Influence of the alkyl chain cation position on thermal behaviour: (1,2) and (1,4) pyridinium Bis(trifluoromethylsulfonyl)imide - Based ionic liquids
This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing...
Ausführliche Beschreibung
Autor*in: |
Gómez, Elena [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2020transfer abstract |
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Übergeordnetes Werk: |
Enthalten in: Fabrication and compressive behaviour of an aluminium foam composite - Li, Yong-gang ELSEVIER, 2015, an international journal, New York, NY [u.a.] |
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Übergeordnetes Werk: |
volume:519 ; year:2020 ; day:1 ; month:09 ; pages:0 |
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DOI / URN: |
10.1016/j.fluid.2020.112658 |
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ELV050698532 |
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520 | |a This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. | ||
520 | |a This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. | ||
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700 | 1 | |a Requejo, Patricia F. |4 oth | |
700 | 1 | |a Domínguez, Ángeles |4 oth | |
700 | 1 | |a Macedo, Eugénia A. |4 oth | |
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10.1016/j.fluid.2020.112658 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001042.pica (DE-627)ELV050698532 (ELSEVIER)S0378-3812(20)30204-1 DE-627 ger DE-627 rakwb eng 670 VZ 540 VZ 630 VZ Gómez, Elena verfasserin aut Influence of the alkyl chain cation position on thermal behaviour: (1,2) and (1,4) pyridinium Bis(trifluoromethylsulfonyl)imide - Based ionic liquids 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. DSC Elsevier Pyridinium Elsevier Thermal behavior Elsevier Ionic liquids Elsevier Heat capacity Elsevier Requejo, Patricia F. oth Domínguez, Ángeles oth Macedo, Eugénia A. oth Enthalten in Science Direct Li, Yong-gang ELSEVIER Fabrication and compressive behaviour of an aluminium foam composite 2015 an international journal New York, NY [u.a.] (DE-627)ELV013241125 volume:519 year:2020 day:1 month:09 pages:0 https://doi.org/10.1016/j.fluid.2020.112658 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_31 GBV_ILN_40 GBV_ILN_100 GBV_ILN_136 AR 519 2020 1 0901 0 |
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10.1016/j.fluid.2020.112658 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001042.pica (DE-627)ELV050698532 (ELSEVIER)S0378-3812(20)30204-1 DE-627 ger DE-627 rakwb eng 670 VZ 540 VZ 630 VZ Gómez, Elena verfasserin aut Influence of the alkyl chain cation position on thermal behaviour: (1,2) and (1,4) pyridinium Bis(trifluoromethylsulfonyl)imide - Based ionic liquids 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. DSC Elsevier Pyridinium Elsevier Thermal behavior Elsevier Ionic liquids Elsevier Heat capacity Elsevier Requejo, Patricia F. oth Domínguez, Ángeles oth Macedo, Eugénia A. oth Enthalten in Science Direct Li, Yong-gang ELSEVIER Fabrication and compressive behaviour of an aluminium foam composite 2015 an international journal New York, NY [u.a.] (DE-627)ELV013241125 volume:519 year:2020 day:1 month:09 pages:0 https://doi.org/10.1016/j.fluid.2020.112658 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_31 GBV_ILN_40 GBV_ILN_100 GBV_ILN_136 AR 519 2020 1 0901 0 |
allfields_unstemmed |
10.1016/j.fluid.2020.112658 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001042.pica (DE-627)ELV050698532 (ELSEVIER)S0378-3812(20)30204-1 DE-627 ger DE-627 rakwb eng 670 VZ 540 VZ 630 VZ Gómez, Elena verfasserin aut Influence of the alkyl chain cation position on thermal behaviour: (1,2) and (1,4) pyridinium Bis(trifluoromethylsulfonyl)imide - Based ionic liquids 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. DSC Elsevier Pyridinium Elsevier Thermal behavior Elsevier Ionic liquids Elsevier Heat capacity Elsevier Requejo, Patricia F. oth Domínguez, Ángeles oth Macedo, Eugénia A. oth Enthalten in Science Direct Li, Yong-gang ELSEVIER Fabrication and compressive behaviour of an aluminium foam composite 2015 an international journal New York, NY [u.a.] (DE-627)ELV013241125 volume:519 year:2020 day:1 month:09 pages:0 https://doi.org/10.1016/j.fluid.2020.112658 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_31 GBV_ILN_40 GBV_ILN_100 GBV_ILN_136 AR 519 2020 1 0901 0 |
allfieldsGer |
