Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process
IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies ha...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Nguyen, Tam D. [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2020transfer abstract |
|---|
| Schlagwörter: |
|---|
| Umfang: |
10 |
|---|
| Übergeordnetes Werk: |
Enthalten in: External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs - Dedhia, Kavita ELSEVIER, 2018, official journal of the International Association for Hydrogen Energy, New York, NY [u.a.] |
|---|---|
| Übergeordnetes Werk: |
volume:45 ; year:2020 ; number:1 ; day:1 ; month:01 ; pages:46-55 ; extent:10 |
| Links: |
|---|
| DOI / URN: |
10.1016/j.ijhydene.2019.10.179 |
|---|
| Katalog-ID: |
ELV048850640 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | ELV048850640 | ||
| 003 | DE-627 | ||
| 005 | 20230626022922.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 200108s2020 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1016/j.ijhydene.2019.10.179 |2 doi | |
| 028 | 5 | 2 | |a /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000899.pica |
| 035 | |a (DE-627)ELV048850640 | ||
| 035 | |a (ELSEVIER)S0360-3199(19)34052-2 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 610 |q VZ |
| 084 | |a 44.94 |2 bkl | ||
| 100 | 1 | |a Nguyen, Tam D. |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process |
| 264 | 1 | |c 2020transfer abstract | |
| 300 | |a 10 | ||
| 336 | |a nicht spezifiziert |b zzz |2 rdacontent | ||
| 337 | |a nicht spezifiziert |b z |2 rdamedia | ||
| 338 | |a nicht spezifiziert |b zu |2 rdacarrier | ||
| 520 | |a IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. | ||
| 520 | |a IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. | ||
| 650 | 7 | |a Mixed RuxIr1-xO2 nano-catalyst |2 Elsevier | |
| 650 | 7 | |a Alkaline media |2 Elsevier | |
| 650 | 7 | |a Wet-chemical synthesis |2 Elsevier | |
| 650 | 7 | |a Oxygen evolution reaction |2 Elsevier | |
| 650 | 7 | |a Acidic media |2 Elsevier | |
| 700 | 1 | |a Nguyen, Hai H. |4 oth | |
| 700 | 1 | |a Dai, Chencheng |4 oth | |
| 700 | 1 | |a Wang, Jingxian |4 oth | |
| 700 | 1 | |a Scherer, Günther G. |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier |a Dedhia, Kavita ELSEVIER |t External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs |d 2018 |d official journal of the International Association for Hydrogen Energy |g New York, NY [u.a.] |w (DE-627)ELV000127019 |
| 773 | 1 | 8 | |g volume:45 |g year:2020 |g number:1 |g day:1 |g month:01 |g pages:46-55 |g extent:10 |
| 856 | 4 | 0 | |u https://doi.org/10.1016/j.ijhydene.2019.10.179 |3 Volltext |
| 912 | |a GBV_USEFLAG_U | ||
| 912 | |a GBV_ELV | ||
| 912 | |a SYSFLAG_U | ||
| 912 | |a SSG-OLC-PHA | ||
| 936 | b | k | |a 44.94 |j Hals-Nasen-Ohrenheilkunde |q VZ |
| 951 | |a AR | ||
| 952 | |d 45 |j 2020 |e 1 |b 1 |c 0101 |h 46-55 |g 10 | ||
| author_variant |
t d n td tdn |
|---|---|
| matchkey_str |
nguyentamdnguyenhaihdaichenchengwangjing:2020----:ciiynsaiiypiiainfui1onnctlsfrhoyeeouinec |
| hierarchy_sort_str |
2020transfer abstract |
| bklnumber |
44.94 |
| publishDate |
2020 |
| allfields |
10.1016/j.ijhydene.2019.10.179 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000899.pica (DE-627)ELV048850640 (ELSEVIER)S0360-3199(19)34052-2 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Nguyen, Tam D. verfasserin aut Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process 2020transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. Mixed RuxIr1-xO2 nano-catalyst Elsevier Alkaline media Elsevier Wet-chemical synthesis Elsevier Oxygen evolution reaction Elsevier Acidic media Elsevier Nguyen, Hai H. oth Dai, Chencheng oth Wang, Jingxian oth Scherer, Günther G. oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:45 year:2020 number:1 day:1 month:01 pages:46-55 extent:10 https://doi.org/10.1016/j.ijhydene.2019.10.179 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 45 2020 1 1 0101 46-55 10 |
| spelling |
10.1016/j.ijhydene.2019.10.179 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000899.pica (DE-627)ELV048850640 (ELSEVIER)S0360-3199(19)34052-2 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Nguyen, Tam D. verfasserin aut Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process 2020transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. Mixed RuxIr1-xO2 nano-catalyst Elsevier Alkaline media Elsevier Wet-chemical synthesis Elsevier Oxygen evolution reaction Elsevier Acidic media Elsevier Nguyen, Hai H. oth Dai, Chencheng oth Wang, Jingxian oth Scherer, Günther G. oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:45 year:2020 number:1 day:1 month:01 pages:46-55 extent:10 https://doi.org/10.1016/j.ijhydene.2019.10.179 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 45 2020 1 1 0101 46-55 10 |
