Barium isotopic fractionation in latosol developed from strongly weathered basalt
Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profil...
Ausführliche Beschreibung
Autor*in: |
Gong, Yingzeng [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2019transfer abstract |
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Umfang: |
10 |
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Übergeordnetes Werk: |
Enthalten in: SPG-56 from Sweet potato Zhongshu-1 delayed growth of tumor xenografts in nude mice by modulating gut microbiota - Wang, Meimei ELSEVIER, 2018, an international journal for scientific research into the environment and its relationship with man, Amsterdam [u.a.] |
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Übergeordnetes Werk: |
volume:687 ; year:2019 ; day:15 ; month:10 ; pages:1295-1304 ; extent:10 |
Links: |
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DOI / URN: |
10.1016/j.scitotenv.2019.05.427 |
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ELV047541180 |
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520 | |a Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. | ||
520 | |a Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. | ||
700 | 1 | |a Zeng, Zhen |4 oth | |
700 | 1 | |a Zhou, Chen |4 oth | |
700 | 1 | |a Nan, Xiaoyun |4 oth | |
700 | 1 | |a Yu, Huimin |4 oth | |
700 | 1 | |a Lu, Ying |4 oth | |
700 | 1 | |a Li, Wangye |4 oth | |
700 | 1 | |a Gou, Wenxian |4 oth | |
700 | 1 | |a Cheng, Wenhan |4 oth | |
700 | 1 | |a Huang, Fang |4 oth | |
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10.1016/j.scitotenv.2019.05.427 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000877.pica (DE-627)ELV047541180 (ELSEVIER)S0048-9697(19)32481-7 DE-627 ger DE-627 rakwb eng 630 640 610 VZ Gong, Yingzeng verfasserin aut Barium isotopic fractionation in latosol developed from strongly weathered basalt 2019transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. Zeng, Zhen oth Zhou, Chen oth Nan, Xiaoyun oth Yu, Huimin oth Lu, Ying oth Li, Wangye oth Gou, Wenxian oth Cheng, Wenhan oth Huang, Fang oth Enthalten in Elsevier Science Wang, Meimei ELSEVIER SPG-56 from Sweet potato Zhongshu-1 delayed growth of tumor xenografts in nude mice by modulating gut microbiota 2018 an international journal for scientific research into the environment and its relationship with man Amsterdam [u.a.] (DE-627)ELV001360035 volume:687 year:2019 day:15 month:10 pages:1295-1304 extent:10 https://doi.org/10.1016/j.scitotenv.2019.05.427 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 687 2019 15 1015 1295-1304 10 |
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10.1016/j.scitotenv.2019.05.427 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000877.pica (DE-627)ELV047541180 (ELSEVIER)S0048-9697(19)32481-7 DE-627 ger DE-627 rakwb eng 630 640 610 VZ Gong, Yingzeng verfasserin aut Barium isotopic fractionation in latosol developed from strongly weathered basalt 2019transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. Zeng, Zhen oth Zhou, Chen oth Nan, Xiaoyun oth Yu, Huimin oth Lu, Ying oth Li, Wangye oth Gou, Wenxian oth Cheng, Wenhan oth Huang, Fang oth Enthalten in Elsevier Science Wang, Meimei ELSEVIER SPG-56 from Sweet potato Zhongshu-1 delayed growth of tumor xenografts in nude mice by modulating gut microbiota 2018 an international journal for scientific research into the environment and its relationship with man Amsterdam [u.a.] (DE-627)ELV001360035 volume:687 year:2019 day:15 month:10 pages:1295-1304 extent:10 https://doi.org/10.1016/j.scitotenv.2019.05.427 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 687 2019 15 1015 1295-1304 10 |
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10.1016/j.scitotenv.2019.05.427 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000877.pica (DE-627)ELV047541180 (ELSEVIER)S0048-9697(19)32481-7 DE-627 ger DE-627 rakwb eng 630 640 610 VZ Gong, Yingzeng verfasserin aut Barium isotopic fractionation in latosol developed from strongly weathered basalt 2019transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. Zeng, Zhen oth Zhou, Chen oth Nan, Xiaoyun oth Yu, Huimin oth Lu, Ying oth Li, Wangye oth Gou, Wenxian oth Cheng, Wenhan oth Huang, Fang oth Enthalten in Elsevier Science Wang, Meimei ELSEVIER SPG-56 from Sweet potato Zhongshu-1 delayed growth of tumor xenografts in nude mice by modulating gut microbiota 2018 an international journal for scientific research into the environment and its relationship with man Amsterdam [u.a.] (DE-627)ELV001360035 volume:687 year:2019 day:15 month:10 pages:1295-1304 extent:10 https://doi.org/10.1016/j.scitotenv.2019.05.427 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 687 2019 15 1015 1295-1304 10 |
