PVDF-HFP/PMMA/TPU-based gel polymer electrolytes composed of conductive Na3Zr2Si2PO12 filler for application in sodium ions batteries
Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Wang, Xinxin [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021transfer abstract |
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| Übergeordnetes Werk: |
Enthalten in: P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION - Garg, A. ELSEVIER, 2014, diffusion and reactions, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:359 ; year:2021 ; pages:0 |
| Links: |
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| DOI / URN: |
10.1016/j.ssi.2020.115532 |
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ELV052585409 |
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| 245 | 1 | 0 | |a PVDF-HFP/PMMA/TPU-based gel polymer electrolytes composed of conductive Na3Zr2Si2PO12 filler for application in sodium ions batteries |
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| 520 | |a Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. | ||
| 520 | |a Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. | ||
| 700 | 1 | |a Liu, Zehua |4 oth | |
| 700 | 1 | |a Tang, Yihua |4 oth | |
| 700 | 1 | |a Chen, Jingjing |4 oth | |
| 700 | 1 | |a Mao, Zhiyong |4 oth | |
| 700 | 1 | |a Wang, Dajian |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier Science |a Garg, A. ELSEVIER |t P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION |d 2014 |d diffusion and reactions |g Amsterdam [u.a.] |w (DE-627)ELV012106844 |
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10.1016/j.ssi.2020.115532 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001398.pica (DE-627)ELV052585409 (ELSEVIER)S0167-2738(20)30586-5 DE-627 ger DE-627 rakwb eng 610 VZ 610 VZ 44.44 bkl Wang, Xinxin verfasserin aut PVDF-HFP/PMMA/TPU-based gel polymer electrolytes composed of conductive Na3Zr2Si2PO12 filler for application in sodium ions batteries 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. Liu, Zehua oth Tang, Yihua oth Chen, Jingjing oth Mao, Zhiyong oth Wang, Dajian oth Enthalten in Elsevier Science Garg, A. ELSEVIER P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION 2014 diffusion and reactions Amsterdam [u.a.] (DE-627)ELV012106844 volume:359 year:2021 pages:0 https://doi.org/10.1016/j.ssi.2020.115532 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_21 GBV_ILN_78 44.44 Parasitologie Medizin VZ AR 359 2021 0 |
| spelling |
10.1016/j.ssi.2020.115532 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001398.pica (DE-627)ELV052585409 (ELSEVIER)S0167-2738(20)30586-5 DE-627 ger DE-627 rakwb eng 610 VZ 610 VZ 44.44 bkl Wang, Xinxin verfasserin aut PVDF-HFP/PMMA/TPU-based gel polymer electrolytes composed of conductive Na3Zr2Si2PO12 filler for application in sodium ions batteries 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. Liu, Zehua oth Tang, Yihua oth Chen, Jingjing oth Mao, Zhiyong oth Wang, Dajian oth Enthalten in Elsevier Science Garg, A. ELSEVIER P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION 2014 diffusion and reactions Amsterdam [u.a.] (DE-627)ELV012106844 volume:359 year:2021 pages:0 https://doi.org/10.1016/j.ssi.2020.115532 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_21 GBV_ILN_78 44.44 Parasitologie Medizin VZ AR 359 2021 0 |
| allfields_unstemmed |
10.1016/j.ssi.2020.115532 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001398.pica (DE-627)ELV052585409 (ELSEVIER)S0167-2738(20)30586-5 DE-627 ger DE-627 rakwb eng 610 VZ 610 VZ 44.44 bkl Wang, Xinxin verfasserin aut PVDF-HFP/PMMA/TPU-based gel polymer electrolytes composed of conductive Na3Zr2Si2PO12 filler for application in sodium ions batteries 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. Liu, Zehua oth Tang, Yihua oth Chen, Jingjing oth Mao, Zhiyong oth Wang, Dajian oth Enthalten in Elsevier Science Garg, A. ELSEVIER P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION 2014 diffusion and reactions Amsterdam [u.a.] (DE-627)ELV012106844 volume:359 year:2021 pages:0 https://doi.org/10.1016/j.ssi.2020.115532 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_21 GBV_ILN_78 44.44 Parasitologie Medizin VZ AR 359 2021 0 |
