Protic/aprotic ionic liquids for effective CO2 separation using supported ionic liquid membrane
Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separa...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Swati, Imran Khan [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021transfer abstract |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: MPI vs Fortran coarrays beyond 100k cores: 3D cellular automata - Shterenlikht, Anton ELSEVIER, 2019, chemistry, biology and toxicology as related to environmental problems, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:267 ; year:2021 ; pages:0 |
| Links: |
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| DOI / URN: |
10.1016/j.chemosphere.2020.128894 |
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ELV05276317X |
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| 245 | 1 | 0 | |a Protic/aprotic ionic liquids for effective CO2 separation using supported ionic liquid membrane |
| 264 | 1 | |c 2021transfer abstract | |
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| 520 | |a Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. | ||
| 520 | |a Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. | ||
| 650 | 7 | |a Membrane separation |2 Elsevier | |
| 650 | 7 | |a Membrane selectivity |2 Elsevier | |
| 650 | 7 | |a Ionic liquids |2 Elsevier | |
| 650 | 7 | |a Supported ionic liquid membrane |2 Elsevier | |
| 650 | 7 | |a Carbon capture |2 Elsevier | |
| 700 | 1 | |a Sohaib, Qazi |4 oth | |
| 700 | 1 | |a Cao, Shuyun |4 oth | |
| 700 | 1 | |a Younas, Mohammad |4 oth | |
| 700 | 1 | |a Liu, Dan |4 oth | |
| 700 | 1 | |a Gui, Jianzhou |4 oth | |
| 700 | 1 | |a Rezakazemi, Mashallah |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier Science |a Shterenlikht, Anton ELSEVIER |t MPI vs Fortran coarrays beyond 100k cores: 3D cellular automata |d 2019 |d chemistry, biology and toxicology as related to environmental problems |g Amsterdam [u.a.] |w (DE-627)ELV002112701 |
| 773 | 1 | 8 | |g volume:267 |g year:2021 |g pages:0 |
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10.1016/j.chemosphere.2020.128894 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001301.pica (DE-627)ELV05276317X (ELSEVIER)S0045-6535(20)33091-5 DE-627 ger DE-627 rakwb eng 004 620 VZ 54.25 bkl Swati, Imran Khan verfasserin aut Protic/aprotic ionic liquids for effective CO2 separation using supported ionic liquid membrane 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. Membrane separation Elsevier Membrane selectivity Elsevier Ionic liquids Elsevier Supported ionic liquid membrane Elsevier Carbon capture Elsevier Sohaib, Qazi oth Cao, Shuyun oth Younas, Mohammad oth Liu, Dan oth Gui, Jianzhou oth Rezakazemi, Mashallah oth Enthalten in Elsevier Science Shterenlikht, Anton ELSEVIER MPI vs Fortran coarrays beyond 100k cores: 3D cellular automata 2019 chemistry, biology and toxicology as related to environmental problems Amsterdam [u.a.] (DE-627)ELV002112701 volume:267 year:2021 pages:0 https://doi.org/10.1016/j.chemosphere.2020.128894 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.25 Parallele Datenverarbeitung VZ AR 267 2021 0 |
| spelling |
10.1016/j.chemosphere.2020.128894 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001301.pica (DE-627)ELV05276317X (ELSEVIER)S0045-6535(20)33091-5 DE-627 ger DE-627 rakwb eng 004 620 VZ 54.25 bkl Swati, Imran Khan verfasserin aut Protic/aprotic ionic liquids for effective CO2 separation using supported ionic liquid membrane 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. Membrane separation Elsevier Membrane selectivity Elsevier Ionic liquids Elsevier Supported ionic liquid membrane Elsevier Carbon capture Elsevier Sohaib, Qazi oth Cao, Shuyun oth Younas, Mohammad oth Liu, Dan oth Gui, Jianzhou oth Rezakazemi, Mashallah oth Enthalten in Elsevier Science Shterenlikht, Anton ELSEVIER MPI vs Fortran coarrays beyond 100k cores: 3D cellular automata 2019 chemistry, biology and toxicology as related to environmental problems Amsterdam [u.a.] (DE-627)ELV002112701 volume:267 year:2021 pages:0 https://doi.org/10.1016/j.chemosphere.2020.128894 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.25 Parallele Datenverarbeitung VZ AR 267 2021 0 |
| allfields_unstemmed |
10.1016/j.chemosphere.2020.128894 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001301.pica (DE-627)ELV05276317X (ELSEVIER)S0045-6535(20)33091-5 DE-627 ger DE-627 rakwb eng 004 620 VZ 54.25 bkl Swati, Imran Khan verfasserin aut Protic/aprotic ionic liquids for effective CO2 separation using supported ionic liquid membrane 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. Membrane separation Elsevier Membrane selectivity Elsevier Ionic liquids Elsevier Supported ionic liquid membrane Elsevier Carbon capture Elsevier Sohaib, Qazi oth Cao, Shuyun oth Younas, Mohammad oth Liu, Dan oth Gui, Jianzhou oth Rezakazemi, Mashallah oth Enthalten in Elsevier Science Shterenlikht, Anton ELSEVIER MPI vs Fortran coarrays beyond 100k cores: 3D cellular automata 2019 chemistry, biology and toxicology as related to environmental problems Amsterdam [u.a.] (DE-627)ELV002112701 volume:267 year:2021 pages:0 https://doi.org/10.1016/j.chemosphere.2020.128894 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.25 Parallele Datenverarbeitung VZ AR 267 2021 0 |
| allfieldsGer |