| allfields_unstemmed |
10.1016/j.ijhydene.2019.10.179 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000899.pica (DE-627)ELV048850640 (ELSEVIER)S0360-3199(19)34052-2 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Nguyen, Tam D. verfasserin aut Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process 2020transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. Mixed RuxIr1-xO2 nano-catalyst Elsevier Alkaline media Elsevier Wet-chemical synthesis Elsevier Oxygen evolution reaction Elsevier Acidic media Elsevier Nguyen, Hai H. oth Dai, Chencheng oth Wang, Jingxian oth Scherer, Günther G. oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:45 year:2020 number:1 day:1 month:01 pages:46-55 extent:10 https://doi.org/10.1016/j.ijhydene.2019.10.179 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 45 2020 1 1 0101 46-55 10 |
| allfieldsGer |
10.1016/j.ijhydene.2019.10.179 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000899.pica (DE-627)ELV048850640 (ELSEVIER)S0360-3199(19)34052-2 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Nguyen, Tam D. verfasserin aut Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process 2020transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. Mixed RuxIr1-xO2 nano-catalyst Elsevier Alkaline media Elsevier Wet-chemical synthesis Elsevier Oxygen evolution reaction Elsevier Acidic media Elsevier Nguyen, Hai H. oth Dai, Chencheng oth Wang, Jingxian oth Scherer, Günther G. oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:45 year:2020 number:1 day:1 month:01 pages:46-55 extent:10 https://doi.org/10.1016/j.ijhydene.2019.10.179 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 45 2020 1 1 0101 46-55 10 |
| allfieldsSound |
10.1016/j.ijhydene.2019.10.179 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000899.pica (DE-627)ELV048850640 (ELSEVIER)S0360-3199(19)34052-2 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Nguyen, Tam D. verfasserin aut Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process 2020transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. Mixed RuxIr1-xO2 nano-catalyst Elsevier Alkaline media Elsevier Wet-chemical synthesis Elsevier Oxygen evolution reaction Elsevier Acidic media Elsevier Nguyen, Hai H. oth Dai, Chencheng oth Wang, Jingxian oth Scherer, Günther G. oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:45 year:2020 number:1 day:1 month:01 pages:46-55 extent:10 https://doi.org/10.1016/j.ijhydene.2019.10.179 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 45 2020 1 1 0101 46-55 10 |
| language |
English |
| source |
Enthalten in External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs New York, NY [u.a.] volume:45 year:2020 number:1 day:1 month:01 pages:46-55 extent:10 |
| sourceStr |
Enthalten in External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs New York, NY [u.a.] volume:45 year:2020 number:1 day:1 month:01 pages:46-55 extent:10 |
| format_phy_str_mv |
Article |
| bklname |
Hals-Nasen-Ohrenheilkunde |
| institution |
findex.gbv.de |
| topic_facet |
Mixed RuxIr1-xO2 nano-catalyst Alkaline media Wet-chemical synthesis Oxygen evolution reaction Acidic media |
| dewey-raw |
610 |
| isfreeaccess_bool |
false |
| container_title |
External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs |
| authorswithroles_txt_mv |
Nguyen, Tam D. @@aut@@ Nguyen, Hai H. @@oth@@ Dai, Chencheng @@oth@@ Wang, Jingxian @@oth@@ Scherer, Günther G. @@oth@@ |
| publishDateDaySort_date |
2020-01-01T00:00:00Z |
| hierarchy_top_id |
ELV000127019 |
| dewey-sort |
3610 |
| id |
ELV048850640 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV048850640</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230626022922.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">200108s2020 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.ijhydene.2019.10.179</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">/cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000899.pica</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV048850640</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0360-3199(19)34052-2</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">610</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">44.94</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Nguyen, Tam D.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2020transfer abstract</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">10</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs.</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Mixed RuxIr1-xO2 nano-catalyst</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Alkaline media</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Wet-chemical synthesis</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Oxygen evolution reaction</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Acidic media</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Nguyen, Hai H.