10.1016/j.fluid.2020.112658 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001042.pica (DE-627)ELV050698532 (ELSEVIER)S0378-3812(20)30204-1 DE-627 ger DE-627 rakwb eng 670 VZ 540 VZ 630 VZ Gómez, Elena verfasserin aut Influence of the alkyl chain cation position on thermal behaviour: (1,2) and (1,4) pyridinium Bis(trifluoromethylsulfonyl)imide - Based ionic liquids 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. DSC Elsevier Pyridinium Elsevier Thermal behavior Elsevier Ionic liquids Elsevier Heat capacity Elsevier Requejo, Patricia F. oth Domínguez, Ángeles oth Macedo, Eugénia A. oth Enthalten in Science Direct Li, Yong-gang ELSEVIER Fabrication and compressive behaviour of an aluminium foam composite 2015 an international journal New York, NY [u.a.] (DE-627)ELV013241125 volume:519 year:2020 day:1 month:09 pages:0 https://doi.org/10.1016/j.fluid.2020.112658 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_31 GBV_ILN_40 GBV_ILN_100 GBV_ILN_136 AR 519 2020 1 0901 0 |
allfieldsSound |
10.1016/j.fluid.2020.112658 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001042.pica (DE-627)ELV050698532 (ELSEVIER)S0378-3812(20)30204-1 DE-627 ger DE-627 rakwb eng 670 VZ 540 VZ 630 VZ Gómez, Elena verfasserin aut Influence of the alkyl chain cation position on thermal behaviour: (1,2) and (1,4) pyridinium Bis(trifluoromethylsulfonyl)imide - Based ionic liquids 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. DSC Elsevier Pyridinium Elsevier Thermal behavior Elsevier Ionic liquids Elsevier Heat capacity Elsevier Requejo, Patricia F. oth Domínguez, Ángeles oth Macedo, Eugénia A. oth Enthalten in Science Direct Li, Yong-gang ELSEVIER Fabrication and compressive behaviour of an aluminium foam composite 2015 an international journal New York, NY [u.a.] (DE-627)ELV013241125 volume:519 year:2020 day:1 month:09 pages:0 https://doi.org/10.1016/j.fluid.2020.112658 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_31 GBV_ILN_40 GBV_ILN_100 GBV_ILN_136 AR 519 2020 1 0901 0 |
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Enthalten in Fabrication and compressive behaviour of an aluminium foam composite New York, NY [u.a.] volume:519 year:2020 day:1 month:09 pages:0 |
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The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. 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Influence of the alkyl chain cation position on thermal behaviour: (1,2) and (1,4) pyridinium Bis(trifluoromethylsulfonyl)imide - Based ionic liquids |
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influence of the alkyl chain cation position on thermal behaviour: (1,2) and (1,4) pyridinium bis(trifluoromethylsulfonyl)imide - based ionic liquids |
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Influence of the alkyl chain cation position on thermal behaviour: (1,2) and (1,4) pyridinium Bis(trifluoromethylsulfonyl)imide - Based ionic liquids |
abstract |
This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. |
abstractGer |
This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. |
abstract_unstemmed |
This work focuses on the influence of the position of the alkyl chain cation on the thermal behavior and on the values of the heat capacities, for ionic liquids with pyridinium cation and bis(trifluoromethylsulfonyl)imide anion To achieve this objective, thermal properties such as, melting, freezing, cold crystallization and glass transition temperatures and heat capacities (in the temperature range from 293.15K to 363.15K) have been experimentally determined for several ionic liquids using differential scanning calorimetry. The ionic liquids chosen were: 1-alkyl-2-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,2) CnMpyNTf2 (n = 2,3,4) and 1-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,4) CnMpyNTf2 (n = 2,3,4). The results obtained were compared with those published by the group in a previous paper concerning 1-alkyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide (1,3) CnMpyNTf2 (n = 2,3,4) ionic liquids. Moreover, the results from this essay were also compared with literature values. Three thermal behaviors were found for the studied ionic liquids: those characterized by the presence only glass transition, those presenting only freezing and melting transitions and those with subcooling phenomenon. |
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Influence of the alkyl chain cation position on thermal behaviour: (1,2) and (1,4) pyridinium Bis(trifluoromethylsulfonyl)imide - Based ionic liquids |
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