Glass-ceramic oxidation protection of higher manganese silicide thermoelectrics
A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are re...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Salvo, M. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2019transfer abstract |
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| Umfang: |
6 |
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| Übergeordnetes Werk: |
Enthalten in: Improved differential evolution for RSSD-based localization in Gaussian mixture noise - Zhang, Yuanyuan ELSEVIER, 2023, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:39 ; year:2019 ; number:1 ; pages:66-71 ; extent:6 |
| Links: |
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| DOI / URN: |
10.1016/j.jeurceramsoc.2018.01.007 |
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| 520 | |a A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. | ||
| 520 | |a A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. | ||
| 650 | 7 | |a Glass-ceramic |2 Elsevier | |
| 650 | 7 | |a Thermoelectric |2 Elsevier | |
| 650 | 7 | |a Oxidation |2 Elsevier | |
| 650 | 7 | |a Coating |2 Elsevier | |
| 700 | 1 | |a Smeacetto, F. |4 oth | |
| 700 | 1 | |a D’Isanto, F. |4 oth | |
| 700 | 1 | |a Viola, G. |4 oth | |
| 700 | 1 | |a Demitri, P. |4 oth | |
| 700 | 1 | |a Gucci, F. |4 oth | |
| 700 | 1 | |a Reece, M.J. |4 oth | |
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10.1016/j.jeurceramsoc.2018.01.007 doi GBV00000000000406.pica (DE-627)ELV044564457 (ELSEVIER)S0955-2219(18)30007-4 DE-627 ger DE-627 rakwb eng 004 VZ 54.00 bkl Salvo, M. verfasserin aut Glass-ceramic oxidation protection of higher manganese silicide thermoelectrics 2019transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. Glass-ceramic Elsevier Thermoelectric Elsevier Oxidation Elsevier Coating Elsevier Smeacetto, F. oth D’Isanto, F. oth Viola, G. oth Demitri, P. oth Gucci, F. oth Reece, M.J. oth Enthalten in Elsevier Science Zhang, Yuanyuan ELSEVIER Improved differential evolution for RSSD-based localization in Gaussian mixture noise 2023 Amsterdam [u.a.] (DE-627)ELV009961755 volume:39 year:2019 number:1 pages:66-71 extent:6 https://doi.org/10.1016/j.jeurceramsoc.2018.01.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.00 Informatik: Allgemeines VZ AR 39 2019 1 66-71 6 |
| spelling |
10.1016/j.jeurceramsoc.2018.01.007 doi GBV00000000000406.pica (DE-627)ELV044564457 (ELSEVIER)S0955-2219(18)30007-4 DE-627 ger DE-627 rakwb eng 004 VZ 54.00 bkl Salvo, M. verfasserin aut Glass-ceramic oxidation protection of higher manganese silicide thermoelectrics 2019transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. Glass-ceramic Elsevier Thermoelectric Elsevier Oxidation Elsevier Coating Elsevier Smeacetto, F. oth D’Isanto, F. oth Viola, G. oth Demitri, P. oth Gucci, F. oth Reece, M.J. oth Enthalten in Elsevier Science Zhang, Yuanyuan ELSEVIER Improved differential evolution for RSSD-based localization in Gaussian mixture noise 2023 Amsterdam [u.a.] (DE-627)ELV009961755 volume:39 year:2019 number:1 pages:66-71 extent:6 https://doi.org/10.1016/j.jeurceramsoc.2018.01.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.00 Informatik: Allgemeines VZ AR 39 2019 1 66-71 6 |
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10.1016/j.jeurceramsoc.2018.01.007 doi GBV00000000000406.pica (DE-627)ELV044564457 (ELSEVIER)S0955-2219(18)30007-4 DE-627 ger DE-627 rakwb eng 004 VZ 54.00 bkl Salvo, M. verfasserin aut Glass-ceramic oxidation protection of higher manganese silicide thermoelectrics 2019transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. Glass-ceramic Elsevier Thermoelectric Elsevier Oxidation Elsevier Coating Elsevier Smeacetto, F. oth D’Isanto, F. oth Viola, G. oth Demitri, P. oth Gucci, F. oth Reece, M.J. oth Enthalten in Elsevier Science Zhang, Yuanyuan ELSEVIER Improved differential evolution for RSSD-based localization in Gaussian mixture noise 2023 Amsterdam [u.a.] (DE-627)ELV009961755 volume:39 year:2019 number:1 pages:66-71 extent:6 https://doi.org/10.1016/j.jeurceramsoc.2018.01.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.00 Informatik: Allgemeines VZ AR 39 2019 1 66-71 6 |
