Integrated glycerol- and ethanol-based chemical synthesis routes using Cu–Mg–Al LDH-derived catalysts without external hydrogen: Intervention of bio-ethanol co-fed with glycerol
In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of gl...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Kuljiraseth, Jirayu [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2020transfer abstract |
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| Schlagwörter: |
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| Umfang: |
11 |
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| Übergeordnetes Werk: |
Enthalten in: Technologies and practice of CO - HU, Yongle ELSEVIER, 2019, an international journal : the official journal of WREN, The World Renewable Energy Network, Amsterdam [u.a.] |
|---|---|
| Übergeordnetes Werk: |
volume:156 ; year:2020 ; pages:975-985 ; extent:11 |
| Links: |
|---|
| DOI / URN: |
10.1016/j.renene.2020.04.151 |
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ELV050576372 |
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| 100 | 1 | |a Kuljiraseth, Jirayu |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Integrated glycerol- and ethanol-based chemical synthesis routes using Cu–Mg–Al LDH-derived catalysts without external hydrogen: Intervention of bio-ethanol co-fed with glycerol |
| 264 | 1 | |c 2020transfer abstract | |
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| 520 | |a In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. | ||
| 520 | |a In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. | ||
| 650 | 7 | |a 1,2-Propandiol |2 Elsevier | |
| 650 | 7 | |a Hydrogenolysis |2 Elsevier | |
| 650 | 7 | |a Glycerol |2 Elsevier | |
| 650 | 7 | |a Bio-ethanol |2 Elsevier | |
| 650 | 7 | |a Ethyl lactate |2 Elsevier | |
| 700 | 1 | |a Kumpradit, Thanakorn |4 oth | |
| 700 | 1 | |a Leungcharoenwattana, Tuangrat |4 oth | |
| 700 | 1 | |a Poo-arporn, Yingyot |4 oth | |
| 700 | 1 | |a Jitkarnka, Sirirat |4 oth | |
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10.1016/j.renene.2020.04.151 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001065.pica (DE-627)ELV050576372 (ELSEVIER)S0960-1481(20)30689-3 DE-627 ger DE-627 rakwb eng Kuljiraseth, Jirayu verfasserin aut Integrated glycerol- and ethanol-based chemical synthesis routes using Cu–Mg–Al LDH-derived catalysts without external hydrogen: Intervention of bio-ethanol co-fed with glycerol 2020transfer abstract 11 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. 1,2-Propandiol Elsevier Hydrogenolysis Elsevier Glycerol Elsevier Bio-ethanol Elsevier Ethyl lactate Elsevier Kumpradit, Thanakorn oth Leungcharoenwattana, Tuangrat oth Poo-arporn, Yingyot oth Jitkarnka, Sirirat oth Enthalten in Elsevier Science HU, Yongle ELSEVIER Technologies and practice of CO 2019 an international journal : the official journal of WREN, The World Renewable Energy Network Amsterdam [u.a.] (DE-627)ELV002723662 volume:156 year:2020 pages:975-985 extent:11 https://doi.org/10.1016/j.renene.2020.04.151 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U AR 156 2020 975-985 11 |
| spelling |
10.1016/j.renene.2020.04.151 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001065.pica (DE-627)ELV050576372 (ELSEVIER)S0960-1481(20)30689-3 DE-627 ger DE-627 rakwb eng Kuljiraseth, Jirayu verfasserin aut Integrated glycerol- and ethanol-based chemical synthesis routes using Cu–Mg–Al LDH-derived catalysts without external hydrogen: Intervention of bio-ethanol co-fed with glycerol 2020transfer abstract 11 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. 1,2-Propandiol Elsevier Hydrogenolysis Elsevier Glycerol Elsevier Bio-ethanol Elsevier Ethyl lactate Elsevier Kumpradit, Thanakorn oth Leungcharoenwattana, Tuangrat oth Poo-arporn, Yingyot oth Jitkarnka, Sirirat oth Enthalten in Elsevier Science HU, Yongle ELSEVIER Technologies and practice of CO 2019 an international journal : the official journal of WREN, The World Renewable Energy Network Amsterdam [u.a.] (DE-627)ELV002723662 volume:156 year:2020 pages:975-985 extent:11 https://doi.org/10.1016/j.renene.2020.04.151 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U AR 156 2020 975-985 11 |
| allfields_unstemmed |
