In-situ generation of Ag, Cd, Hg, In, Pb, Tl and Zn volatile species by flowing liquid anode atmospheric pressure glow discharge operated in gaseous jet mode – Evaluation of excitation processes and analytical performance
The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective st...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Greda, Krzysztof [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2019transfer abstract |
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| Schlagwörter: |
Electrolyte cathode glow discharge |
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| Umfang: |
9 |
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| Übergeordnetes Werk: |
Enthalten in: Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications - Mohamed, S.H. ELSEVIER, 2019, the international journal of pure and applied analytical chemistry, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:199 ; year:2019 ; day:1 ; month:07 ; pages:107-115 ; extent:9 |
| Links: |
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| DOI / URN: |
10.1016/j.talanta.2019.02.058 |
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ELV046312374 |
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| 245 | 1 | 0 | |a In-situ generation of Ag, Cd, Hg, In, Pb, Tl and Zn volatile species by flowing liquid anode atmospheric pressure glow discharge operated in gaseous jet mode – Evaluation of excitation processes and analytical performance |
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| 520 | |a The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. | ||
| 520 | |a The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. | ||
| 650 | 7 | |a Electrolyte cathode glow discharge |2 Elsevier | |
| 650 | 7 | |a Miniaturized plasma |2 Elsevier | |
| 650 | 7 | |a Solution cathode glow discharge |2 Elsevier | |
| 650 | 7 | |a Optical emission spectrometry |2 Elsevier | |
| 650 | 7 | |a Spectral analysis |2 Elsevier | |
| 650 | 7 | |a Analytical chemistry instrumentation |2 Elsevier | |
| 700 | 1 | |a Gorska, Monika |4 oth | |
| 700 | 1 | |a Welna, Maja |4 oth | |
| 700 | 1 | |a Jamroz, Piotr |4 oth | |
| 700 | 1 | |a Pohl, Pawel |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier Science |a Mohamed, S.H. ELSEVIER |t Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications |d 2019 |d the international journal of pure and applied analytical chemistry |g Amsterdam [u.a.] |w (DE-627)ELV003060667 |
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10.1016/j.talanta.2019.02.058 doi GBV00000000000572.pica (DE-627)ELV046312374 (ELSEVIER)S0039-9140(19)30201-2 DE-627 ger DE-627 rakwb eng 530 620 VZ 53.56 bkl Greda, Krzysztof verfasserin aut In-situ generation of Ag, Cd, Hg, In, Pb, Tl and Zn volatile species by flowing liquid anode atmospheric pressure glow discharge operated in gaseous jet mode – Evaluation of excitation processes and analytical performance 2019transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. Electrolyte cathode glow discharge Elsevier Miniaturized plasma Elsevier Solution cathode glow discharge Elsevier Optical emission spectrometry Elsevier Spectral analysis Elsevier Analytical chemistry instrumentation Elsevier Gorska, Monika oth Welna, Maja oth Jamroz, Piotr oth Pohl, Pawel oth Enthalten in Elsevier Science Mohamed, S.H. ELSEVIER Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications 2019 the international journal of pure and applied analytical chemistry Amsterdam [u.a.] (DE-627)ELV003060667 volume:199 year:2019 day:1 month:07 pages:107-115 extent:9 https://doi.org/10.1016/j.talanta.2019.02.058 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 53.56 Halbleitertechnologie VZ AR 199 2019 1 0701 107-115 9 |
| spelling |
10.1016/j.talanta.2019.02.058 doi GBV00000000000572.pica (DE-627)ELV046312374 (ELSEVIER)S0039-9140(19)30201-2 DE-627 ger DE-627 rakwb eng 530 620 VZ 53.56 bkl Greda, Krzysztof verfasserin aut In-situ generation of Ag, Cd, Hg, In, Pb, Tl and Zn volatile species by flowing liquid anode atmospheric pressure glow discharge operated in gaseous jet mode – Evaluation of excitation processes and analytical performance 2019transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. Electrolyte cathode glow discharge Elsevier Miniaturized plasma Elsevier Solution cathode glow discharge Elsevier Optical emission spectrometry Elsevier Spectral analysis Elsevier Analytical chemistry instrumentation Elsevier Gorska, Monika oth Welna, Maja oth Jamroz, Piotr oth Pohl, Pawel oth Enthalten in Elsevier Science Mohamed, S.H. ELSEVIER Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications 2019 the international journal of pure and applied analytical chemistry Amsterdam [u.a.] (DE-627)ELV003060667 volume:199 year:2019 day:1 month:07 pages:107-115 extent:9 https://doi.org/10.1016/j.talanta.2019.02.058 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 53.56 Halbleitertechnologie VZ AR 199 2019 1 0701 107-115 9 |
