A novel photochromic ceramics with reversible luminescence modulation and light bleaching behavior: Sm3+-doped KSr2Nb5O15
A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 3...
Ausführliche Beschreibung
Autor*in: |
Cao, Shuyao [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2020transfer abstract |
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12 |
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Übergeordnetes Werk: |
Enthalten in: Improved differential evolution for RSSD-based localization in Gaussian mixture noise - Zhang, Yuanyuan ELSEVIER, 2023, Amsterdam [u.a.] |
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Übergeordnetes Werk: |
volume:40 ; year:2020 ; number:15 ; pages:6061-6072 ; extent:12 |
Links: |
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DOI / URN: |
10.1016/j.jeurceramsoc.2020.07.030 |
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Katalog-ID: |
ELV051075288 |
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245 | 1 | 0 | |a A novel photochromic ceramics with reversible luminescence modulation and light bleaching behavior: Sm3+-doped KSr2Nb5O15 |
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520 | |a A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. | ||
520 | |a A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. | ||
650 | 7 | |a Light bleaching |2 Elsevier | |
650 | 7 | |a Sintering atmosphere |2 Elsevier | |
650 | 7 | |a Photochromism |2 Elsevier | |
650 | 7 | |a Luminescence modulation |2 Elsevier | |
650 | 7 | |a Tetragonal tungsten bronze structure |2 Elsevier | |
700 | 1 | |a Chen, Qian |4 oth | |
700 | 1 | |a Liu, Junting |4 oth | |
700 | 1 | |a Wu, Changying |4 oth | |
700 | 1 | |a Li, Leilei |4 oth | |
700 | 1 | |a Xu, Jie |4 oth | |
700 | 1 | |a Cheng, Guanghua |4 oth | |
700 | 1 | |a Gao, Feng |4 oth | |
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10.1016/j.jeurceramsoc.2020.07.030 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001229.pica (DE-627)ELV051075288 (ELSEVIER)S0955-2219(20)30585-9 DE-627 ger DE-627 rakwb eng 004 VZ 54.00 bkl Cao, Shuyao verfasserin aut A novel photochromic ceramics with reversible luminescence modulation and light bleaching behavior: Sm3+-doped KSr2Nb5O15 2020transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. Light bleaching Elsevier Sintering atmosphere Elsevier Photochromism Elsevier Luminescence modulation Elsevier Tetragonal tungsten bronze structure Elsevier Chen, Qian oth Liu, Junting oth Wu, Changying oth Li, Leilei oth Xu, Jie oth Cheng, Guanghua oth Gao, Feng oth Enthalten in Elsevier Science Zhang, Yuanyuan ELSEVIER Improved differential evolution for RSSD-based localization in Gaussian mixture noise 2023 Amsterdam [u.a.] (DE-627)ELV009961755 volume:40 year:2020 number:15 pages:6061-6072 extent:12 https://doi.org/10.1016/j.jeurceramsoc.2020.07.030 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.00 Informatik: Allgemeines VZ AR 40 2020 15 6061-6072 12 |
spelling |
10.1016/j.jeurceramsoc.2020.07.030 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001229.pica (DE-627)ELV051075288 (ELSEVIER)S0955-2219(20)30585-9 DE-627 ger DE-627 rakwb eng 004 VZ 54.00 bkl Cao, Shuyao verfasserin aut A novel photochromic ceramics with reversible luminescence modulation and light bleaching behavior: Sm3+-doped KSr2Nb5O15 2020transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. Light bleaching Elsevier Sintering atmosphere Elsevier Photochromism Elsevier Luminescence modulation Elsevier Tetragonal tungsten bronze structure Elsevier Chen, Qian oth Liu, Junting oth Wu, Changying oth Li, Leilei oth Xu, Jie oth Cheng, Guanghua oth Gao, Feng oth Enthalten in Elsevier Science Zhang, Yuanyuan ELSEVIER Improved differential evolution for RSSD-based localization in Gaussian mixture noise 2023 Amsterdam [u.a.] (DE-627)ELV009961755 volume:40 year:2020 number:15 pages:6061-6072 extent:12 https://doi.org/10.1016/j.jeurceramsoc.2020.07.030 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.00 Informatik: Allgemeines VZ AR 40 2020 15 6061-6072 12 |
allfields_unstemmed |
10.1016/j.jeurceramsoc.2020.07.030 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001229.pica (DE-627)ELV051075288 (ELSEVIER)S0955-2219(20)30585-9 DE-627 ger DE-627 rakwb eng 004 VZ 54.00 bkl Cao, Shuyao verfasserin aut A novel photochromic ceramics with reversible luminescence modulation and light bleaching behavior: Sm3+-doped KSr2Nb5O15 2020transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. Light bleaching Elsevier Sintering atmosphere Elsevier Photochromism Elsevier Luminescence modulation Elsevier Tetragonal tungsten bronze structure Elsevier Chen, Qian oth Liu, Junting oth Wu, Changying oth Li, Leilei oth Xu, Jie oth Cheng, Guanghua oth Gao, Feng oth Enthalten in Elsevier Science Zhang, Yuanyuan ELSEVIER Improved differential evolution for RSSD-based localization in Gaussian mixture noise 2023 Amsterdam [u.a.] (DE-627)ELV009961755 volume:40 year:2020 number:15 pages:6061-6072 extent:12 https://doi.org/10.1016/j.jeurceramsoc.2020.07.030 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.00 Informatik: Allgemeines VZ AR 40 2020 15 6061-6072 12 |