10.1016/j.chemosphere.2020.128894 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001301.pica (DE-627)ELV05276317X (ELSEVIER)S0045-6535(20)33091-5 DE-627 ger DE-627 rakwb eng 004 620 VZ 54.25 bkl Swati, Imran Khan verfasserin aut Protic/aprotic ionic liquids for effective CO2 separation using supported ionic liquid membrane 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. Membrane separation Elsevier Membrane selectivity Elsevier Ionic liquids Elsevier Supported ionic liquid membrane Elsevier Carbon capture Elsevier Sohaib, Qazi oth Cao, Shuyun oth Younas, Mohammad oth Liu, Dan oth Gui, Jianzhou oth Rezakazemi, Mashallah oth Enthalten in Elsevier Science Shterenlikht, Anton ELSEVIER MPI vs Fortran coarrays beyond 100k cores: 3D cellular automata 2019 chemistry, biology and toxicology as related to environmental problems Amsterdam [u.a.] (DE-627)ELV002112701 volume:267 year:2021 pages:0 https://doi.org/10.1016/j.chemosphere.2020.128894 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.25 Parallele Datenverarbeitung VZ AR 267 2021 0 |
| allfieldsSound |
10.1016/j.chemosphere.2020.128894 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001301.pica (DE-627)ELV05276317X (ELSEVIER)S0045-6535(20)33091-5 DE-627 ger DE-627 rakwb eng 004 620 VZ 54.25 bkl Swati, Imran Khan verfasserin aut Protic/aprotic ionic liquids for effective CO2 separation using supported ionic liquid membrane 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. Membrane separation Elsevier Membrane selectivity Elsevier Ionic liquids Elsevier Supported ionic liquid membrane Elsevier Carbon capture Elsevier Sohaib, Qazi oth Cao, Shuyun oth Younas, Mohammad oth Liu, Dan oth Gui, Jianzhou oth Rezakazemi, Mashallah oth Enthalten in Elsevier Science Shterenlikht, Anton ELSEVIER MPI vs Fortran coarrays beyond 100k cores: 3D cellular automata 2019 chemistry, biology and toxicology as related to environmental problems Amsterdam [u.a.] (DE-627)ELV002112701 volume:267 year:2021 pages:0 https://doi.org/10.1016/j.chemosphere.2020.128894 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 54.25 Parallele Datenverarbeitung VZ AR 267 2021 0 |
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protic/aprotic ionic liquids for effective co2 separation using supported ionic liquid membrane |
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Protic/aprotic ionic liquids for effective CO2 separation using supported ionic liquid membrane |
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Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. |
| abstractGer |
Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. |
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Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs. |
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Protic/aprotic ionic liquids for effective CO2 separation using supported ionic liquid membrane |
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ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Four ionic liquids (ILs) namely, 1-butylsulfonate-3-methylimidazolium P-toluene sulfonate ([BSmim][tos]), 1-butylsulfonate pyridine P-toluene sulfonate ([BSmpy][tos]), 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) and 1-butylpyridine chloride ([Bpy][Cl]) were synthesized for the effective separation of gases CO2/N2 and CO2/CH4 through supported ionic liquid membranes (SILMs). ILs were confirmed by NMR and FTIR spectroscopy, and their characteristics and physical properties were studied. The ILs were immobilized on the porous hydrophobic 200 μm thick polyvinylidene difluoride (PVDF) support. Pure and mixed gas separation performances of the prepared SILMs were analyzed in a custom-built gas permeation unit. The SILMs were stable up to 0.6 MPa at room temperature without leaching the ionic liquid. [BSmim][tos] was recorded to have the highest solubility coefficient and permeability for CO2, among other ILs. At 0.5 MPa, for pure CO2/N2 and CO2/CH4, IL [BSmim][tos] was observed with selectivities of 56.2 and 47.5, respectively. Based on the SILMs separation performance, the ILs synthesized for this work can be ranked as [BSmim][tos] > [BSmpy][tos] > [Bmim][Cl] > [Bpy][Cl]. Moreover, the exceptionally high selectivity values of [BSmim][tos] and [BSmpy][tos] confirms the potential use of ILs for CO2 separation through SILMs.</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Membrane separation</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Membrane selectivity</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Ionic liquids</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Supported ionic liquid membrane</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Carbon capture</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Sohaib, Qazi</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Cao, Shuyun</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Younas, Mohammad</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Liu, Dan</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Gui, Jianzhou</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Rezakazemi, Mashallah</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="n">Elsevier Science</subfield><subfield code="a">Shterenlikht, Anton ELSEVIER</subfield><subfield code="t">MPI vs Fortran coarrays beyond 100k cores: 3D cellular automata</subfield><subfield code="d">2019</subfield><subfield code="d">chemistry, biology and toxicology as related to environmental problems</subfield><subfield code="g">Amsterdam [u.a.]</subfield><subfield code="w">(DE-627)ELV002112701</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:267</subfield><subfield code="g">year:2021</subfield><subfield code="g">pages:0</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.1016/j.chemosphere.2020.128894</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">54.25</subfield><subfield code="j">Parallele Datenverarbeitung</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">267</subfield><subfield code="j">2021</subfield><subfield code="h">0</subfield></datafield></record></collection>
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