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10.1016/j.jeurceramsoc.2018.01.007 doi GBV00000000000406.pica (DE-627)ELV044564457 (ELSEVIER)S0955-2219(18)30007-4 DE-627 ger DE-627 rakwb eng 004 VZ 54.00 bkl Salvo, M. verfasserin aut Glass-ceramic oxidation protection of higher manganese silicide thermoelectrics 2019transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. Glass-ceramic Elsevier Thermoelectric Elsevier Oxidation Elsevier Coating Elsevier Smeacetto, F. oth D’Isanto, F. oth Viola, G. oth Demitri, P. oth Gucci, F. oth Reece, M.J. oth Enthalten in Elsevier Science Zhang, Yuanyuan ELSEVIER Improved differential evolution for RSSD-based localization in Gaussian mixture noise 2023 Amsterdam [u.a.] (DE-627)ELV009961755 volume:39 year:2019 number:1 pages:66-71 extent:6 https://doi.org/10.1016/j.jeurceramsoc.2018.01.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.00 Informatik: Allgemeines VZ AR 39 2019 1 66-71 6 |
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10.1016/j.jeurceramsoc.2018.01.007 doi GBV00000000000406.pica (DE-627)ELV044564457 (ELSEVIER)S0955-2219(18)30007-4 DE-627 ger DE-627 rakwb eng 004 VZ 54.00 bkl Salvo, M. verfasserin aut Glass-ceramic oxidation protection of higher manganese silicide thermoelectrics 2019transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. Glass-ceramic Elsevier Thermoelectric Elsevier Oxidation Elsevier Coating Elsevier Smeacetto, F. oth D’Isanto, F. oth Viola, G. oth Demitri, P. oth Gucci, F. oth Reece, M.J. oth Enthalten in Elsevier Science Zhang, Yuanyuan ELSEVIER Improved differential evolution for RSSD-based localization in Gaussian mixture noise 2023 Amsterdam [u.a.] (DE-627)ELV009961755 volume:39 year:2019 number:1 pages:66-71 extent:6 https://doi.org/10.1016/j.jeurceramsoc.2018.01.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.00 Informatik: Allgemeines VZ AR 39 2019 1 66-71 6 |
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Enthalten in Improved differential evolution for RSSD-based localization in Gaussian mixture noise Amsterdam [u.a.] volume:39 year:2019 number:1 pages:66-71 extent:6 |
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Improved differential evolution for RSSD-based localization in Gaussian mixture noise |
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glass-ceramic oxidation protection of higher manganese silicide thermoelectrics |
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Glass-ceramic oxidation protection of higher manganese silicide thermoelectrics |
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A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. |
| abstractGer |
A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. |
| abstract_unstemmed |
A higher manganese silicide (HMS) thermoelectric, with composition MnSi1.74, densified by spark plasma sintering, was successfully coated with a glass-ceramic, in order to be used at temperatures higher than 500 °C. Compositional changes in both the HMS substrate and the glass-ceramic coating are reviewed and discussed with respect to the electrical properties of the uncoated and coated HMS before and after thermal cycles from RT to 600 °C in air. The formation of a Si-deficient layer (MnSi) on the uncoated HMS surface is due to the reaction between the HMS and oxygen at 600 °C, thus contributing to a lower power factor in comparison with the as-sintered HMS. Coated HMS samples (after thermal cycles RT-600 °C) show a lower electrical resistivity and a significantly higher power factor in comparison with the uncoated ones. The glass-ceramic coating is self-reparable at 600 °C, as demonstrated by the complete sealing of an induced scratch on its surface. |
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