratios in the presence of 50 gl-1 NaCl. The promotional effect on dye uptake imparted by both added electrolyte and reduced liquor ratio was interpreted in terms of their effects on the substantivity of the reactive dyes towards the cotton substrate. The two, seemingly different actions of adding electrolyte such as NaCl or Na2SO4 to the reactive dye dyebath and reducing the liquor ratio used for immersion dyeing have the same result, namely that of encouraging dye aggregation in the dyebath, which reduces the solubility of the direct dye in the dyebath, which, in turn, shifts the inherent preference of the dye to favour the aqueous phase towards the fibre phase. It is thus possible to dye cotton using pure reactive dyes in the complete (ie 100%) absence of added inorganic electrolyte. The ensuing dyeings were of realistic depths of shade and displayed excellent levels of wash fastness. |
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The role of auxiliaries in the immersion dyeing of textile fibres: Part 9 practical aspects of the role of inorganic electrolytes in dyeing cellulosic fibres with pure reactive dyes |
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