allfieldsGer |
10.1016/j.jeurceramsoc.2020.07.030 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001229.pica (DE-627)ELV051075288 (ELSEVIER)S0955-2219(20)30585-9 DE-627 ger DE-627 rakwb eng 004 VZ 54.00 bkl Cao, Shuyao verfasserin aut A novel photochromic ceramics with reversible luminescence modulation and light bleaching behavior: Sm3+-doped KSr2Nb5O15 2020transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. Light bleaching Elsevier Sintering atmosphere Elsevier Photochromism Elsevier Luminescence modulation Elsevier Tetragonal tungsten bronze structure Elsevier Chen, Qian oth Liu, Junting oth Wu, Changying oth Li, Leilei oth Xu, Jie oth Cheng, Guanghua oth Gao, Feng oth Enthalten in Elsevier Science Zhang, Yuanyuan ELSEVIER Improved differential evolution for RSSD-based localization in Gaussian mixture noise 2023 Amsterdam [u.a.] (DE-627)ELV009961755 volume:40 year:2020 number:15 pages:6061-6072 extent:12 https://doi.org/10.1016/j.jeurceramsoc.2020.07.030 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.00 Informatik: Allgemeines VZ AR 40 2020 15 6061-6072 12 |
allfieldsSound |
10.1016/j.jeurceramsoc.2020.07.030 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001229.pica (DE-627)ELV051075288 (ELSEVIER)S0955-2219(20)30585-9 DE-627 ger DE-627 rakwb eng 004 VZ 54.00 bkl Cao, Shuyao verfasserin aut A novel photochromic ceramics with reversible luminescence modulation and light bleaching behavior: Sm3+-doped KSr2Nb5O15 2020transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. Light bleaching Elsevier Sintering atmosphere Elsevier Photochromism Elsevier Luminescence modulation Elsevier Tetragonal tungsten bronze structure Elsevier Chen, Qian oth Liu, Junting oth Wu, Changying oth Li, Leilei oth Xu, Jie oth Cheng, Guanghua oth Gao, Feng oth Enthalten in Elsevier Science Zhang, Yuanyuan ELSEVIER Improved differential evolution for RSSD-based localization in Gaussian mixture noise 2023 Amsterdam [u.a.] (DE-627)ELV009961755 volume:40 year:2020 number:15 pages:6061-6072 extent:12 https://doi.org/10.1016/j.jeurceramsoc.2020.07.030 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.00 Informatik: Allgemeines VZ AR 40 2020 15 6061-6072 12 |
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English |
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Enthalten in Improved differential evolution for RSSD-based localization in Gaussian mixture noise Amsterdam [u.a.] volume:40 year:2020 number:15 pages:6061-6072 extent:12 |
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Enthalten in Improved differential evolution for RSSD-based localization in Gaussian mixture noise Amsterdam [u.a.] volume:40 year:2020 number:15 pages:6061-6072 extent:12 |
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Light bleaching Sintering atmosphere Photochromism Luminescence modulation Tetragonal tungsten bronze structure |
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Improved differential evolution for RSSD-based localization in Gaussian mixture noise |
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Cao, Shuyao @@aut@@ Chen, Qian @@oth@@ Liu, Junting @@oth@@ Wu, Changying @@oth@@ Li, Leilei @@oth@@ Xu, Jie @@oth@@ Cheng, Guanghua @@oth@@ Gao, Feng @@oth@@ |
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A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. 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a novel photochromic ceramics with reversible luminescence modulation and light bleaching behavior: sm3+-doped ksr2nb5o15 |
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A novel photochromic ceramics with reversible luminescence modulation and light bleaching behavior: Sm3+-doped KSr2Nb5O15 |
abstract |
A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. |
abstractGer |
A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. |
abstract_unstemmed |
A novel tetragonal tungsten bronze (TTB) type Sm3+-doped KSr2Nb5O15 (KSN-Sm) optical ceramic is fabricated by atmosphere sintering technology. A reversible photochromic effect between faint yellow and olive colors and accompanied luminescence modulation behaviour can be realized by alternating the 395 nm light irradiation and thermal treatment. The thermal stimulus model is introduced to modify the classical resonance energy transfer mechanism. The results show that the optimal luminescence modulation ratio △Rt about the red emission (601 nm) intensity amounted to 60.0 %, and the KSN-Sm ceramic exhibits excellent luminescence modulation rate and reproducibility. The colored KSN-Sm ceramic can be partly bleached by external light stimulus (620 nm), and the luminescence emission intensity can be recovered from 45 % to 84.2 %. The light bleaching efficiency is strongly dependent on the irradiation wavelength, exposure duration and irradiation dose. These discoveries pave the way to develop new luminescence materials with TTB structure. |
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A novel photochromic ceramics with reversible luminescence modulation and light bleaching behavior: Sm3+-doped KSr2Nb5O15 |
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