Conditions for mutual conversion of Cr(Ⅲ) and Cr(Ⅵ) in aluminum chromium slag
The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhao, Pengda [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
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2019transfer abstract |
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| Umfang: |
8 |
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| Übergeordnetes Werk: |
Enthalten in: Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners - Jacobs, Jacquelyn A. ELSEVIER, 2017, JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics, Lausanne |
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| Übergeordnetes Werk: |
volume:788 ; year:2019 ; day:5 ; month:06 ; pages:506-513 ; extent:8 |
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| DOI / URN: |
10.1016/j.jallcom.2019.02.093 |
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| 520 | |a The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). | ||
| 520 | |a The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). | ||
| 650 | 7 | |a Refractory |2 Elsevier | |
| 650 | 7 | |a Hexavalent chromium |2 Elsevier | |
| 650 | 7 | |a Aluminum chromium slag |2 Elsevier | |
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| 700 | 1 | |a Yu, Jun |4 oth | |
| 700 | 1 | |a Gao, Hongjun |4 oth | |
| 700 | 1 | |a Cao, Yang |4 oth | |
| 700 | 1 | |a Zhu, Yuqian |4 oth | |
| 700 | 1 | |a Zhao, Huizhong |4 oth | |
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10.1016/j.jallcom.2019.02.093 doi GBV00000000000567.pica (DE-627)ELV046267646 (ELSEVIER)S0925-8388(19)30533-X DE-627 ger DE-627 rakwb eng 630 VZ Zhao, Pengda verfasserin aut Conditions for mutual conversion of Cr(Ⅲ) and Cr(Ⅵ) in aluminum chromium slag 2019transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). Refractory Elsevier Hexavalent chromium Elsevier Aluminum chromium slag Elsevier Zhang, Han oth Yu, Jun oth Gao, Hongjun oth Cao, Yang oth Zhu, Yuqian oth Zhao, Huizhong oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:788 year:2019 day:5 month:06 pages:506-513 extent:8 https://doi.org/10.1016/j.jallcom.2019.02.093 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 788 2019 5 0605 506-513 8 |
| spelling |
10.1016/j.jallcom.2019.02.093 doi GBV00000000000567.pica (DE-627)ELV046267646 (ELSEVIER)S0925-8388(19)30533-X DE-627 ger DE-627 rakwb eng 630 VZ Zhao, Pengda verfasserin aut Conditions for mutual conversion of Cr(Ⅲ) and Cr(Ⅵ) in aluminum chromium slag 2019transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). Refractory Elsevier Hexavalent chromium Elsevier Aluminum chromium slag Elsevier Zhang, Han oth Yu, Jun oth Gao, Hongjun oth Cao, Yang oth Zhu, Yuqian oth Zhao, Huizhong oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:788 year:2019 day:5 month:06 pages:506-513 extent:8 https://doi.org/10.1016/j.jallcom.2019.02.093 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 788 2019 5 0605 506-513 8 |
| allfields_unstemmed |
10.1016/j.jallcom.2019.02.093 doi GBV00000000000567.pica (DE-627)ELV046267646 (ELSEVIER)S0925-8388(19)30533-X DE-627 ger DE-627 rakwb eng 630 VZ Zhao, Pengda verfasserin aut Conditions for mutual conversion of Cr(Ⅲ) and Cr(Ⅵ) in aluminum chromium slag 2019transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). Refractory Elsevier Hexavalent chromium Elsevier Aluminum chromium slag Elsevier Zhang, Han oth Yu, Jun oth Gao, Hongjun oth Cao, Yang oth Zhu, Yuqian oth Zhao, Huizhong oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:788 year:2019 day:5 month:06 pages:506-513 extent:8 https://doi.org/10.1016/j.jallcom.2019.02.093 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 788 2019 5 0605 506-513 8 |
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10.1016/j.jallcom.2019.02.093 doi GBV00000000000567.pica (DE-627)ELV046267646 (ELSEVIER)S0925-8388(19)30533-X DE-627 ger DE-627 rakwb eng 630 VZ Zhao, Pengda verfasserin aut Conditions for mutual conversion of Cr(Ⅲ) and Cr(Ⅵ) in aluminum chromium slag 2019transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). Refractory Elsevier Hexavalent chromium Elsevier Aluminum chromium slag Elsevier Zhang, Han oth Yu, Jun oth Gao, Hongjun oth Cao, Yang oth Zhu, Yuqian oth Zhao, Huizhong oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:788 year:2019 day:5 month:06 pages:506-513 extent:8 https://doi.org/10.1016/j.jallcom.2019.02.093 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 788 2019 5 0605 506-513 8 |
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10.1016/j.jallcom.2019.02.093 doi GBV00000000000567.pica (DE-627)ELV046267646 (ELSEVIER)S0925-8388(19)30533-X DE-627 ger DE-627 rakwb eng 630 VZ Zhao, Pengda verfasserin aut Conditions for mutual conversion of Cr(Ⅲ) and Cr(Ⅵ) in aluminum chromium slag 2019transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). Refractory Elsevier Hexavalent chromium Elsevier Aluminum chromium slag Elsevier Zhang, Han oth Yu, Jun oth Gao, Hongjun oth Cao, Yang oth Zhu, Yuqian oth Zhao, Huizhong oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:788 year:2019 day:5 month:06 pages:506-513 extent:8 https://doi.org/10.1016/j.jallcom.2019.02.093 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 788 2019 5 0605 506-513 8 |
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Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. 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In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. 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Conditions for mutual conversion of Cr(Ⅲ) and Cr(Ⅵ) in aluminum chromium slag |
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The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). |
| abstractGer |
The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). |
| abstract_unstemmed |
The conditions for the mutual conversion of Cr(III) and Cr(VI) are investigated to realize safe application of aluminum chromium slag. Aluminum chromium slag is sintered with conventional refractory oxides in different atmospheres and at different temperatures to examine the phase of the sample and its Cr(Ⅵ) content in an aqueous solution. The results show that the slag system contains CaO and MgO that facilitate Cr(Ⅵ) formation, Al2O3 that inhibits Cr(Ⅵ) formation, TiO2, Fe2O3, and SiO2 that reduce Cr(Ⅵ) to Cr(III). In a reducing atmosphere, even if the alkaline environment condition is satisfied, Cr(Ⅵ) in the aluminum chromium slag is reduced to Cr(Ⅲ), thus detoxifying the slag. In addition, under alkaline environment and oxidizing atmosphere conditions, the slag temperature corresponding to the transition of Cr(Ⅵ) to Cr(III) is between 900 °C and 1000 °C. Thus, the transition of Cr(III) to Cr(VI) in aluminum chromium slag requires three conditions, alkaline environment, oxidizing atmosphere, and high temperature, and all the three conditions are indispensable. Consequently, the safe application of aluminum chromium slag can be realized by controlling the conditions for the mutual conversion of Cr (III) and Cr (VI). |
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Conditions for mutual conversion of Cr(Ⅲ) and Cr(Ⅵ) in aluminum chromium slag |
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Zhang, Han Yu, Jun Gao, Hongjun Cao, Yang Zhu, Yuqian Zhao, Huizhong |
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