The quest for efficient oxygenated fuels: Examining interactions between lubricant components and oxygenates

This work empirically evaluated oxygenated blendstock - lubricant compatibility using a novel but simple method. The reactivity or compatibility was evaluated via gas chromatograph equipped with a flame ionization detector (GC-FID) before and after heating for 2 h at 150 °C, which would roughly mimi...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Cosimbescu, Lelia [verfasserIn] Campbell, Kristen B. [verfasserIn] Baker, Tracy J. [verfasserIn] Swita, Marie [verfasserIn] Gaspar, Daniel J. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2020

Schlagwörter:	Fuel-lubricant compatibility Oxygenate compatibility Additive interactions

Übergeordnetes Werk:	Enthalten in: Fuel - New York, NY [u.a.] : Elsevier, 1970, 288
Übergeordnetes Werk:	volume:288

DOI / URN:	10.1016/j.fuel.2020.119728

Katalog-ID:	ELV052635287

Internformat


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245	1	0	\|a The quest for efficient oxygenated fuels: Examining interactions between lubricant components and oxygenates
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520			\|a This work empirically evaluated oxygenated blendstock - lubricant compatibility using a novel but simple method. The reactivity or compatibility was evaluated via gas chromatograph equipped with a flame ionization detector (GC-FID) before and after heating for 2 h at 150 °C, which would roughly mimic conditions encountered in the crankcase of a Spark Ignition (SI) or Compression-Ignition (CI) engine. Although 150 °C does not mimic combustion chamber temperatures, it may provide an insight of potential in-cylinder interactions. Five oxygenate blendstocks spanning several functional groups and chain lengths (prenol, isoprenol, butyl acetate, isohexanol, polyoxymethylene dimethyl ethers) were evaluated in a base fuel with nine variations of lubricant components of controlled concentrations, including fully formulated commercial lubricants. Baseline comparative examples were also generated, to decouple the effect of the oxygenate on the mixture, by heating only the base fuel with the lubricant component. Results demonstrate the relative compatibility between noted lubricants and oxygenates in base fuel upon heating. This was illustrated by minimal to no changes in the GC-FID traces. However, reactions of several of the chosen lubricants, especially Molybdenum di(2-ethylhexyl) phosphorodithioate (Molyvan L) and zinc dialkyldithiophosphate (ZDDP), with prenol and polyoxymethylene dimethyl ethers blendstocks showed substantial side reactions compared to corresponding baseline examples. Control experiments without oxygenates but comprising the same lubricant components showed no change in the mixture with heating. We concluded the reactivity is due to the oxygenate and not the components of the base fuel. This preliminary work is valuable in establishing trends as well as providing useful information when a new component is introduced in the fuel.
650		4	\|a Fuel-lubricant compatibility
650		4	\|a Oxygenate compatibility
650		4	\|a Additive interactions
700	1		\|a Campbell, Kristen B. \|e verfasserin \|4 aut
700	1		\|a Baker, Tracy J. \|e verfasserin \|0 (orcid)0000-0003-4508-3471 \|4 aut
700	1		\|a Swita, Marie \|e verfasserin \|4 aut
700	1		\|a Gaspar, Daniel J. \|e verfasserin \|0 (orcid)0000-0002-8089-810X \|4 aut
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912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_224
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2470
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
936	b	k	\|a 58.21 \|j Brennstoffe \|j Kraftstoffe \|j Explosivstoffe \|q VZ
951			\|a AR
952			\|d 288

Indexfelder

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publishDate	2020
allfields	10.1016/j.fuel.2020.119728 doi (DE-627)ELV052635287 (ELSEVIER)S0016-2361(20)32724-1 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Cosimbescu, Lelia verfasserin aut The quest for efficient oxygenated fuels: Examining interactions between lubricant components and oxygenates 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier This work empirically evaluated oxygenated blendstock - lubricant compatibility using a novel but simple method. The reactivity or compatibility was evaluated via gas chromatograph equipped with a flame ionization detector (GC-FID) before and after heating for 2 h at 150 °C, which would roughly mimic conditions encountered in the crankcase of a Spark Ignition (SI) or Compression-Ignition (CI) engine. Although 150 °C does not mimic