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Dai, Chencheng</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Jingxian</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Scherer, Günther G.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="n">Elsevier</subfield><subfield code="a">Dedhia, Kavita ELSEVIER</subfield><subfield code="t">External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs</subfield><subfield code="d">2018</subfield><subfield code="d">official journal of the International Association for Hydrogen Energy</subfield><subfield code="g">New York, NY [u.a.]</subfield><subfield code="w">(DE-627)ELV000127019</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:45</subfield><subfield code="g">year:2020</subfield><subfield code="g">number:1</subfield><subfield code="g">day:1</subfield><subfield code="g">month:01</subfield><subfield code="g">pages:46-55</subfield><subfield code="g">extent:10</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.1016/j.ijhydene.2019.10.179</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">44.94</subfield><subfield code="j">Hals-Nasen-Ohrenheilkunde</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">45</subfield><subfield code="j">2020</subfield><subfield code="e">1</subfield><subfield code="b">1</subfield><subfield code="c">0101</subfield><subfield code="h">46-55</subfield><subfield code="g">10</subfield></datafield></record></collection>
|
| author |
Nguyen, Tam D. |
| spellingShingle |
Nguyen, Tam D. ddc 610 bkl 44.94 Elsevier Mixed RuxIr1-xO2 nano-catalyst Elsevier Alkaline media Elsevier Wet-chemical synthesis Elsevier Oxygen evolution reaction Elsevier Acidic media Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process |
| authorStr |
Nguyen, Tam D. |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)ELV000127019 |
| format |
electronic Article |
| dewey-ones |
610 - Medicine & health |
| delete_txt_mv |
keep |
| author_role |
aut |
| collection |
elsevier |
| remote_str |
true |
| illustrated |
Not Illustrated |
| topic_title |
610 VZ 44.94 bkl Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process Mixed RuxIr1-xO2 nano-catalyst Elsevier Alkaline media Elsevier Wet-chemical synthesis Elsevier Oxygen evolution reaction Elsevier Acidic media Elsevier |
| topic |
ddc 610 bkl 44.94 Elsevier Mixed RuxIr1-xO2 nano-catalyst Elsevier Alkaline media Elsevier Wet-chemical synthesis Elsevier Oxygen evolution reaction Elsevier Acidic media |
| topic_unstemmed |
ddc 610 bkl 44.94 Elsevier Mixed RuxIr1-xO2 nano-catalyst Elsevier Alkaline media Elsevier Wet-chemical synthesis Elsevier Oxygen evolution reaction Elsevier Acidic media |
| topic_browse |
ddc 610 bkl 44.94 Elsevier Mixed RuxIr1-xO2 nano-catalyst Elsevier Alkaline media Elsevier Wet-chemical synthesis Elsevier Oxygen evolution reaction Elsevier Acidic media |
| format_facet |
Elektronische Aufsätze Aufsätze Elektronische Ressource |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
zu |
| author2_variant |
h h n hh hhn c d cd j w jw g g s gg ggs |
| hierarchy_parent_title |
External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs |
| hierarchy_parent_id |
ELV000127019 |
| dewey-tens |
610 - Medicine & health |
| hierarchy_top_title |
External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)ELV000127019 |
| title |
Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process |
| ctrlnum |
(DE-627)ELV048850640 (ELSEVIER)S0360-3199(19)34052-2 |
| title_full |
Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process |
| author_sort |
Nguyen, Tam D. |
| journal |
External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs |
| journalStr |
External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
600 - Technology |
| recordtype |
marc |
| publishDateSort |
2020 |
| contenttype_str_mv |
zzz |
| container_start_page |
46 |
| author_browse |
Nguyen, Tam D. |
| container_volume |
45 |
| physical |
10 |
| class |
610 VZ 44.94 bkl |
| format_se |
Elektronische Aufsätze |
| author-letter |
Nguyen, Tam D. |
| doi_str_mv |
10.1016/j.ijhydene.2019.10.179 |
| dewey-full |
610 |
| title_sort |
activity and stability optimization of ruxir1-xo2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process |
| title_auth |
Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process |
| abstract |
IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. |
| abstractGer |
IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. |
| abstract_unstemmed |
IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs. |
| collection_details |
GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA |
| container_issue |
1 |
| title_short |
Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process |
