A new cyclic thioanhydride derived from chlorophyll a and its aurophilic properties
The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Pogorilyy, Viktor [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021transfer abstract |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells - Haghgoo, M. ELSEVIER, 2020, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:184 ; year:2021 ; pages:0 |
| Links: |
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| DOI / URN: |
10.1016/j.dyepig.2020.108858 |
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ELV051736934 |
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| 520 | |a The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). | ||
| 520 | |a The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). | ||
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10.1016/j.dyepig.2020.108858 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001871.pica (DE-627)ELV051736934 (ELSEVIER)S0143-7208(20)31555-2 DE-627 ger DE-627 rakwb eng 690 VZ 50.31 bkl 56.11 bkl Pogorilyy, Viktor verfasserin aut A new cyclic thioanhydride derived from chlorophyll a and its aurophilic properties 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). Naturally occurring chlorins Elsevier Gold nanoparticles (Au-NP) Elsevier Cyclic thioanhydrides Elsevier Kirin, Nikita oth Mironov, Andrey oth Grin, Mikhail oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:184 year:2021 pages:0 https://doi.org/10.1016/j.dyepig.2020.108858 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 184 2021 0 |
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10.1016/j.dyepig.2020.108858 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001871.pica (DE-627)ELV051736934 (ELSEVIER)S0143-7208(20)31555-2 DE-627 ger DE-627 rakwb eng 690 VZ 50.31 bkl 56.11 bkl Pogorilyy, Viktor verfasserin aut A new cyclic thioanhydride derived from chlorophyll a and its aurophilic properties 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). Naturally occurring chlorins Elsevier Gold nanoparticles (Au-NP) Elsevier Cyclic thioanhydrides Elsevier Kirin, Nikita oth Mironov, Andrey oth Grin, Mikhail oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:184 year:2021 pages:0 https://doi.org/10.1016/j.dyepig.2020.108858 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 184 2021 0 |
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10.1016/j.dyepig.2020.108858 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001871.pica (DE-627)ELV051736934 (ELSEVIER)S0143-7208(20)31555-2 DE-627 ger DE-627 rakwb eng 690 VZ 50.31 bkl 56.11 bkl Pogorilyy, Viktor verfasserin aut A new cyclic thioanhydride derived from chlorophyll a and its aurophilic properties 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). Naturally occurring chlorins Elsevier Gold nanoparticles (Au-NP) Elsevier Cyclic thioanhydrides Elsevier Kirin, Nikita oth Mironov, Andrey oth Grin, Mikhail oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:184 year:2021 pages:0 https://doi.org/10.1016/j.dyepig.2020.108858 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 184 2021 0 |
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10.1016/j.dyepig.2020.108858 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001871.pica (DE-627)ELV051736934 (ELSEVIER)S0143-7208(20)31555-2 DE-627 ger DE-627 rakwb eng 690 VZ 50.31 bkl 56.11 bkl Pogorilyy, Viktor verfasserin aut A new cyclic thioanhydride derived from chlorophyll a and its aurophilic properties 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). Naturally occurring chlorins Elsevier Gold nanoparticles (Au-NP) Elsevier Cyclic thioanhydrides Elsevier Kirin, Nikita oth Mironov, Andrey oth Grin, Mikhail oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:184 year:2021 pages:0 https://doi.org/10.1016/j.dyepig.2020.108858 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 184 2021 0 |
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10.1016/j.dyepig.2020.108858 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001871.pica (DE-627)ELV051736934 (ELSEVIER)S0143-7208(20)31555-2 DE-627 ger DE-627 rakwb eng 690 VZ 50.31 bkl 56.11 bkl Pogorilyy, Viktor verfasserin aut A new cyclic thioanhydride derived from chlorophyll a and its aurophilic properties 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). Naturally occurring chlorins Elsevier Gold nanoparticles (Au-NP) Elsevier Cyclic thioanhydrides Elsevier Kirin, Nikita oth Mironov, Andrey oth Grin, Mikhail oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:184 year:2021 pages:0 https://doi.org/10.1016/j.dyepig.2020.108858 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 184 2021 0 |
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Enthalten in A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells Amsterdam [u.a.] volume:184 year:2021 pages:0 |
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Enthalten in A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells Amsterdam [u.a.] volume:184 year:2021 pages:0 |
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A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells |
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| author |
Pogorilyy, Viktor |
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Pogorilyy, Viktor ddc 690 bkl 50.31 bkl 56.11 Elsevier Naturally occurring chlorins Elsevier Gold nanoparticles (Au-NP) Elsevier Cyclic thioanhydrides A new cyclic thioanhydride derived from chlorophyll a and its aurophilic properties |
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690 VZ 50.31 bkl 56.11 bkl A new cyclic thioanhydride derived from chlorophyll a and its aurophilic properties Naturally occurring chlorins Elsevier Gold nanoparticles (Au-NP) Elsevier Cyclic thioanhydrides Elsevier |
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ddc 690 bkl 50.31 bkl 56.11 Elsevier Naturally occurring chlorins Elsevier Gold nanoparticles (Au-NP) Elsevier Cyclic thioanhydrides |
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ddc 690 bkl 50.31 bkl 56.11 Elsevier Naturally occurring chlorins Elsevier Gold nanoparticles (Au-NP) Elsevier Cyclic thioanhydrides |
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ddc 690 bkl 50.31 bkl 56.11 Elsevier Naturally occurring chlorins Elsevier Gold nanoparticles (Au-NP) Elsevier Cyclic thioanhydrides |
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A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells |
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A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells |
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A new cyclic thioanhydride derived from chlorophyll a and its aurophilic properties |
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A new cyclic thioanhydride derived from chlorophyll a and its aurophilic properties |
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Pogorilyy, Viktor |
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A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells |
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A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells |
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a new cyclic thioanhydride derived from chlorophyll a and its aurophilic properties |
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A new cyclic thioanhydride derived from chlorophyll a and its aurophilic properties |
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The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). |
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The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). |
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The need to modify the chlorine macrocycle by additional exocycles is dictated by the desire to increase the stability of the pigment, improve its spectral characteristics, including the shift of the main absorption band to the long-wavelength region, as well as the introduction of chemically active groups for the introduction of other bioactive molecules. Replacing the oxygen atom in the purpurin-18 anhydride exocycle with a sulfur atom can be considered as a bioisosteric substitution, which should not strongly affect the spectral and biological properties of the photosensitizer, but may allow the implementation of new chemical modifications at the periphery of the macrocycle. In this paper, we propose a synthesis pathway for a derivative of naturally occurring chlorin that contains an additional thioanhydride cycle attached to the main macrocycle. We report the spectral characteristics of the compound and demonstrate the possibility of immobilization of chlorin p6 thioanhydride on gold nanoparticles (Au-NP). |
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A new cyclic thioanhydride derived from chlorophyll a and its aurophilic properties |
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Kirin, Nikita Mironov, Andrey Grin, Mikhail |
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