combustion chamber temperatures, it may provide an insight of potential in-cylinder interactions. Five oxygenate blendstocks spanning several functional groups and chain lengths (prenol, isoprenol, butyl acetate, isohexanol, polyoxymethylene dimethyl ethers) were evaluated in a base fuel with nine variations of lubricant components of controlled concentrations, including fully formulated commercial lubricants. Baseline comparative examples were also generated, to decouple the effect of the oxygenate on the mixture, by heating only the base fuel with the lubricant component. Results demonstrate the relative compatibility between noted lubricants and oxygenates in base fuel upon heating. This was illustrated by minimal to no changes in the GC-FID traces. However, reactions of several of the chosen lubricants, especially Molybdenum di(2-ethylhexyl) phosphorodithioate (Molyvan L) and zinc dialkyldithiophosphate (ZDDP), with prenol and polyoxymethylene dimethyl ethers blendstocks showed substantial side reactions compared to corresponding baseline examples. Control experiments without oxygenates but comprising the same lubricant components showed no change in the mixture with heating. We concluded the reactivity is due to the oxygenate and not the components of the base fuel. This preliminary work is valuable in establishing trends as well as providing useful information when a new component is introduced in the fuel. Fuel-lubricant compatibility Oxygenate compatibility Additive interactions Campbell, Kristen B. verfasserin aut Baker, Tracy J. verfasserin (orcid)0000-0003-4508-3471 aut Swita, Marie verfasserin aut Gaspar, Daniel J. verfasserin (orcid)0000-0002-8089-810X aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 288 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:288 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 288
spelling	10.1016/j.fuel.2020.119728 doi (DE-627)ELV052635287 (ELSEVIER)S0016-2361(20)32724-1 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Cosimbescu, Lelia verfasserin aut The quest for efficient oxygenated fuels: Examining interactions between lubricant components and oxygenates 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier This work empirically evaluated oxygenated blendstock - lubricant compatibility using a novel but simple method. The reactivity or compatibility was evaluated via gas chromatograph equipped with a flame ionization detector (GC-FID) before and after heating for 2 h at 150 °C, which would roughly mimic conditions encountered in the crankcase of a Spark Ignition (SI) or Compression-Ignition (CI) engine. Although 150 °C does not mimic combustion chamber temperatures, it may provide an insight of potential in-cylinder interactions. Five oxygenate blendstocks spanning several functional groups and chain lengths (prenol, isoprenol, butyl acetate, isohexanol, polyoxymethylene dimethyl ethers) were evaluated in a base fuel with nine variations of lubricant components of controlled concentrations, including fully formulated commercial lubricants. Baseline comparative examples were also generated, to decouple the effect of the oxygenate on the mixture, by heating only the base fuel with the lubricant component. Results demonstrate the relative compatibility between noted lubricants and oxygenates in base fuel upon heating. This was illustrated by minimal to no changes in the GC-FID traces. However, reactions of several of the chosen lubricants, especially Molybdenum di(2-ethylhexyl) phosphorodithioate (Molyvan L) and zinc dialkyldithiophosphate (ZDDP), with prenol and polyoxymethylene dimethyl ethers blendstocks showed substantial side reactions compared to corresponding baseline examples. Control experiments without oxygenates but comprising the same lubricant components showed no change in the mixture with heating. We concluded the reactivity is due to the oxygenate and not the components of the base fuel. This preliminary work is valuable in establishing trends as well as providing useful information when a new component is introduced in the fuel. Fuel-lubricant compatibility Oxygenate compatibility Additive interactions Campbell, Kristen B. verfasserin aut Baker, Tracy J. verfasserin (orcid)0000-0003-4508-3471 aut Swita, Marie verfasserin aut Gaspar, Daniel J. verfasserin (orcid)0000-0002-8089-810X aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 288 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:288 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 288
