Electrical and electrochemical properties of imidazolium and phosphonium-based pNIPAAM ionogels
The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification fo...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Gil-González, Nerea [verfasserIn] |
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E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2020transfer abstract |
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| Übergeordnetes Werk: |
Enthalten in: Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch - Zhang, Lei ELSEVIER, 2018, the journal of the International Society of Electrochemistry (ISE), New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:345 ; year:2020 ; day:10 ; month:06 ; pages:0 |
| Links: |
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| DOI / URN: |
10.1016/j.electacta.2020.136167 |
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| 520 | |a The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. | ||
| 520 | |a The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. | ||
| 650 | 7 | |a Interdigitated electrodes (IDEs) |2 Elsevier | |
| 650 | 7 | |a Ionic liquid (IL) |2 Elsevier | |
| 650 | 7 | |a Ionogel (IO) |2 Elsevier | |
| 650 | 7 | |a Current rectification |2 Elsevier | |
| 650 | 7 | |a electrochemical window (ECW) |2 Elsevier | |
| 700 | 1 | |a Benito-Lopez, F. |4 oth | |
| 700 | 1 | |a Castaño, E. |4 oth | |
| 700 | 1 | |a Morant-Miñana, Maria C. |4 oth | |
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10.1016/j.electacta.2020.136167 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000995.pica (DE-627)ELV050148745 (ELSEVIER)S0013-4686(20)30559-4 DE-627 ger DE-627 rakwb eng 610 VZ 44.00 bkl Gil-González, Nerea verfasserin aut Electrical and electrochemical properties of imidazolium and phosphonium-based pNIPAAM ionogels 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. Interdigitated electrodes (IDEs) Elsevier Ionic liquid (IL) Elsevier Ionogel (IO) Elsevier Current rectification Elsevier electrochemical window (ECW) Elsevier Benito-Lopez, F. oth Castaño, E. oth Morant-Miñana, Maria C. oth Enthalten in Elsevier Zhang, Lei ELSEVIER Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch 2018 the journal of the International Society of Electrochemistry (ISE) New York, NY [u.a.] (DE-627)ELV001212419 volume:345 year:2020 day:10 month:06 pages:0 https://doi.org/10.1016/j.electacta.2020.136167 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.00 Medizin: Allgemeines VZ AR 345 2020 10 0610 0 |
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10.1016/j.electacta.2020.136167 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000995.pica (DE-627)ELV050148745 (ELSEVIER)S0013-4686(20)30559-4 DE-627 ger DE-627 rakwb eng 610 VZ 44.00 bkl Gil-González, Nerea verfasserin aut Electrical and electrochemical properties of imidazolium and phosphonium-based pNIPAAM ionogels 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. Interdigitated electrodes (IDEs) Elsevier Ionic liquid (IL) Elsevier Ionogel (IO) Elsevier Current rectification Elsevier electrochemical window (ECW) Elsevier Benito-Lopez, F. oth Castaño, E. oth Morant-Miñana, Maria C. oth Enthalten in Elsevier Zhang, Lei ELSEVIER Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch 2018 the journal of the International Society of Electrochemistry (ISE) New York, NY [u.a.] (DE-627)ELV001212419 volume:345 year:2020 day:10 month:06 pages:0 https://doi.org/10.1016/j.electacta.2020.136167 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.00 Medizin: Allgemeines VZ AR 345 2020 10 0610 0 |
| allfields_unstemmed |
10.1016/j.electacta.2020.136167 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000995.pica (DE-627)ELV050148745 (ELSEVIER)S0013-4686(20)30559-4 DE-627 ger DE-627 rakwb eng 610 VZ 44.00 bkl Gil-González, Nerea verfasserin aut Electrical and electrochemical properties of imidazolium and phosphonium-based pNIPAAM ionogels 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. Interdigitated electrodes (IDEs) Elsevier Ionic liquid (IL) Elsevier Ionogel (IO) Elsevier Current rectification Elsevier electrochemical window (ECW) Elsevier Benito-Lopez, F. oth Castaño, E. oth Morant-Miñana, Maria C. oth Enthalten in Elsevier Zhang, Lei ELSEVIER Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch 2018 the journal of the International Society of Electrochemistry (ISE) New York, NY [u.a.] (DE-627)ELV001212419 volume:345 year:2020 day:10 month:06 pages:0 https://doi.org/10.1016/j.electacta.2020.136167 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.00 Medizin: Allgemeines VZ AR 345 2020 10 0610 0 |
| allfieldsGer |
