Futuristic advance and perspective of deep eutectic solvent for extractive desulfurization of fuel oil: A review
Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essent...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Majid, Mohd Faridzuan [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2020transfer abstract |
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| Übergeordnetes Werk: |
Enthalten in: Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects - Moreno-Cabezali, Belen Maria ELSEVIER, 2020, an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids, New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:306 ; year:2020 ; day:15 ; month:05 ; pages:0 |
| Links: |
|---|
| DOI / URN: |
10.1016/j.molliq.2020.112870 |
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| 520 | |a Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. | ||
| 520 | |a Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. | ||
| 700 | 1 | |a Mohd Zaid, Hayyiratul Fatimah |4 oth | |
| 700 | 1 | |a Kait, Chong Fai |4 oth | |
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| 700 | 1 | |a Yuan, Lim Chiau |4 oth | |
| 700 | 1 | |a Rajasuriyan, Sarrthesvaarni |4 oth | |
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10.1016/j.molliq.2020.112870 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001080.pica (DE-627)ELV050270621 (ELSEVIER)S0167-7322(19)36668-1 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Majid, Mohd Faridzuan verfasserin aut Futuristic advance and perspective of deep eutectic solvent for extractive desulfurization of fuel oil: A review 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. Mohd Zaid, Hayyiratul Fatimah oth Kait, Chong Fai oth Jumbri, Khairulazhar oth Yuan, Lim Chiau oth Rajasuriyan, Sarrthesvaarni oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:306 year:2020 day:15 month:05 pages:0 https://doi.org/10.1016/j.molliq.2020.112870 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 306 2020 15 0515 0 |
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10.1016/j.molliq.2020.112870 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001080.pica (DE-627)ELV050270621 (ELSEVIER)S0167-7322(19)36668-1 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Majid, Mohd Faridzuan verfasserin aut Futuristic advance and perspective of deep eutectic solvent for extractive desulfurization of fuel oil: A review 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. Mohd Zaid, Hayyiratul Fatimah oth Kait, Chong Fai oth Jumbri, Khairulazhar oth Yuan, Lim Chiau oth Rajasuriyan, Sarrthesvaarni oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:306 year:2020 day:15 month:05 pages:0 https://doi.org/10.1016/j.molliq.2020.112870 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 306 2020 15 0515 0 |
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10.1016/j.molliq.2020.112870 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001080.pica (DE-627)ELV050270621 (ELSEVIER)S0167-7322(19)36668-1 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Majid, Mohd Faridzuan verfasserin aut Futuristic advance and perspective of deep eutectic solvent for extractive desulfurization of fuel oil: A review 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. Mohd Zaid, Hayyiratul Fatimah oth Kait, Chong Fai oth Jumbri, Khairulazhar oth Yuan, Lim Chiau oth Rajasuriyan, Sarrthesvaarni oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:306 year:2020 day:15 month:05 pages:0 https://doi.org/10.1016/j.molliq.2020.112870 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 306 2020 15 0515 0 |
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10.1016/j.molliq.2020.112870 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001080.pica (DE-627)ELV050270621 (ELSEVIER)S0167-7322(19)36668-1 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Majid, Mohd Faridzuan verfasserin aut Futuristic advance and perspective of deep eutectic solvent for extractive desulfurization of fuel oil: A review 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. Mohd Zaid, Hayyiratul Fatimah oth Kait, Chong Fai oth Jumbri, Khairulazhar oth Yuan, Lim Chiau oth Rajasuriyan, Sarrthesvaarni oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:306 year:2020 day:15 month:05 pages:0 https://doi.org/10.1016/j.molliq.2020.112870 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 306 2020 15 0515 0 |
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10.1016/j.molliq.2020.112870 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001080.pica (DE-627)ELV050270621 (ELSEVIER)S0167-7322(19)36668-1 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Majid, Mohd Faridzuan verfasserin aut Futuristic advance and perspective of deep eutectic solvent for extractive desulfurization of fuel oil: A review 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. Mohd Zaid, Hayyiratul Fatimah oth Kait, Chong Fai oth Jumbri, Khairulazhar oth Yuan, Lim Chiau oth Rajasuriyan, Sarrthesvaarni oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:306 year:2020 day:15 month:05 pages:0 https://doi.org/10.1016/j.molliq.2020.112870 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 306 2020 15 0515 0 |
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Futuristic advance and perspective of deep eutectic solvent for extractive desulfurization of fuel oil: A review |
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Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. |
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Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. |
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Sulfur containing compounds (SCC) in fuel oil is now becoming a worldwide concern as it released sulfur dioxide, a toxic molecule which give detrimental impact towards human and environment. To encounter this, production of ultra-low sulfur fuel oil that fulfil Euro V standard (<10 ppm) is essential to eradicate the unfavourable consequences. Hydrodesulfurization is the conventional technique to remove SCC, however it is not worthy to use as it requires harsh operation conditions and costly. Moreover, some of the sterically-hindered SCC such as dibenzothiophene still remained in the oil. Non-conventional techniques to desulfurize SCC are currently being tested such as adsorption, biodesulfurization, extraction and oxidation. Research in desulfurization by means of extraction is widely progressed in the past decade using organic solvent and ionic liquids as extraction medium. However, the expensive costs of the solvent with questionable toxicity have driven researchers to explore the potential of deep eutectic solvent (DES) as alternative solvent. Compared to traditional solvent, DES is easy to synthesis, low cost and environmental-friendly. In this review, recent updates on the utilization of different type DES in extractive desulfurization is systematically classified and discussed. Eventually, the mechanism of extraction system is detailed to provide an insight at molecular level. Strategies to maximize the performance of extractive desulfurization are presented which focuses on the effective design of DES, integrative approach using oxidant and catalyst as well as usage of ultrasonic method. Several aspects of DES including DES and fuel solubility, influence of water, recylability and dearomatization towards extraction efficiency will be elaborated. Finally, challenges and future directions of the implementation of DES in extractive desulfurization are presented. |
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