allfields_unstemmed	10.1016/j.fuel.2020.119728 doi (DE-627)ELV052635287 (ELSEVIER)S0016-2361(20)32724-1 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Cosimbescu, Lelia verfasserin aut The quest for efficient oxygenated fuels: Examining interactions between lubricant components and oxygenates 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier This work empirically evaluated oxygenated blendstock - lubricant compatibility using a novel but simple method. The reactivity or compatibility was evaluated via gas chromatograph equipped with a flame ionization detector (GC-FID) before and after heating for 2 h at 150 °C, which would roughly mimic conditions encountered in the crankcase of a Spark Ignition (SI) or Compression-Ignition (CI) engine. Although 150 °C does not mimic combustion chamber temperatures, it may provide an insight of potential in-cylinder interactions. Five oxygenate blendstocks spanning several functional groups and chain lengths (prenol, isoprenol, butyl acetate, isohexanol, polyoxymethylene dimethyl ethers) were evaluated in a base fuel with nine variations of lubricant components of controlled concentrations, including fully formulated commercial lubricants. Baseline comparative examples were also generated, to decouple the effect of the oxygenate on the mixture, by heating only the base fuel with the lubricant component. Results demonstrate the relative compatibility between noted lubricants and oxygenates in base fuel upon heating. This was illustrated by minimal to no changes in the GC-FID traces. However, reactions of several of the chosen lubricants, especially Molybdenum di(2-ethylhexyl) phosphorodithioate (Molyvan L) and zinc dialkyldithiophosphate (ZDDP), with prenol and polyoxymethylene dimethyl ethers blendstocks showed substantial side reactions compared to corresponding baseline examples. Control experiments without oxygenates but comprising the same lubricant components showed no change in the mixture with heating. We concluded the reactivity is due to the oxygenate and not the components of the base fuel. This preliminary work is valuable in establishing trends as well as providing useful information when a new component is introduced in the fuel. Fuel-lubricant compatibility Oxygenate compatibility Additive interactions Campbell, Kristen B. verfasserin aut Baker, Tracy J. verfasserin (orcid)0000-0003-4508-3471 aut Swita, Marie verfasserin aut Gaspar, Daniel J. verfasserin (orcid)0000-0002-8089-810X aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 288 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:288 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 288
allfieldsGer	10.1016/j.fuel.2020.119728 doi (DE-627)ELV052635287 (ELSEVIER)S0016-2361(20)32724-1 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Cosimbescu, Lelia verfasserin aut The quest for efficient oxygenated fuels: Examining interactions between lubricant components and oxygenates 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier This work empirically evaluated oxygenated blendstock - lubricant compatibility using a novel but simple method. The reactivity or compatibility was evaluated via gas chromatograph equipped with a flame ionization detector (GC-FID) before and after heating for 2 h at 150 °C, which would roughly mimic conditions encountered in the crankcase of a Spark Ignition (SI) or Compression-Ignition (CI) engine. Although 150 °C does not mimic combustion chamber temperatures, it may provide an insight of potential in-cylinder interactions. Five oxygenate blendstocks spanning several functional groups and chain lengths (prenol, isoprenol, butyl acetate, isohexanol, polyoxymethylene dimethyl ethers) were evaluated in a base fuel with nine variations of lubricant components of controlled concentrations, including fully formulated commercial lubricants. Baseline comparative examples were also generated, to decouple the effect of the oxygenate on the mixture, by heating only the base fuel with the lubricant component. Results demonstrate the relative compatibility between noted lubricants and oxygenates in base fuel upon heating. This was illustrated by minimal to no changes in the GC-FID traces. However, reactions of several of the chosen lubricants, especially Molybdenum di(2-ethylhexyl) phosphorodithioate (Molyvan L) and zinc dialkyldithiophosphate (ZDDP), with prenol and polyoxymethylene dimethyl ethers blendstocks showed substantial side reactions compared to corresponding baseline examples. Control experiments without oxygenates but comprising the same lubricant components showed no change in the mixture with heating. We concluded the reactivity is due to the oxygenate and not the components of the base fuel. This preliminary work is valuable in establishing trends as well as providing useful information when a new component is introduced in the fuel. Fuel-lubricant compatibility Oxygenate compatibility Additive interactions Campbell, Kristen B. verfasserin aut Baker, Tracy J. verfasserin (orcid)0000-0003-4508-3471 aut Swita, Marie verfasserin aut Gaspar, Daniel J. verfasserin (orcid)0000-0002-8089-810X aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 288 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:288 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 288