10.1016/j.electacta.2020.136167 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000995.pica (DE-627)ELV050148745 (ELSEVIER)S0013-4686(20)30559-4 DE-627 ger DE-627 rakwb eng 610 VZ 44.00 bkl Gil-González, Nerea verfasserin aut Electrical and electrochemical properties of imidazolium and phosphonium-based pNIPAAM ionogels 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. Interdigitated electrodes (IDEs) Elsevier Ionic liquid (IL) Elsevier Ionogel (IO) Elsevier Current rectification Elsevier electrochemical window (ECW) Elsevier Benito-Lopez, F. oth Castaño, E. oth Morant-Miñana, Maria C. oth Enthalten in Elsevier Zhang, Lei ELSEVIER Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch 2018 the journal of the International Society of Electrochemistry (ISE) New York, NY [u.a.] (DE-627)ELV001212419 volume:345 year:2020 day:10 month:06 pages:0 https://doi.org/10.1016/j.electacta.2020.136167 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.00 Medizin: Allgemeines VZ AR 345 2020 10 0610 0 |
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10.1016/j.electacta.2020.136167 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000995.pica (DE-627)ELV050148745 (ELSEVIER)S0013-4686(20)30559-4 DE-627 ger DE-627 rakwb eng 610 VZ 44.00 bkl Gil-González, Nerea verfasserin aut Electrical and electrochemical properties of imidazolium and phosphonium-based pNIPAAM ionogels 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. Interdigitated electrodes (IDEs) Elsevier Ionic liquid (IL) Elsevier Ionogel (IO) Elsevier Current rectification Elsevier electrochemical window (ECW) Elsevier Benito-Lopez, F. oth Castaño, E. oth Morant-Miñana, Maria C. oth Enthalten in Elsevier Zhang, Lei ELSEVIER Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch 2018 the journal of the International Society of Electrochemistry (ISE) New York, NY [u.a.] (DE-627)ELV001212419 volume:345 year:2020 day:10 month:06 pages:0 https://doi.org/10.1016/j.electacta.2020.136167 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.00 Medizin: Allgemeines VZ AR 345 2020 10 0610 0 |
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English |
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Enthalten in Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch New York, NY [u.a.] volume:345 year:2020 day:10 month:06 pages:0 |
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Enthalten in Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch New York, NY [u.a.] volume:345 year:2020 day:10 month:06 pages:0 |
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Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch |
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The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. 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Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch |
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Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch |
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Electrical and electrochemical properties of imidazolium and phosphonium-based pNIPAAM ionogels |
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The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. |
| abstractGer |
The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. |
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The electrical and electrochemical properties of two ionogel materials based on the poly(N-isopropylacrylamide) gel with 1-ethyl-3-methylimidazolium ethyl sulfate and trihexyltetradecyl-phosphonium dicyanamide ionic liquids are investigated. The current-voltage curves show a current rectification for both ionogels and ionic liquids after inducing ion adsorption on gold electrode surface. The polymer matrix of the ionogels mitigates ion adsorption, resulting in lower rectification ratios when comparing with the corresponding ionic liquids. The stability and the electrochemical window (ECW) of the ionogels are calculated from cyclic voltammograms and compared with the ones obtained for the ionic liquids. The widest electrochemical window is achieved by the phosphonium ionic liquid and its ionogel. Finally, the effect of the absorbed atmospheric water and the mutual coefficient diffusion of the redox active species inside the IO is calculated. This work widens the knowledge of the behavior of ionogel materials characterized on gold electrode interfaces. |
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Electrical and electrochemical properties of imidazolium and phosphonium-based pNIPAAM ionogels |
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