| url |
https://doi.org/10.1016/j.ijhydene.2019.10.179 |
| remote_bool |
true |
| author2 |
Nguyen, Hai H. Dai, Chencheng Wang, Jingxian Scherer, Günther G. |
| author2Str |
Nguyen, Hai H. Dai, Chencheng Wang, Jingxian Scherer, Günther G. |
| ppnlink |
ELV000127019 |
| mediatype_str_mv |
z |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| author2_role |
oth oth oth oth |
| doi_str |
10.1016/j.ijhydene.2019.10.179 |
| up_date |
2024-07-06T19:57:24.947Z |
| _version_ |
1803860935913242624 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV048850640</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230626022922.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">200108s2020 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.ijhydene.2019.10.179</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">/cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000899.pica</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV048850640</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0360-3199(19)34052-2</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">610</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">44.94</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Nguyen, Tam D.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Activity and stability optimization of RuxIr1-xO2 nanocatalyst for the oxygen evolution reaction by tuning the synthetic process</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2020transfer abstract</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">10</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">IrO2 and RuO2 are known as two of the best catalysts for the oxygen evolution reaction (OER) in acidic electrolyte. It is reported that RuO2 has higher OER catalytic activity, while IrO2 possesses better electrochemical stability during the OER process in acid. Therefore, many combined strategies have been proposed to utilize the advantages of both IrO2 and RuO2 catalysts in water electrolysis applications. In this article we describe how, by tuning the wet-chemical synthesis process in which the Ir precursor is added after the synthesis of RuO2 nanoparticles (NPs) (two-step), the Ru0.5Ir0.5O2 NPs have been synthesized to improve the OER catalytic activity in both acidic and alkaline media. In detail, the specific OER activity of the Ru0.5Ir0.5O2 NPs (with a particle size of ca. 10 nm) is 48.9 μA cm−2 at an overpotential ŋ = 0.22 V (vs. RHE) and 21.7 μA cm−2 at ŋ = 0.27 V (vs. RHE) in 0.1 M HClO4 and 0.1 M KOH, respectively. These values are higher than those for the one-step (Ir0.5+Ru0.5)O2 NPs (obtained by contemporaneously adding both Ru and Ir precursors), which are 19.5 and 15.5 μA cm−2 at the same measuring conditions, respectively. Additionally, with more IrO2 component distributed on the particle surface, the two-step Ru0.5Ir0.5O2 NPs show better OER catalytic stability than RuO2 NPs.</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Mixed RuxIr1-xO2 nano-catalyst</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Alkaline media</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Wet-chemical synthesis</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Oxygen evolution reaction</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Acidic media</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Nguyen, Hai H.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Dai, Chencheng</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Jingxian</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Scherer, Günther G.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="n">Elsevier</subfield><subfield code="a">Dedhia, Kavita ELSEVIER</subfield><subfield code="t">External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs</subfield><subfield code="d">2018</subfield><subfield code="d">official journal of the International Association for Hydrogen Energy</subfield><subfield code="g">New York, NY [u.a.]</subfield><subfield code="w">(DE-627)ELV000127019</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:45</subfield><subfield code="g">year:2020</subfield><subfield code="g">number:1</subfield><subfield code="g">day:1</subfield><subfield code="g">month:01</subfield><subfield code="g">pages:46-55</subfield><subfield code="g">extent:10</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.1016/j.ijhydene.2019.10.179</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">44.94</subfield><subfield code="j">Hals-Nasen-Ohrenheilkunde</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">45</subfield><subfield code="j">2020</subfield><subfield code="e">1</subfield><subfield code="b">1</subfield><subfield code="c">0101</subfield><subfield code="h">46-55</subfield><subfield code="g">10</subfield></datafield></record></collection>
|
| score |
7.4013624 |