allfieldsSound	10.1016/j.fuel.2020.119728 doi (DE-627)ELV052635287 (ELSEVIER)S0016-2361(20)32724-1 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Cosimbescu, Lelia verfasserin aut The quest for efficient oxygenated fuels: Examining interactions between lubricant components and oxygenates 2020 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier This work empirically evaluated oxygenated blendstock - lubricant compatibility using a novel but simple method. The reactivity or compatibility was evaluated via gas chromatograph equipped with a flame ionization detector (GC-FID) before and after heating for 2 h at 150 °C, which would roughly mimic conditions encountered in the crankcase of a Spark Ignition (SI) or Compression-Ignition (CI) engine. Although 150 °C does not mimic combustion chamber temperatures, it may provide an insight of potential in-cylinder interactions. Five oxygenate blendstocks spanning several functional groups and chain lengths (prenol, isoprenol, butyl acetate, isohexanol, polyoxymethylene dimethyl ethers) were evaluated in a base fuel with nine variations of lubricant components of controlled concentrations, including fully formulated commercial lubricants. Baseline comparative examples were also generated, to decouple the effect of the oxygenate on the mixture, by heating only the base fuel with the lubricant component. Results demonstrate the relative compatibility between noted lubricants and oxygenates in base fuel upon heating. This was illustrated by minimal to no changes in the GC-FID traces. However, reactions of several of the chosen lubricants, especially Molybdenum di(2-ethylhexyl) phosphorodithioate (Molyvan L) and zinc dialkyldithiophosphate (ZDDP), with prenol and polyoxymethylene dimethyl ethers blendstocks showed substantial side reactions compared to corresponding baseline examples. Control experiments without oxygenates but comprising the same lubricant components showed no change in the mixture with heating. We concluded the reactivity is due to the oxygenate and not the components of the base fuel. This preliminary work is valuable in establishing trends as well as providing useful information when a new component is introduced in the fuel. Fuel-lubricant compatibility Oxygenate compatibility Additive interactions Campbell, Kristen B. verfasserin aut Baker, Tracy J. verfasserin (orcid)0000-0003-4508-3471 aut Swita, Marie verfasserin aut Gaspar, Daniel J. verfasserin (orcid)0000-0002-8089-810X aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 288 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:288 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 288
language	English
source	Enthalten in Fuel 288 volume:288
sourceStr	Enthalten in Fuel 288 volume:288
format_phy_str_mv	Article
bklname	Brennstoffe Kraftstoffe Explosivstoffe
institution	findex.gbv.de
topic_facet	Fuel-lubricant compatibility Oxygenate compatibility Additive interactions
dewey-raw	660
isfreeaccess_bool	false
container_title	Fuel
authorswithroles_txt_mv	Cosimbescu, Lelia @@aut@@ Campbell, Kristen B. @@aut@@ Baker, Tracy J. @@aut@@ Swita, Marie @@aut@@ Gaspar, Daniel J. @@aut@@
publishDateDaySort_date	2020-01-01T00:00:00Z
hierarchy_top_id	300898584
dewey-sort	3660
id	ELV052635287
language_de	englisch
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The reactivity or compatibility was evaluated via gas chromatograph equipped with a flame ionization detector (GC-FID) before and after heating for 2 h at 150 °C, which would roughly mimic conditions encountered in the crankcase of a Spark Ignition (SI) or Compression-Ignition (CI) engine. Although 150 °C does not mimic combustion chamber temperatures, it may provide an insight of potential in-cylinder interactions. Five oxygenate blendstocks spanning several functional groups and chain lengths (prenol, isoprenol, butyl acetate, isohexanol, polyoxymethylene dimethyl ethers) were evaluated in a base fuel with nine variations of lubricant components of controlled concentrations, including fully formulated commercial