10.1016/j.renene.2020.04.151 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001065.pica (DE-627)ELV050576372 (ELSEVIER)S0960-1481(20)30689-3 DE-627 ger DE-627 rakwb eng Kuljiraseth, Jirayu verfasserin aut Integrated glycerol- and ethanol-based chemical synthesis routes using Cu–Mg–Al LDH-derived catalysts without external hydrogen: Intervention of bio-ethanol co-fed with glycerol 2020transfer abstract 11 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. 1,2-Propandiol Elsevier Hydrogenolysis Elsevier Glycerol Elsevier Bio-ethanol Elsevier Ethyl lactate Elsevier Kumpradit, Thanakorn oth Leungcharoenwattana, Tuangrat oth Poo-arporn, Yingyot oth Jitkarnka, Sirirat oth Enthalten in Elsevier Science HU, Yongle ELSEVIER Technologies and practice of CO 2019 an international journal : the official journal of WREN, The World Renewable Energy Network Amsterdam [u.a.] (DE-627)ELV002723662 volume:156 year:2020 pages:975-985 extent:11 https://doi.org/10.1016/j.renene.2020.04.151 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U AR 156 2020 975-985 11 |
| allfieldsGer |
10.1016/j.renene.2020.04.151 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001065.pica (DE-627)ELV050576372 (ELSEVIER)S0960-1481(20)30689-3 DE-627 ger DE-627 rakwb eng Kuljiraseth, Jirayu verfasserin aut Integrated glycerol- and ethanol-based chemical synthesis routes using Cu–Mg–Al LDH-derived catalysts without external hydrogen: Intervention of bio-ethanol co-fed with glycerol 2020transfer abstract 11 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. 1,2-Propandiol Elsevier Hydrogenolysis Elsevier Glycerol Elsevier Bio-ethanol Elsevier Ethyl lactate Elsevier Kumpradit, Thanakorn oth Leungcharoenwattana, Tuangrat oth Poo-arporn, Yingyot oth Jitkarnka, Sirirat oth Enthalten in Elsevier Science HU, Yongle ELSEVIER Technologies and practice of CO 2019 an international journal : the official journal of WREN, The World Renewable Energy Network Amsterdam [u.a.] (DE-627)ELV002723662 volume:156 year:2020 pages:975-985 extent:11 https://doi.org/10.1016/j.renene.2020.04.151 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U AR 156 2020 975-985 11 |
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10.1016/j.renene.2020.04.151 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001065.pica (DE-627)ELV050576372 (ELSEVIER)S0960-1481(20)30689-3 DE-627 ger DE-627 rakwb eng Kuljiraseth, Jirayu verfasserin aut Integrated glycerol- and ethanol-based chemical synthesis routes using Cu–Mg–Al LDH-derived catalysts without external hydrogen: Intervention of bio-ethanol co-fed with glycerol 2020transfer abstract 11 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. 1,2-Propandiol Elsevier Hydrogenolysis Elsevier Glycerol Elsevier Bio-ethanol Elsevier Ethyl lactate Elsevier Kumpradit, Thanakorn oth Leungcharoenwattana, Tuangrat oth Poo-arporn, Yingyot oth Jitkarnka, Sirirat oth Enthalten in Elsevier Science HU, Yongle ELSEVIER Technologies and practice of CO 2019 an international journal : the official journal of WREN, The World Renewable Energy Network Amsterdam [u.a.] (DE-627)ELV002723662 volume:156 year:2020 pages:975-985 extent:11 https://doi.org/10.1016/j.renene.2020.04.151 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U AR 156 2020 975-985 11 |
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Kuljiraseth, Jirayu @@aut@@ Kumpradit, Thanakorn @@oth@@ Leungcharoenwattana, Tuangrat @@oth@@ Poo-arporn, Yingyot @@oth@@ Jitkarnka, Sirirat @@oth@@ |
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However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. 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Kuljiraseth, Jirayu Elsevier 1,2-Propandiol Elsevier Hydrogenolysis Elsevier Glycerol Elsevier Bio-ethanol Elsevier Ethyl lactate Integrated glycerol- and ethanol-based chemical synthesis routes using Cu–Mg–Al LDH-derived catalysts without external hydrogen: Intervention of bio-ethanol co-fed with glycerol |
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Integrated glycerol- and ethanol-based chemical synthesis routes using Cu–Mg–Al LDH-derived catalysts without external hydrogen: Intervention of bio-ethanol co-fed with glycerol 1,2-Propandiol Elsevier Hydrogenolysis Elsevier Glycerol Elsevier Bio-ethanol Elsevier Ethyl lactate Elsevier |
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integrated glycerol- and ethanol-based chemical synthesis routes using cu–mg–al ldh-derived catalysts without external hydrogen: intervention of bio-ethanol co-fed with glycerol |
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Integrated glycerol- and ethanol-based chemical synthesis routes using Cu–Mg–Al LDH-derived catalysts without external hydrogen: Intervention of bio-ethanol co-fed with glycerol |
| abstract |
In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. |
| abstractGer |
In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. |
| abstract_unstemmed |
In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed. |
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Integrated glycerol- and ethanol-based chemical synthesis routes using Cu–Mg–Al LDH-derived catalysts without external hydrogen: Intervention of bio-ethanol co-fed with glycerol |
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