Palladacycle promoted asymmetric hydrophosphination of <ce:italic>α</ce:italic>,<ce:italic>β</ce:italic>-unsaturated sulfonyl fluorides
The first example of an enantioselective hydrophosphination reaction of ethenesulfonyl fluoride derivatives catalyzed by a phosphapalladacycle afforded chiral sulfonyl fluoride-derived phosphines in quantitative yields and enantioselectivities of up to 93% ee. Investigations revealed the importance...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Li, Xi-Rui [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2019 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial - Li, Chenglong ELSEVIER, 2019, New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:899 ; year:2019 ; day:30 ; month:10 ; pages:0 |
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| DOI / URN: |
10.1016/j.jorganchem.2019.120912 |
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| 520 | |a The first example of an enantioselective hydrophosphination reaction of ethenesulfonyl fluoride derivatives catalyzed by a phosphapalladacycle afforded chiral sulfonyl fluoride-derived phosphines in quantitative yields and enantioselectivities of up to 93% ee. Investigations revealed the importance of adjacent vacant sites within the active metal center for intramolecular nucleophilic attack to provide the functionalized phosphine. | ||
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| 650 | 7 | |a Sulfonyl fluorides |2 Elsevier | |
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| 700 | 1 | |a Pullarkat, Sumod A. |4 oth | |
| 700 | 1 | |a Leung, Pak-Hing |4 oth | |
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10.1016/j.jorganchem.2019.120912 doi GBV00000000000746.pica (DE-627)ELV04788939X (ELSEVIER)S0022-328X(19)30355-9 DE-627 ger DE-627 rakwb eng 610 VZ 44.85 bkl 44.66 bkl Li, Xi-Rui verfasserin aut Palladacycle promoted asymmetric hydrophosphination of <ce:italic>α</ce:italic>,<ce:italic>β</ce:italic>-unsaturated sulfonyl fluorides 2019 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The first example of an enantioselective hydrophosphination reaction of ethenesulfonyl fluoride derivatives catalyzed by a phosphapalladacycle afforded chiral sulfonyl fluoride-derived phosphines in quantitative yields and enantioselectivities of up to 93% ee. Investigations revealed the importance of adjacent vacant sites within the active metal center for intramolecular nucleophilic attack to provide the functionalized phosphine. Hydrophosphination Elsevier Chiral phosphines Elsevier Sulfonyl fluorides Elsevier Cyclometalated complexes Elsevier Asymmetric catalysis Elsevier Chen, Houguang Jeremy oth Wang, Weifan oth Ma, Mengtao oth Chen, Yu oth Li, Yongxin oth Pullarkat, Sumod A. oth Leung, Pak-Hing oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:899 year:2019 day:30 month:10 pages:0 https://doi.org/10.1016/j.jorganchem.2019.120912 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 899 2019 30 1030 0 |
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10.1016/j.jorganchem.2019.120912 doi GBV00000000000746.pica (DE-627)ELV04788939X (ELSEVIER)S0022-328X(19)30355-9 DE-627 ger DE-627 rakwb eng 610 VZ 44.85 bkl 44.66 bkl Li, Xi-Rui verfasserin aut Palladacycle promoted asymmetric hydrophosphination of <ce:italic>α</ce:italic>,<ce:italic>β</ce:italic>-unsaturated sulfonyl fluorides 2019 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The first example of an enantioselective hydrophosphination reaction of ethenesulfonyl fluoride derivatives catalyzed by a phosphapalladacycle afforded chiral sulfonyl fluoride-derived phosphines in quantitative yields and enantioselectivities of up to 93% ee. Investigations revealed the importance of adjacent vacant sites within the active metal center for intramolecular nucleophilic attack to provide the functionalized phosphine. Hydrophosphination Elsevier Chiral phosphines Elsevier Sulfonyl fluorides Elsevier Cyclometalated complexes Elsevier Asymmetric catalysis Elsevier Chen, Houguang Jeremy oth Wang, Weifan oth Ma, Mengtao oth Chen, Yu oth Li, Yongxin oth Pullarkat, Sumod A. oth Leung, Pak-Hing oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:899 year:2019 day:30 month:10 pages:0 https://doi.org/10.1016/j.jorganchem.2019.120912 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 899 2019 30 1030 0 |
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10.1016/j.jorganchem.2019.120912 doi GBV00000000000746.pica (DE-627)ELV04788939X (ELSEVIER)S0022-328X(19)30355-9 DE-627 ger DE-627 rakwb eng 610 VZ 44.85 bkl 44.66 bkl Li, Xi-Rui verfasserin aut Palladacycle promoted asymmetric hydrophosphination of <ce:italic>α</ce:italic>,<ce:italic>β</ce:italic>-unsaturated sulfonyl fluorides 2019 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The first example of an enantioselective hydrophosphination reaction of ethenesulfonyl fluoride derivatives catalyzed by a phosphapalladacycle afforded chiral sulfonyl fluoride-derived phosphines in quantitative yields and enantioselectivities of up to 93% ee. Investigations revealed the importance of adjacent vacant sites within the active metal center for intramolecular nucleophilic attack to provide the functionalized phosphine. Hydrophosphination Elsevier Chiral phosphines Elsevier Sulfonyl fluorides Elsevier Cyclometalated complexes Elsevier Asymmetric catalysis Elsevier Chen, Houguang Jeremy oth Wang, Weifan oth Ma, Mengtao oth Chen, Yu oth Li, Yongxin oth Pullarkat, Sumod A. oth Leung, Pak-Hing oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:899 year:2019 day:30 month:10 pages:0 https://doi.org/10.1016/j.jorganchem.2019.120912 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 899 2019 30 1030 0 |