lubricants. Baseline comparative examples were also generated, to decouple the effect of the oxygenate on the mixture, by heating only the base fuel with the lubricant component. Results demonstrate the relative compatibility between noted lubricants and oxygenates in base fuel upon heating. This was illustrated by minimal to no changes in the GC-FID traces. However, reactions of several of the chosen lubricants, especially Molybdenum di(2-ethylhexyl) phosphorodithioate (Molyvan L) and zinc dialkyldithiophosphate (ZDDP), with prenol and polyoxymethylene dimethyl ethers blendstocks showed substantial side reactions compared to corresponding baseline examples. Control experiments without oxygenates but comprising the same lubricant components showed no change in the mixture with heating. We concluded the reactivity is due to the oxygenate and not the components of the base fuel. 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author	Cosimbescu, Lelia
spellingShingle	Cosimbescu, Lelia ddc 660 bkl 58.21 misc Fuel-lubricant compatibility misc Oxygenate compatibility misc Additive interactions The quest for efficient oxygenated fuels: Examining interactions between lubricant components and oxygenates
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topic_title	660 VZ 58.21 bkl The quest for efficient oxygenated fuels: Examining interactions between lubricant components and oxygenates Fuel-lubricant compatibility Oxygenate compatibility Additive interactions
topic	ddc 660 bkl 58.21 misc Fuel-lubricant compatibility misc Oxygenate compatibility misc Additive interactions
topic_unstemmed	ddc 660 bkl 58.21 misc Fuel-lubricant compatibility misc Oxygenate compatibility misc Additive interactions
topic_browse	ddc 660 bkl 58.21 misc Fuel-lubricant compatibility misc Oxygenate compatibility misc Additive interactions
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title	The quest for efficient oxygenated fuels: Examining interactions between lubricant components and oxygenates
ctrlnum	(DE-627)ELV052635287 (ELSEVIER)S0016-2361(20)32724-1
title_full	The quest for efficient oxygenated fuels: Examining interactions between lubricant components and oxygenates
author_sort	Cosimbescu, Lelia
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author_browse	Cosimbescu, Lelia Campbell, Kristen B. Baker, Tracy J. Swita, Marie Gaspar, Daniel J.
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author-letter	Cosimbescu, Lelia
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title_sort	the quest for efficient oxygenated fuels: examining interactions between lubricant components and oxygenates
title_auth	The quest for efficient oxygenated fuels: Examining interactions between lubricant components and oxygenates
abstract	This work empirically evaluated oxygenated blendstock - lubricant compatibility using a novel but simple method. The reactivity or compatibility was evaluated via gas chromatograph equipped with a flame ionization detector (GC-FID) before and after heating for 2 h at 150 °C, which would roughly mimic conditions encountered in the crankcase of a Spark Ignition (SI) or Compression-Ignition (CI) engine. Although 150 °C does not mimic combustion chamber temperatures, it may provide an insight of potential in-cylinder interactions. Five oxygenate blendstocks spanning several functional groups and chain lengths (prenol, isoprenol, butyl acetate, isohexanol, polyoxymethylene dimethyl ethers) were evaluated in a base fuel with nine variations of lubricant components of controlled concentrations, including fully formulated commercial lubricants. Baseline comparative examples were also generated, to decouple the effect of the oxygenate on the mixture, by heating only the base fuel with the lubricant component. Results demonstrate the relative compatibility between noted lubricants and oxygenates in base fuel upon heating. This was illustrated by minimal to no changes in the GC-FID traces. However, reactions of several of the chosen lubricants, especially Molybdenum di(2-ethylhexyl) phosphorodithioate (Molyvan L) and zinc dialkyldithiophosphate (ZDDP), with prenol and polyoxymethylene dimethyl ethers blendstocks showed substantial side reactions compared to corresponding baseline examples. Control experiments without oxygenates but comprising the same lubricant components showed no change in the mixture with heating. We concluded the reactivity is due to the oxygenate and not the components of the base fuel. This preliminary work is valuable in establishing trends as well as providing useful information when a new component is introduced in the fuel.