| allfields_unstemmed |
10.1016/j.talanta.2019.02.058 doi GBV00000000000572.pica (DE-627)ELV046312374 (ELSEVIER)S0039-9140(19)30201-2 DE-627 ger DE-627 rakwb eng 530 620 VZ 53.56 bkl Greda, Krzysztof verfasserin aut In-situ generation of Ag, Cd, Hg, In, Pb, Tl and Zn volatile species by flowing liquid anode atmospheric pressure glow discharge operated in gaseous jet mode – Evaluation of excitation processes and analytical performance 2019transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. Electrolyte cathode glow discharge Elsevier Miniaturized plasma Elsevier Solution cathode glow discharge Elsevier Optical emission spectrometry Elsevier Spectral analysis Elsevier Analytical chemistry instrumentation Elsevier Gorska, Monika oth Welna, Maja oth Jamroz, Piotr oth Pohl, Pawel oth Enthalten in Elsevier Science Mohamed, S.H. ELSEVIER Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications 2019 the international journal of pure and applied analytical chemistry Amsterdam [u.a.] (DE-627)ELV003060667 volume:199 year:2019 day:1 month:07 pages:107-115 extent:9 https://doi.org/10.1016/j.talanta.2019.02.058 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 53.56 Halbleitertechnologie VZ AR 199 2019 1 0701 107-115 9 |
| allfieldsGer |
10.1016/j.talanta.2019.02.058 doi GBV00000000000572.pica (DE-627)ELV046312374 (ELSEVIER)S0039-9140(19)30201-2 DE-627 ger DE-627 rakwb eng 530 620 VZ 53.56 bkl Greda, Krzysztof verfasserin aut In-situ generation of Ag, Cd, Hg, In, Pb, Tl and Zn volatile species by flowing liquid anode atmospheric pressure glow discharge operated in gaseous jet mode – Evaluation of excitation processes and analytical performance 2019transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. Electrolyte cathode glow discharge Elsevier Miniaturized plasma Elsevier Solution cathode glow discharge Elsevier Optical emission spectrometry Elsevier Spectral analysis Elsevier Analytical chemistry instrumentation Elsevier Gorska, Monika oth Welna, Maja oth Jamroz, Piotr oth Pohl, Pawel oth Enthalten in Elsevier Science Mohamed, S.H. ELSEVIER Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications 2019 the international journal of pure and applied analytical chemistry Amsterdam [u.a.] (DE-627)ELV003060667 volume:199 year:2019 day:1 month:07 pages:107-115 extent:9 https://doi.org/10.1016/j.talanta.2019.02.058 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 53.56 Halbleitertechnologie VZ AR 199 2019 1 0701 107-115 9 |
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10.1016/j.talanta.2019.02.058 doi GBV00000000000572.pica (DE-627)ELV046312374 (ELSEVIER)S0039-9140(19)30201-2 DE-627 ger DE-627 rakwb eng 530 620 VZ 53.56 bkl Greda, Krzysztof verfasserin aut In-situ generation of Ag, Cd, Hg, In, Pb, Tl and Zn volatile species by flowing liquid anode atmospheric pressure glow discharge operated in gaseous jet mode – Evaluation of excitation processes and analytical performance 2019transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. Electrolyte cathode glow discharge Elsevier Miniaturized plasma Elsevier Solution cathode glow discharge Elsevier Optical emission spectrometry Elsevier Spectral analysis Elsevier Analytical chemistry instrumentation Elsevier Gorska, Monika oth Welna, Maja oth Jamroz, Piotr oth Pohl, Pawel oth Enthalten in Elsevier Science Mohamed, S.H. ELSEVIER Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications 2019 the international journal of pure and applied analytical chemistry Amsterdam [u.a.] (DE-627)ELV003060667 volume:199 year:2019 day:1 month:07 pages:107-115 extent:9 https://doi.org/10.1016/j.talanta.2019.02.058 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 53.56 Halbleitertechnologie VZ AR 199 2019 1 0701 107-115 9 |
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In-situ generation of Ag, Cd, Hg, In, Pb, Tl and Zn volatile species by flowing liquid anode atmospheric pressure glow discharge operated in gaseous jet mode – Evaluation of excitation processes and analytical performance |
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The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. |
| abstractGer |
The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. |
| abstract_unstemmed |