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10.1016/j.jorganchem.2019.120912 doi GBV00000000000746.pica (DE-627)ELV04788939X (ELSEVIER)S0022-328X(19)30355-9 DE-627 ger DE-627 rakwb eng 610 VZ 44.85 bkl 44.66 bkl Li, Xi-Rui verfasserin aut Palladacycle promoted asymmetric hydrophosphination of <ce:italic>α</ce:italic>,<ce:italic>β</ce:italic>-unsaturated sulfonyl fluorides 2019 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The first example of an enantioselective hydrophosphination reaction of ethenesulfonyl fluoride derivatives catalyzed by a phosphapalladacycle afforded chiral sulfonyl fluoride-derived phosphines in quantitative yields and enantioselectivities of up to 93% ee. Investigations revealed the importance of adjacent vacant sites within the active metal center for intramolecular nucleophilic attack to provide the functionalized phosphine. Hydrophosphination Elsevier Chiral phosphines Elsevier Sulfonyl fluorides Elsevier Cyclometalated complexes Elsevier Asymmetric catalysis Elsevier Chen, Houguang Jeremy oth Wang, Weifan oth Ma, Mengtao oth Chen, Yu oth Li, Yongxin oth Pullarkat, Sumod A. oth Leung, Pak-Hing oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:899 year:2019 day:30 month:10 pages:0 https://doi.org/10.1016/j.jorganchem.2019.120912 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 899 2019 30 1030 0 |
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10.1016/j.jorganchem.2019.120912 doi GBV00000000000746.pica (DE-627)ELV04788939X (ELSEVIER)S0022-328X(19)30355-9 DE-627 ger DE-627 rakwb eng 610 VZ 44.85 bkl 44.66 bkl Li, Xi-Rui verfasserin aut Palladacycle promoted asymmetric hydrophosphination of <ce:italic>α</ce:italic>,<ce:italic>β</ce:italic>-unsaturated sulfonyl fluorides 2019 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The first example of an enantioselective hydrophosphination reaction of ethenesulfonyl fluoride derivatives catalyzed by a phosphapalladacycle afforded chiral sulfonyl fluoride-derived phosphines in quantitative yields and enantioselectivities of up to 93% ee. Investigations revealed the importance of adjacent vacant sites within the active metal center for intramolecular nucleophilic attack to provide the functionalized phosphine. Hydrophosphination Elsevier Chiral phosphines Elsevier Sulfonyl fluorides Elsevier Cyclometalated complexes Elsevier Asymmetric catalysis Elsevier Chen, Houguang Jeremy oth Wang, Weifan oth Ma, Mengtao oth Chen, Yu oth Li, Yongxin oth Pullarkat, Sumod A. oth Leung, Pak-Hing oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:899 year:2019 day:30 month:10 pages:0 https://doi.org/10.1016/j.jorganchem.2019.120912 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 899 2019 30 1030 0 |
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Enthalten in The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial New York, NY [u.a.] volume:899 year:2019 day:30 month:10 pages:0 |
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10.1016/j.jorganchem.2019.120912 |
| dewey-full |
610 |
| title_sort |
palladacycle promoted asymmetric hydrophosphination of <ce:italic>α</ce:italic>,<ce:italic>β</ce:italic>-unsaturated sulfonyl fluorides |
| title_auth |
Palladacycle promoted asymmetric hydrophosphination of <ce:italic>α</ce:italic>,<ce:italic>β</ce:italic>-unsaturated sulfonyl fluorides |
| abstract |
The first example of an enantioselective hydrophosphination reaction of ethenesulfonyl fluoride derivatives catalyzed by a phosphapalladacycle afforded chiral sulfonyl fluoride-derived phosphines in quantitative yields and enantioselectivities of up to 93% ee. Investigations revealed the importance of adjacent vacant sites within the active metal center for intramolecular nucleophilic attack to provide the functionalized phosphine. |
| abstractGer |
The first example of an enantioselective hydrophosphination reaction of ethenesulfonyl fluoride derivatives catalyzed by a phosphapalladacycle afforded chiral sulfonyl fluoride-derived phosphines in quantitative yields and enantioselectivities of up to 93% ee. Investigations revealed the importance of adjacent vacant sites within the active metal center for intramolecular nucleophilic attack to provide the functionalized phosphine. |
| abstract_unstemmed |
The first example of an enantioselective hydrophosphination reaction of ethenesulfonyl fluoride derivatives catalyzed by a phosphapalladacycle afforded chiral sulfonyl fluoride-derived phosphines in quantitative yields and enantioselectivities of up to 93% ee. Investigations revealed the importance of adjacent vacant sites within the active metal center for intramolecular nucleophilic attack to provide the functionalized phosphine. |
| collection_details |
GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA |
| title_short |
Palladacycle promoted asymmetric hydrophosphination of <ce:italic>α</ce:italic>,<ce:italic>β</ce:italic>-unsaturated sulfonyl fluorides |
| url |
https://doi.org/10.1016/j.jorganchem.2019.120912 |
| remote_bool |
true |
| author2 |
Chen, Houguang Jeremy Wang, Weifan Ma, Mengtao Chen, Yu Li, Yongxin Pullarkat, Sumod A. Leung, Pak-Hing |
| author2Str |
Chen, Houguang Jeremy Wang, Weifan Ma, Mengtao Chen, Yu Li, Yongxin Pullarkat, Sumod A. Leung, Pak-Hing |
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| doi_str |
10.1016/j.jorganchem.2019.120912 |
| up_date |
2024-07-06T17:23:38.391Z |
| _version_ |
1803851261169106944 |
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