abstractGer	This work empirically evaluated oxygenated blendstock - lubricant compatibility using a novel but simple method. The reactivity or compatibility was evaluated via gas chromatograph equipped with a flame ionization detector (GC-FID) before and after heating for 2 h at 150 °C, which would roughly mimic conditions encountered in the crankcase of a Spark Ignition (SI) or Compression-Ignition (CI) engine. Although 150 °C does not mimic combustion chamber temperatures, it may provide an insight of potential in-cylinder interactions. Five oxygenate blendstocks spanning several functional groups and chain lengths (prenol, isoprenol, butyl acetate, isohexanol, polyoxymethylene dimethyl ethers) were evaluated in a base fuel with nine variations of lubricant components of controlled concentrations, including fully formulated commercial lubricants. Baseline comparative examples were also generated, to decouple the effect of the oxygenate on the mixture, by heating only the base fuel with the lubricant component. Results demonstrate the relative compatibility between noted lubricants and oxygenates in base fuel upon heating. This was illustrated by minimal to no changes in the GC-FID traces. However, reactions of several of the chosen lubricants, especially Molybdenum di(2-ethylhexyl) phosphorodithioate (Molyvan L) and zinc dialkyldithiophosphate (ZDDP), with prenol and polyoxymethylene dimethyl ethers blendstocks showed substantial side reactions compared to corresponding baseline examples. Control experiments without oxygenates but comprising the same lubricant components showed no change in the mixture with heating. We concluded the reactivity is due to the oxygenate and not the components of the base fuel. This preliminary work is valuable in establishing trends as well as providing useful information when a new component is introduced in the fuel.
abstract_unstemmed	This work empirically evaluated oxygenated blendstock - lubricant compatibility using a novel but simple method. The reactivity or compatibility was evaluated via gas chromatograph equipped with a flame ionization detector (GC-FID) before and after heating for 2 h at 150 °C, which would roughly mimic conditions encountered in the crankcase of a Spark Ignition (SI) or Compression-Ignition (CI) engine. Although 150 °C does not mimic combustion chamber temperatures, it may provide an insight of potential in-cylinder interactions. Five oxygenate blendstocks spanning several functional groups and chain lengths (prenol, isoprenol, butyl acetate, isohexanol, polyoxymethylene dimethyl ethers) were evaluated in a base fuel with nine variations of lubricant components of controlled concentrations, including fully formulated commercial lubricants. Baseline comparative examples were also generated, to decouple the effect of the oxygenate on the mixture, by heating only the base fuel with the lubricant component. Results demonstrate the relative compatibility between noted lubricants and oxygenates in base fuel upon heating. This was illustrated by minimal to no changes in the GC-FID traces. However, reactions of several of the chosen lubricants, especially Molybdenum di(2-ethylhexyl) phosphorodithioate (Molyvan L) and zinc dialkyldithiophosphate (ZDDP), with prenol and polyoxymethylene dimethyl ethers blendstocks showed substantial side reactions compared to corresponding baseline examples. Control experiments without oxygenates but comprising the same lubricant components showed no change in the mixture with heating. We concluded the reactivity is due to the oxygenate and not the components of the base fuel. This preliminary work is valuable in establishing trends as well as providing useful information when a new component is introduced in the fuel.
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title_short	The quest for efficient oxygenated fuels: Examining interactions between lubricant components and oxygenates
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author2	Campbell, Kristen B. Baker, Tracy J. Swita, Marie Gaspar, Daniel J.
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up_date	2024-07-06T16:42:46.745Z
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