| allfieldsGer |
10.1016/j.ssi.2020.115532 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001398.pica (DE-627)ELV052585409 (ELSEVIER)S0167-2738(20)30586-5 DE-627 ger DE-627 rakwb eng 610 VZ 610 VZ 44.44 bkl Wang, Xinxin verfasserin aut PVDF-HFP/PMMA/TPU-based gel polymer electrolytes composed of conductive Na3Zr2Si2PO12 filler for application in sodium ions batteries 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. Liu, Zehua oth Tang, Yihua oth Chen, Jingjing oth Mao, Zhiyong oth Wang, Dajian oth Enthalten in Elsevier Science Garg, A. ELSEVIER P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION 2014 diffusion and reactions Amsterdam [u.a.] (DE-627)ELV012106844 volume:359 year:2021 pages:0 https://doi.org/10.1016/j.ssi.2020.115532 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_21 GBV_ILN_78 44.44 Parasitologie Medizin VZ AR 359 2021 0 |
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10.1016/j.ssi.2020.115532 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001398.pica (DE-627)ELV052585409 (ELSEVIER)S0167-2738(20)30586-5 DE-627 ger DE-627 rakwb eng 610 VZ 610 VZ 44.44 bkl Wang, Xinxin verfasserin aut PVDF-HFP/PMMA/TPU-based gel polymer electrolytes composed of conductive Na3Zr2Si2PO12 filler for application in sodium ions batteries 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. Liu, Zehua oth Tang, Yihua oth Chen, Jingjing oth Mao, Zhiyong oth Wang, Dajian oth Enthalten in Elsevier Science Garg, A. ELSEVIER P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION 2014 diffusion and reactions Amsterdam [u.a.] (DE-627)ELV012106844 volume:359 year:2021 pages:0 https://doi.org/10.1016/j.ssi.2020.115532 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_21 GBV_ILN_78 44.44 Parasitologie Medizin VZ AR 359 2021 0 |
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Enthalten in P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION Amsterdam [u.a.] volume:359 year:2021 pages:0 |
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Enthalten in P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION Amsterdam [u.a.] volume:359 year:2021 pages:0 |
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PVDF-HFP/PMMA/TPU-based gel polymer electrolytes composed of conductive Na3Zr2Si2PO12 filler for application in sodium ions batteries |
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Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. |
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Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. |
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Gel polymer electrolytes (GPEs) have attracted abundant attentions due to its higher ion conductivity and better compatibility with electrode than the inorganic solid-state electrolytes and safer than the liquid electrolytes. In this work, sodium conductive Na3Zr2Si2PO12 nanoparticles modified PVDF-HFP/PMMA/TPU-based GPEs are prepared and its application performances in sodium ions batteries (SIBs) are demonstrated. The addition of Na3Zr2Si2PO12 filler decreases the crystallinity of polymer matrix and improves the porosity of GPEs membranes, resulting in the increasing of liquid electrolyte uptake. As a result, the Na3Zr2Si2PO12 filler modified GPEs delivers enhanced ion conductivity as high as 2.83 × 10−3 S cm−1 with a small activation energy of ~0.039 eV and enlarged electrochemical window width of 5.16 V. Application in SIBs, high first discharge capacity of 92.7 mAh·g−1 at 0.5C and promising capacity retention capability (99.2% after 100 cycles) as well as excellent rate performance (83.9 mAh·g−1 at 5C) are recorded for the obtained GPEs. These results suggest that the performances of PVDF-HFP/PMMA/TPU-based GPEs can be enhanced obviously by adding conductive Na3Zr2Si2PO12 filler, promoting the practical application of GPEs in energy storage devices. |
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