Systematic study of synthesizing various heteroatom-substituted rhodamines from diaryl ether analogues
The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Deng, Fei [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2020transfer abstract |
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| Übergeordnetes Werk: |
Enthalten in: Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training - An, Chen-Chi ELSEVIER, 2017, Amsterdam [u.a.] |
|---|---|
| Übergeordnetes Werk: |
volume:240 ; year:2020 ; day:15 ; month:10 ; pages:0 |
| Links: |
|---|
| DOI / URN: |
10.1016/j.saa.2020.118466 |
|---|
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ELV050905597 |
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| 520 | |a The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. | ||
| 520 | |a The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. | ||
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10.1016/j.saa.2020.118466 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001080.pica (DE-627)ELV050905597 (ELSEVIER)S1386-1425(20)30444-3 DE-627 ger DE-627 rakwb eng 660 VZ 50.21 bkl Deng, Fei verfasserin aut Systematic study of synthesizing various heteroatom-substituted rhodamines from diaryl ether analogues 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. Liu, Limin oth Huang, Wei oth Huang, Chunfang oth Qiao, Qinglong oth Xu, Zhaochao oth Enthalten in Elsevier Science An, Chen-Chi ELSEVIER Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training 2017 Amsterdam [u.a.] (DE-627)ELV000384860 volume:240 year:2020 day:15 month:10 pages:0 https://doi.org/10.1016/j.saa.2020.118466 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 50.21 Messtechnik VZ AR 240 2020 15 1015 0 |
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10.1016/j.saa.2020.118466 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001080.pica (DE-627)ELV050905597 (ELSEVIER)S1386-1425(20)30444-3 DE-627 ger DE-627 rakwb eng 660 VZ 50.21 bkl Deng, Fei verfasserin aut Systematic study of synthesizing various heteroatom-substituted rhodamines from diaryl ether analogues 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. Liu, Limin oth Huang, Wei oth Huang, Chunfang oth Qiao, Qinglong oth Xu, Zhaochao oth Enthalten in Elsevier Science An, Chen-Chi ELSEVIER Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training 2017 Amsterdam [u.a.] (DE-627)ELV000384860 volume:240 year:2020 day:15 month:10 pages:0 https://doi.org/10.1016/j.saa.2020.118466 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 50.21 Messtechnik VZ AR 240 2020 15 1015 0 |
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10.1016/j.saa.2020.118466 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001080.pica (DE-627)ELV050905597 (ELSEVIER)S1386-1425(20)30444-3 DE-627 ger DE-627 rakwb eng 660 VZ 50.21 bkl Deng, Fei verfasserin aut Systematic study of synthesizing various heteroatom-substituted rhodamines from diaryl ether analogues 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. Liu, Limin oth Huang, Wei oth Huang, Chunfang oth Qiao, Qinglong oth Xu, Zhaochao oth Enthalten in Elsevier Science An, Chen-Chi ELSEVIER Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training 2017 Amsterdam [u.a.] (DE-627)ELV000384860 volume:240 year:2020 day:15 month:10 pages:0 https://doi.org/10.1016/j.saa.2020.118466 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 50.21 Messtechnik VZ AR 240 2020 15 1015 0 |
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10.1016/j.saa.2020.118466 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001080.pica (DE-627)ELV050905597 (ELSEVIER)S1386-1425(20)30444-3 DE-627 ger DE-627 rakwb eng 660 VZ 50.21 bkl Deng, Fei verfasserin aut Systematic study of synthesizing various heteroatom-substituted rhodamines from diaryl ether analogues 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. Liu, Limin oth Huang, Wei oth Huang, Chunfang oth Qiao, Qinglong oth Xu, Zhaochao oth Enthalten in Elsevier Science An, Chen-Chi ELSEVIER Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training 2017 Amsterdam [u.a.] (DE-627)ELV000384860 volume:240 year:2020 day:15 month:10 pages:0 https://doi.org/10.1016/j.saa.2020.118466 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 50.21 Messtechnik VZ AR 240 2020 15 1015 0 |
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10.1016/j.saa.2020.118466 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001080.pica (DE-627)ELV050905597 (ELSEVIER)S1386-1425(20)30444-3 DE-627 ger DE-627 rakwb eng 660 VZ 50.21 bkl Deng, Fei verfasserin aut Systematic study of synthesizing various heteroatom-substituted rhodamines from diaryl ether analogues 2020transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. Liu, Limin oth Huang, Wei oth Huang, Chunfang oth Qiao, Qinglong oth Xu, Zhaochao oth Enthalten in Elsevier Science An, Chen-Chi ELSEVIER Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training 2017 Amsterdam [u.a.] (DE-627)ELV000384860 volume:240 year:2020 day:15 month:10 pages:0 https://doi.org/10.1016/j.saa.2020.118466 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 50.21 Messtechnik VZ AR 240 2020 15 1015 0 |
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Deng, Fei |
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Deng, Fei ddc 660 bkl 50.21 Systematic study of synthesizing various heteroatom-substituted rhodamines from diaryl ether analogues |
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660 VZ 50.21 bkl Systematic study of synthesizing various heteroatom-substituted rhodamines from diaryl ether analogues |
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Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training |
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Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training |
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Systematic study of synthesizing various heteroatom-substituted rhodamines from diaryl ether analogues |
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Systematic study of synthesizing various heteroatom-substituted rhodamines from diaryl ether analogues |
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Deng, Fei |
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Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training |
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Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training |
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10.1016/j.saa.2020.118466 |
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systematic study of synthesizing various heteroatom-substituted rhodamines from diaryl ether analogues |
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Systematic study of synthesizing various heteroatom-substituted rhodamines from diaryl ether analogues |
| abstract |
The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. |
| abstractGer |
The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. |
| abstract_unstemmed |
The dye rhodamine, as the most popular scaffold to construct fluorescent labels and probes, has been explored extensively on its structure-fluorescence relationships. Particularly, the replacement of the oxygen atom in the 10th position with heteroatoms obtained various new rhodamines with improved photophysical properties, such as brightness, photostability, red-shifted emission and fluorogenicity. However, the applications of heteroatom-substituted rhodamines have been hindered by difficult synthetic routes. Herein, we explored the condensation strategy of diaryl ether analogues and o-tolualdehyde to synthesize various heteroatom-substituted rhodamines. We found that the electron property and steric effect in the rhodamine 10th position determined the synthetic yield. It's concluded that this condensation method was more suitable for the synthesis of heteroatom-substituted rhodamines with small or electron-donating groups like rhodamine, S-rhodamine and Si-rhodamine. We hope these results will benefit the design and synthesis of heteroatom-substituted rhodamines. |
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Systematic study of synthesizing various heteroatom-substituted rhodamines from diaryl ether analogues |
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https://doi.org/10.1016/j.saa.2020.118466 |
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Liu, Limin Huang, Wei Huang, Chunfang Qiao, Qinglong Xu, Zhaochao |
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Liu, Limin Huang, Wei Huang, Chunfang Qiao, Qinglong Xu, Zhaochao |
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