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10.1016/j.scitotenv.2019.05.427 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000877.pica (DE-627)ELV047541180 (ELSEVIER)S0048-9697(19)32481-7 DE-627 ger DE-627 rakwb eng 630 640 610 VZ Gong, Yingzeng verfasserin aut Barium isotopic fractionation in latosol developed from strongly weathered basalt 2019transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. Zeng, Zhen oth Zhou, Chen oth Nan, Xiaoyun oth Yu, Huimin oth Lu, Ying oth Li, Wangye oth Gou, Wenxian oth Cheng, Wenhan oth Huang, Fang oth Enthalten in Elsevier Science Wang, Meimei ELSEVIER SPG-56 from Sweet potato Zhongshu-1 delayed growth of tumor xenografts in nude mice by modulating gut microbiota 2018 an international journal for scientific research into the environment and its relationship with man Amsterdam [u.a.] (DE-627)ELV001360035 volume:687 year:2019 day:15 month:10 pages:1295-1304 extent:10 https://doi.org/10.1016/j.scitotenv.2019.05.427 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 687 2019 15 1015 1295-1304 10 |
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10.1016/j.scitotenv.2019.05.427 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000877.pica (DE-627)ELV047541180 (ELSEVIER)S0048-9697(19)32481-7 DE-627 ger DE-627 rakwb eng 630 640 610 VZ Gong, Yingzeng verfasserin aut Barium isotopic fractionation in latosol developed from strongly weathered basalt 2019transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. Zeng, Zhen oth Zhou, Chen oth Nan, Xiaoyun oth Yu, Huimin oth Lu, Ying oth Li, Wangye oth Gou, Wenxian oth Cheng, Wenhan oth Huang, Fang oth Enthalten in Elsevier Science Wang, Meimei ELSEVIER SPG-56 from Sweet potato Zhongshu-1 delayed growth of tumor xenografts in nude mice by modulating gut microbiota 2018 an international journal for scientific research into the environment and its relationship with man Amsterdam [u.a.] (DE-627)ELV001360035 volume:687 year:2019 day:15 month:10 pages:1295-1304 extent:10 https://doi.org/10.1016/j.scitotenv.2019.05.427 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 687 2019 15 1015 1295-1304 10 |
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Enthalten in SPG-56 from Sweet potato Zhongshu-1 delayed growth of tumor xenografts in nude mice by modulating gut microbiota Amsterdam [u.a.] volume:687 year:2019 day:15 month:10 pages:1295-1304 extent:10 |
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Enthalten in SPG-56 from Sweet potato Zhongshu-1 delayed growth of tumor xenografts in nude mice by modulating gut microbiota Amsterdam [u.a.] volume:687 year:2019 day:15 month:10 pages:1295-1304 extent:10 |
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SPG-56 from Sweet potato Zhongshu-1 delayed growth of tumor xenografts in nude mice by modulating gut microbiota |
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SPG-56 from Sweet potato Zhongshu-1 delayed growth of tumor xenografts in nude mice by modulating gut microbiota |
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barium isotopic fractionation in latosol developed from strongly weathered basalt |
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Barium isotopic fractionation in latosol developed from strongly weathered basalt |
abstract |
Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. |
abstractGer |
Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. |
abstract_unstemmed |
Weathering is a key process in the transfer of material from continents to the hydrosphere. A latosol profile in Zhanjiang, Guangdong Province, South China, formed through intense weathering of basalt, was studied to improve understanding of Ba isotopic fractionation during basalt weathering. Profile horizons were grouped into Ba-depleted and Ba-enriched layers (D- and E-layers, respectively) according to the mass fraction of Ba lost or gained from the weathered profile relative to bedrock. δ137/134Ba values in the soil profile ranged from −0.22‰ to +0.02‰, lower than those of the parent basaltic rock (0.03‰ ± 0.03‰). In the D-layers, Ba isotopic fractionation can be explained by Rayleigh fractionation, implying that heavy Ba isotopes are preferentially leached. The Rayleigh fractionation model is not applicable to the E-layers because they preferentially acquired isotopically light Ba isotopes during weathering. Results indicate a net loss of heavy Ba isotopes during strong weathering of basalt due to the precipitation of FeMn (oxyhydr)oxides and adsorption on secondary minerals. A mass-balance model indicates that the average δ137/134Ba value of materials leached from the weathered profile is ~0.08‰, slightly higher than that of the bedrock. This suggests a loss of heavy Ba isotopes into the hydrosphere during weathering of basalt, consistent with the enrichment of heavy Ba isotopes in river waters. |
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Barium isotopic fractionation in latosol developed from strongly weathered basalt |
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Zeng, Zhen Zhou, Chen Nan, Xiaoyun Yu, Huimin Lu, Ying Li, Wangye Gou, Wenxian Cheng, Wenhan Huang, Fang |
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