The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV046312374</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230626013458.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">191021s2019 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.talanta.2019.02.058</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">GBV00000000000572.pica</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV046312374</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0039-9140(19)30201-2</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">530</subfield><subfield code="a">620</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">53.56</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Greda, Krzysztof</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">In-situ generation of Ag, Cd, Hg, In, Pb, Tl and Zn volatile species by flowing liquid anode atmospheric pressure glow discharge operated in gaseous jet mode – Evaluation of excitation processes and analytical performance</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019transfer abstract</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">9</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The use of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) operated with the aid of a gaseous jet as an efficient and novel excitation source for optical emission spectrometry (OES) was evaluated in details. Although about 50 elements have been tested by introducing respective standard solutions into a discharge system, only emission lines of Ag, Cd, Hg, In, Pb, Tl and Zn have been identified. In this arrangement, the surface of solution was bombarded by electrons resulting in generation of volatile species of mentioned elements. After penetrating the plasma, they were excited and extraordinary atomic emission was observed for these elements. It was found that the use of the Ar or He jet provided beneficial excitation conditions, while reduction of the discharge gap led to suppression of the intensity of interfering diatomic molecular bands like NO, OH and N2. Under optimal operating conditions of the discharge system, detection limits (DLs) assessed for Ag, Cd, Hg, In, Pb, Tl and Zn were respectively 0.001, 0.006, 0.16, 0.093, 0.076, 0.007 and 0.018 µg L−1, and they were on average by 10-times better as referred to earlier FLA-APGD constructions operated without the gaseous jet. In addition, the discharge was characterized by greater stability and precision of measurements (< 2%). Dynamic ranges of calibration curves covered between 3.5 (Cd, In, Zn) and over 5 orders of magnitude (Ag, Tl). The biggest weakness of the developed system turned out to be high susceptibility to matrix interferences. It was found that presence of foreign ions (at concentrations of 1–10 mg L−1) suppressed emission from studied elements on average by 20–60%. To clarify the reason for extremely high sensitivity of emission lines of Ag, Cd, Hg In, Pb, Tl and Zn, efficiency of transport of these elements from the liquid phase to the plasma was determined. It was established that from 5% to 70% of analytes presented in sample solutions were released, whereas evaporation of water was merely 5–15%. Since the FLA-APGD plasma was enriched with analytes atoms, it was concluded that such processes like electrospray formation or solution evaporation do not make a major contribution to transport of analytes from the liquid phase to the discharge, and that it was mainly due to plasma-induced volatile species generation processes.</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Electrolyte cathode glow discharge</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Miniaturized plasma</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Solution cathode glow discharge</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Optical emission spectrometry</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Spectral analysis</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Analytical chemistry instrumentation</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Gorska, Monika</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Welna, Maja</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Jamroz, Piotr</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Pohl, Pawel</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="n">Elsevier Science</subfield><subfield code="a">Mohamed, S.H. ELSEVIER</subfield><subfield code="t">Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications</subfield><subfield code="d">2019</subfield><subfield code="d">the international journal of pure and applied analytical chemistry</subfield><subfield code="g">Amsterdam [u.a.]</subfield><subfield code="w">(DE-627)ELV003060667</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:199</subfield><subfield code="g">year:2019</subfield><subfield code="g">day:1</subfield><subfield code="g">month:07</subfield><subfield code="g">pages:107-115</subfield><subfield code="g">extent:9</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.1016/j.talanta.2019.02.058</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">53.56</subfield><subfield code="j">Halbleitertechnologie</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">199</subfield><subfield code="j">2019</subfield><subfield code="b">1</subfield><subfield code="c">0701</subfield><subfield code="h">107-115</subfield><subfield code="g">9</subfield></datafield></record></collection>
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