Electrochemical performance of pure Al, Al–Sn, Al–Mg and Al–Mg–Sn anodes for Al-air batteries
In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Ren, Jianming [verfasserIn] |
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E-Artikel |
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| Sprache: |
Englisch |
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2019transfer abstract |
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| Übergeordnetes Werk: |
Enthalten in: Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners - Jacobs, Jacquelyn A. ELSEVIER, 2017, JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics, Lausanne |
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| Übergeordnetes Werk: |
volume:808 ; year:2019 ; day:5 ; month:11 ; pages:0 |
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| DOI / URN: |
10.1016/j.jallcom.2019.151708 |
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| 520 | |a In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. | ||
| 520 | |a In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. | ||
| 650 | 7 | |a Electrochemistry |2 Elsevier | |
| 650 | 7 | |a Self-corrosion |2 Elsevier | |
| 650 | 7 | |a Al-air battery |2 Elsevier | |
| 650 | 7 | |a Aluminum alloy |2 Elsevier | |
| 700 | 1 | |a Ma, Jianbo |4 oth | |
| 700 | 1 | |a Zhang, Jiao |4 oth | |
| 700 | 1 | |a Fu, Chaopeng |4 oth | |
| 700 | 1 | |a Sun, Baode |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier |a Jacobs, Jacquelyn A. ELSEVIER |t Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners |d 2017 |d JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics |g Lausanne |w (DE-627)ELV001115774 |
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10.1016/j.jallcom.2019.151708 doi GBV00000000000733.pica (DE-627)ELV047768835 (ELSEVIER)S0925-8388(19)32941-X DE-627 ger DE-627 rakwb eng 630 VZ Ren, Jianming verfasserin aut Electrochemical performance of pure Al, Al–Sn, Al–Mg and Al–Mg–Sn anodes for Al-air batteries 2019transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. Electrochemistry Elsevier Self-corrosion Elsevier Al-air battery Elsevier Aluminum alloy Elsevier Ma, Jianbo oth Zhang, Jiao oth Fu, Chaopeng oth Sun, Baode oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:808 year:2019 day:5 month:11 pages:0 https://doi.org/10.1016/j.jallcom.2019.151708 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 808 2019 5 1105 0 |
| spelling |
10.1016/j.jallcom.2019.151708 doi GBV00000000000733.pica (DE-627)ELV047768835 (ELSEVIER)S0925-8388(19)32941-X DE-627 ger DE-627 rakwb eng 630 VZ Ren, Jianming verfasserin aut Electrochemical performance of pure Al, Al–Sn, Al–Mg and Al–Mg–Sn anodes for Al-air batteries 2019transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. Electrochemistry Elsevier Self-corrosion Elsevier Al-air battery Elsevier Aluminum alloy Elsevier Ma, Jianbo oth Zhang, Jiao oth Fu, Chaopeng oth Sun, Baode oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:808 year:2019 day:5 month:11 pages:0 https://doi.org/10.1016/j.jallcom.2019.151708 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 808 2019 5 1105 0 |
| allfields_unstemmed |
10.1016/j.jallcom.2019.151708 doi GBV00000000000733.pica (DE-627)ELV047768835 (ELSEVIER)S0925-8388(19)32941-X DE-627 ger DE-627 rakwb eng 630 VZ Ren, Jianming verfasserin aut Electrochemical performance of pure Al, Al–Sn, Al–Mg and Al–Mg–Sn anodes for Al-air batteries 2019transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. Electrochemistry Elsevier Self-corrosion Elsevier Al-air battery Elsevier Aluminum alloy Elsevier Ma, Jianbo oth Zhang, Jiao oth Fu, Chaopeng oth Sun, Baode oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:808 year:2019 day:5 month:11 pages:0 https://doi.org/10.1016/j.jallcom.2019.151708 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 808 2019 5 1105 0 |
| allfieldsGer |
10.1016/j.jallcom.2019.151708 doi GBV00000000000733.pica (DE-627)ELV047768835 (ELSEVIER)S0925-8388(19)32941-X DE-627 ger DE-627 rakwb eng 630 VZ Ren, Jianming verfasserin aut Electrochemical performance of pure Al, Al–Sn, Al–Mg and Al–Mg–Sn anodes for Al-air batteries 2019transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. Electrochemistry Elsevier Self-corrosion Elsevier Al-air battery Elsevier Aluminum alloy Elsevier Ma, Jianbo oth Zhang, Jiao oth Fu, Chaopeng oth Sun, Baode oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:808 year:2019 day:5 month:11 pages:0 https://doi.org/10.1016/j.jallcom.2019.151708 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 808 2019 5 1105 0 |
| allfieldsSound |
10.1016/j.jallcom.2019.151708 doi GBV00000000000733.pica (DE-627)ELV047768835 (ELSEVIER)S0925-8388(19)32941-X DE-627 ger DE-627 rakwb eng 630 VZ Ren, Jianming verfasserin aut Electrochemical performance of pure Al, Al–Sn, Al–Mg and Al–Mg–Sn anodes for Al-air batteries 2019transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. Electrochemistry Elsevier Self-corrosion Elsevier Al-air battery Elsevier Aluminum alloy Elsevier Ma, Jianbo oth Zhang, Jiao oth Fu, Chaopeng oth Sun, Baode oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:808 year:2019 day:5 month:11 pages:0 https://doi.org/10.1016/j.jallcom.2019.151708 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 808 2019 5 1105 0 |
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Enthalten in Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners Lausanne volume:808 year:2019 day:5 month:11 pages:0 |
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Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. 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Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners |
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electrochemical performance of pure al, al–sn, al–mg and al–mg–sn anodes for al-air batteries |
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Electrochemical performance of pure Al, Al–Sn, Al–Mg and Al–Mg–Sn anodes for Al-air batteries |
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In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. |
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In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. |
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In this work, pure Al, Al–Sn, Al–Mg, and Al–Mg–Sn alloys have been investigated as anodes for aluminum-air batteries. Effects of Mg and Sn additions on the aluminum anodes for Al-air battery in 4 mol L−1 KOH solution have been evaluated by self-corrosion test, open circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, cell voltage and galvanostatic discharge as well as ab-initio energy calculation based on density functional theory. The results show that Al alloy anodes show better corrosion resistance and battery performance than the pure Al anodes. The self-corrosion rate of Al alloys increase in the following order: Al > Al–Sn > Al–Mg–Sn > Al–Mg. The Al–Mg alloy shows the smallest self-corrosion rate and largest capacity among the three Al alloy anodes. The Al–Mg–Sn alloy has the best electrochemical performance and battery discharge performance. SEM, EDS and 3D measuring laser microscope analysis of Al alloys are in good agreement with the self-corrosion test and electrochemical characteristics. Furthermore, the ab-initio energy calculation also reveals the positive role of alloying elements in enhancing corrosion and electrochemical performances. |
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Electrochemical performance of pure Al, Al–Sn, Al–Mg and Al–Mg–Sn anodes for Al-air batteries |
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Ma, Jianbo Zhang, Jiao Fu, Chaopeng Sun, Baode |
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