Aggregate morphology transition of an adamantane-containing surfactant via the host-guest interaction with β-cyclodextrin
(11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction...
Ausführliche Beschreibung
Autor*in: |
Zhong, Xing [verfasserIn] |
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Englisch |
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2018transfer abstract |
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9 |
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Übergeordnetes Werk: |
Enthalten in: Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects - Moreno-Cabezali, Belen Maria ELSEVIER, 2020, an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids, New York, NY [u.a.] |
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Übergeordnetes Werk: |
volume:272 ; year:2018 ; day:15 ; month:12 ; pages:209-217 ; extent:9 |
Links: |
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DOI / URN: |
10.1016/j.molliq.2018.09.096 |
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ELV04495218X |
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520 | |a (11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. | ||
520 | |a (11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. | ||
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10.1016/j.molliq.2018.09.096 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001204.pica (DE-627)ELV04495218X (ELSEVIER)S0167-7322(18)32836-8 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Zhong, Xing verfasserin aut Aggregate morphology transition of an adamantane-containing surfactant via the host-guest interaction with β-cyclodextrin 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier (11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. (11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. Hu, Caixia oth Yan, Xiaowei oth Liu, Xing oth Zhu, Dongjian oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:272 year:2018 day:15 month:12 pages:209-217 extent:9 https://doi.org/10.1016/j.molliq.2018.09.096 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 272 2018 15 1215 209-217 9 |
spelling |
10.1016/j.molliq.2018.09.096 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001204.pica (DE-627)ELV04495218X (ELSEVIER)S0167-7322(18)32836-8 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Zhong, Xing verfasserin aut Aggregate morphology transition of an adamantane-containing surfactant via the host-guest interaction with β-cyclodextrin 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier (11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. (11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. Hu, Caixia oth Yan, Xiaowei oth Liu, Xing oth Zhu, Dongjian oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:272 year:2018 day:15 month:12 pages:209-217 extent:9 https://doi.org/10.1016/j.molliq.2018.09.096 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 272 2018 15 1215 209-217 9 |
allfields_unstemmed |
10.1016/j.molliq.2018.09.096 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001204.pica (DE-627)ELV04495218X (ELSEVIER)S0167-7322(18)32836-8 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Zhong, Xing verfasserin aut Aggregate morphology transition of an adamantane-containing surfactant via the host-guest interaction with β-cyclodextrin 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier (11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. (11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. Hu, Caixia oth Yan, Xiaowei oth Liu, Xing oth Zhu, Dongjian oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:272 year:2018 day:15 month:12 pages:209-217 extent:9 https://doi.org/10.1016/j.molliq.2018.09.096 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 272 2018 15 1215 209-217 9 |
allfieldsGer |
10.1016/j.molliq.2018.09.096 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001204.pica (DE-627)ELV04495218X (ELSEVIER)S0167-7322(18)32836-8 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Zhong, Xing verfasserin aut Aggregate morphology transition of an adamantane-containing surfactant via the host-guest interaction with β-cyclodextrin 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier (11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. (11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. Hu, Caixia oth Yan, Xiaowei oth Liu, Xing oth Zhu, Dongjian oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:272 year:2018 day:15 month:12 pages:209-217 extent:9 https://doi.org/10.1016/j.molliq.2018.09.096 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 272 2018 15 1215 209-217 9 |
allfieldsSound |
10.1016/j.molliq.2018.09.096 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001204.pica (DE-627)ELV04495218X (ELSEVIER)S0167-7322(18)32836-8 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Zhong, Xing verfasserin aut Aggregate morphology transition of an adamantane-containing surfactant via the host-guest interaction with β-cyclodextrin 2018transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier (11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. (11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. Hu, Caixia oth Yan, Xiaowei oth Liu, Xing oth Zhu, Dongjian oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:272 year:2018 day:15 month:12 pages:209-217 extent:9 https://doi.org/10.1016/j.molliq.2018.09.096 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 272 2018 15 1215 209-217 9 |
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aggregate morphology transition of an adamantane-containing surfactant via the host-guest interaction with β-cyclodextrin |
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Aggregate morphology transition of an adamantane-containing surfactant via the host-guest interaction with β-cyclodextrin |
abstract |
(11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. |
abstractGer |
(11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. |
abstract_unstemmed |
(11-((Adamantane-1-carbonyl) oxy)-N,N-dimethylundecan-1-benzylammonium bromide (C11AD), a novel cationic surfactant containing an adamantane group and a hydrophobic chain, had been synthesized. Experiments were carried out to understand aggregate morphology transition via the host-guest interaction with β-cyclodextrin. Two groups of inclusion complexes were prepared by mixing C11AD and β-cyclodextrin (β-CD) in aqueous solution with 1:1 or 1:2 stoichiometry, denoted as C11AD/nβ-CD (n = 1 or 2). Results showed that C11AD could self-assemble into spherical-like micelles in aqueous solution, and the micelles of C11AD transformed into spherical vesicles, straight nanotubes or networks hydrogels with β-CD in different stoichiometries. The aggregation behaviors of surfactant C11AD by the host-guest interaction with β-cyclodextrin (β-CD) were investigated by transmission electron microscopy (TEM), Cryogenic Transmission electron microscopy (Cryo-TEM), scanning electron microscopy (SEM) and dynamic light scattering (DLS) measurement. A possible mechanism to explain aggregate transitions was suggested by the results of FT-IR, 1H NMR and 1H-1H 2D ROESY NMR spectra. Data reflected that β-CD first combined with the adamantane group in C11AD/1β-CD system to form spherical vesicles. Then increasing the β-CD amount, superfluous cyclodextrin would combine with the hydrophobic chain in C11AD/2β-CD system. Thus the hydrophobic interaction was destroyed and the hydrogen bonds, the main driving force, were the prime mover in the process of nanotubes and hydrogels formation. |
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Aggregate morphology transition of an adamantane-containing surfactant via the host-guest interaction with β-cyclodextrin |
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