Ni-doped Ni3S2 nanoflake intertexture grown on graphene oxide as sheet-like anode for high-performance lithium-ion batteries
Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using gra...
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| Autor*in: |
Xu, Jia-Lin [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2020transfer abstract |
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| Übergeordnetes Werk: |
Enthalten in: Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners - Jacobs, Jacquelyn A. ELSEVIER, 2017, JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics, Lausanne |
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| Übergeordnetes Werk: |
volume:835 ; year:2020 ; day:15 ; month:09 ; pages:0 |
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| DOI / URN: |
10.1016/j.jallcom.2020.155418 |
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| 520 | |a Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. | ||
| 520 | |a Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. | ||
| 650 | 7 | |a Lithium-ion batteries |2 Elsevier | |
| 650 | 7 | |a Ni3S2 |2 Elsevier | |
| 650 | 7 | |a Nanocomposite |2 Elsevier | |
| 650 | 7 | |a Ni-doped |2 Elsevier | |
| 650 | 7 | |a Sheet |2 Elsevier | |
| 700 | 1 | |a Liu, Long |4 oth | |
| 700 | 1 | |a Sun, Yong-Hui |4 oth | |
| 700 | 1 | |a Yan, Wen-Jie |4 oth | |
| 700 | 1 | |a Wang, Zeng-Rong |4 oth | |
| 700 | 1 | |a Sun, Qiang |4 oth | |
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10.1016/j.jallcom.2020.155418 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001033.pica (DE-627)ELV050410822 (ELSEVIER)S0925-8388(20)31781-3 DE-627 ger DE-627 rakwb eng 630 VZ Xu, Jia-Lin verfasserin aut Ni-doped Ni3S2 nanoflake intertexture grown on graphene oxide as sheet-like anode for high-performance lithium-ion batteries 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. Lithium-ion batteries Elsevier Ni3S2 Elsevier Nanocomposite Elsevier Ni-doped Elsevier Sheet Elsevier Liu, Long oth Sun, Yong-Hui oth Yan, Wen-Jie oth Wang, Zeng-Rong oth Sun, Qiang oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:835 year:2020 day:15 month:09 pages:0 https://doi.org/10.1016/j.jallcom.2020.155418 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 835 2020 15 0915 0 |
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10.1016/j.jallcom.2020.155418 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001033.pica (DE-627)ELV050410822 (ELSEVIER)S0925-8388(20)31781-3 DE-627 ger DE-627 rakwb eng 630 VZ Xu, Jia-Lin verfasserin aut Ni-doped Ni3S2 nanoflake intertexture grown on graphene oxide as sheet-like anode for high-performance lithium-ion batteries 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. Lithium-ion batteries Elsevier Ni3S2 Elsevier Nanocomposite Elsevier Ni-doped Elsevier Sheet Elsevier Liu, Long oth Sun, Yong-Hui oth Yan, Wen-Jie oth Wang, Zeng-Rong oth Sun, Qiang oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:835 year:2020 day:15 month:09 pages:0 https://doi.org/10.1016/j.jallcom.2020.155418 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 835 2020 15 0915 0 |
| allfields_unstemmed |
10.1016/j.jallcom.2020.155418 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001033.pica (DE-627)ELV050410822 (ELSEVIER)S0925-8388(20)31781-3 DE-627 ger DE-627 rakwb eng 630 VZ Xu, Jia-Lin verfasserin aut Ni-doped Ni3S2 nanoflake intertexture grown on graphene oxide as sheet-like anode for high-performance lithium-ion batteries 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. Lithium-ion batteries Elsevier Ni3S2 Elsevier Nanocomposite Elsevier Ni-doped Elsevier Sheet Elsevier Liu, Long oth Sun, Yong-Hui oth Yan, Wen-Jie oth Wang, Zeng-Rong oth Sun, Qiang oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:835 year:2020 day:15 month:09 pages:0 https://doi.org/10.1016/j.jallcom.2020.155418 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 835 2020 15 0915 0 |
| allfieldsGer |
10.1016/j.jallcom.2020.155418 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001033.pica (DE-627)ELV050410822 (ELSEVIER)S0925-8388(20)31781-3 DE-627 ger DE-627 rakwb eng 630 VZ Xu, Jia-Lin verfasserin aut Ni-doped Ni3S2 nanoflake intertexture grown on graphene oxide as sheet-like anode for high-performance lithium-ion batteries 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. Lithium-ion batteries Elsevier Ni3S2 Elsevier Nanocomposite Elsevier Ni-doped Elsevier Sheet Elsevier Liu, Long oth Sun, Yong-Hui oth Yan, Wen-Jie oth Wang, Zeng-Rong oth Sun, Qiang oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:835 year:2020 day:15 month:09 pages:0 https://doi.org/10.1016/j.jallcom.2020.155418 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 835 2020 15 0915 0 |
| allfieldsSound |
10.1016/j.jallcom.2020.155418 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001033.pica (DE-627)ELV050410822 (ELSEVIER)S0925-8388(20)31781-3 DE-627 ger DE-627 rakwb eng 630 VZ Xu, Jia-Lin verfasserin aut Ni-doped Ni3S2 nanoflake intertexture grown on graphene oxide as sheet-like anode for high-performance lithium-ion batteries 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. Lithium-ion batteries Elsevier Ni3S2 Elsevier Nanocomposite Elsevier Ni-doped Elsevier Sheet Elsevier Liu, Long oth Sun, Yong-Hui oth Yan, Wen-Jie oth Wang, Zeng-Rong oth Sun, Qiang oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:835 year:2020 day:15 month:09 pages:0 https://doi.org/10.1016/j.jallcom.2020.155418 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 835 2020 15 0915 0 |
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Enthalten in Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners Lausanne volume:835 year:2020 day:15 month:09 pages:0 |
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In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. 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Ni-doped Ni3S2 nanoflake intertexture grown on graphene oxide as sheet-like anode for high-performance lithium-ion batteries |
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Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. |
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Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. |
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Ni3S2 has become a promising anode material for lithium-ion batteries (LIBs) due to its favorable electrochemical conversion reaction, high theoretical specific capacity, and low cost. In this work, a nanoflake-assembled Ni-doped Ni3S2 sheet-like nanocomposite (Ni3S2–Ni–NF) was constructed using graphene oxide as the structure-directing agent by a simple two-step solvothermal reaction. The design of nanoflake subunit, sheet-like morphology, and Ni-doped Ni3S2 nanocomposite gains great promise for the application of LIBs by shortening the diffusion pathway of Li ions, improving the electrical connectivity as well as minimizing the electrode volume strain. As expected, the Ni3S2–Ni–NF nanocomposite exhibited excellent reversible capacities, high rate performance, and satisfactory cycling performance. For instance, reversible specific capacities of 741.8 mA h g−1 and 598.2 mA h g−1 can be retained after 120 cycles at current densities of 200 mA g−1 and 500 mA g−1, respectively. Furthermore, even at a very high current density of 1000 mA g−1, the discharge capacity remained as high as 497 mA h g−1. |
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Ni-doped Ni3S2 nanoflake intertexture grown on graphene oxide as sheet-like anode for high-performance lithium-ion batteries |
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Liu, Long Sun, Yong-Hui Yan, Wen-Jie Wang, Zeng-Rong Sun, Qiang |
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