Studies on the surface oxidation and its role in the flotation of mixed Cu-Ni sulfide ore
Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effe...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Liu, Dezhi [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021transfer abstract |
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| Umfang: |
9 |
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| Übergeordnetes Werk: |
Enthalten in: Role of sulfur in combating arsenic stress through upregulation of important proteins, and - Amna, Syeda ELSEVIER, 2020, an international journal on the science and technology of wet and dry particulate systems, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:381 ; year:2021 ; pages:576-584 ; extent:9 |
| Links: |
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| DOI / URN: |
10.1016/j.powtec.2020.12.038 |
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| 520 | |a Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. | ||
| 520 | |a Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. | ||
| 700 | 1 | |a Zhang, Guofan |4 oth | |
| 700 | 1 | |a Liu, Jianxin |4 oth | |
| 700 | 1 | |a Pan, Guangjiu |4 oth | |
| 700 | 1 | |a Chen, Yanfei |4 oth | |
| 700 | 1 | |a Wang, Mengtao |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier Science |a Amna, Syeda ELSEVIER |t Role of sulfur in combating arsenic stress through upregulation of important proteins, and |d 2020 |d an international journal on the science and technology of wet and dry particulate systems |g Amsterdam [u.a.] |w (DE-627)ELV005093252 |
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10.1016/j.powtec.2020.12.038 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001276.pica (DE-627)ELV052855686 (ELSEVIER)S0032-5910(20)31205-5 DE-627 ger DE-627 rakwb eng 630 640 580 VZ BIODIV DE-30 fid 42.00 bkl Liu, Dezhi verfasserin aut Studies on the surface oxidation and its role in the flotation of mixed Cu-Ni sulfide ore 2021transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. Zhang, Guofan oth Liu, Jianxin oth Pan, Guangjiu oth Chen, Yanfei oth Wang, Mengtao oth Enthalten in Elsevier Science Amna, Syeda ELSEVIER Role of sulfur in combating arsenic stress through upregulation of important proteins, and 2020 an international journal on the science and technology of wet and dry particulate systems Amsterdam [u.a.] (DE-627)ELV005093252 volume:381 year:2021 pages:576-584 extent:9 https://doi.org/10.1016/j.powtec.2020.12.038 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV 42.00 Biologie: Allgemeines VZ AR 381 2021 576-584 9 |
| spelling |
10.1016/j.powtec.2020.12.038 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001276.pica (DE-627)ELV052855686 (ELSEVIER)S0032-5910(20)31205-5 DE-627 ger DE-627 rakwb eng 630 640 580 VZ BIODIV DE-30 fid 42.00 bkl Liu, Dezhi verfasserin aut Studies on the surface oxidation and its role in the flotation of mixed Cu-Ni sulfide ore 2021transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. Zhang, Guofan oth Liu, Jianxin oth Pan, Guangjiu oth Chen, Yanfei oth Wang, Mengtao oth Enthalten in Elsevier Science Amna, Syeda ELSEVIER Role of sulfur in combating arsenic stress through upregulation of important proteins, and 2020 an international journal on the science and technology of wet and dry particulate systems Amsterdam [u.a.] (DE-627)ELV005093252 volume:381 year:2021 pages:576-584 extent:9 https://doi.org/10.1016/j.powtec.2020.12.038 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV 42.00 Biologie: Allgemeines VZ AR 381 2021 576-584 9 |
| allfields_unstemmed |
10.1016/j.powtec.2020.12.038 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001276.pica (DE-627)ELV052855686 (ELSEVIER)S0032-5910(20)31205-5 DE-627 ger DE-627 rakwb eng 630 640 580 VZ BIODIV DE-30 fid 42.00 bkl Liu, Dezhi verfasserin aut Studies on the surface oxidation and its role in the flotation of mixed Cu-Ni sulfide ore 2021transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. Zhang, Guofan oth Liu, Jianxin oth Pan, Guangjiu oth Chen, Yanfei oth Wang, Mengtao oth Enthalten in Elsevier Science Amna, Syeda ELSEVIER Role of sulfur in combating arsenic stress through upregulation of important proteins, and 2020 an international journal on the science and technology of wet and dry particulate systems Amsterdam [u.a.] (DE-627)ELV005093252 volume:381 year:2021 pages:576-584 extent:9 https://doi.org/10.1016/j.powtec.2020.12.038 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV 42.00 Biologie: Allgemeines VZ AR 381 2021 576-584 9 |
| allfieldsGer |
10.1016/j.powtec.2020.12.038 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001276.pica (DE-627)ELV052855686 (ELSEVIER)S0032-5910(20)31205-5 DE-627 ger DE-627 rakwb eng 630 640 580 VZ BIODIV DE-30 fid 42.00 bkl Liu, Dezhi verfasserin aut Studies on the surface oxidation and its role in the flotation of mixed Cu-Ni sulfide ore 2021transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. Zhang, Guofan oth Liu, Jianxin oth Pan, Guangjiu oth Chen, Yanfei oth Wang, Mengtao oth Enthalten in Elsevier Science Amna, Syeda ELSEVIER Role of sulfur in combating arsenic stress through upregulation of important proteins, and 2020 an international journal on the science and technology of wet and dry particulate systems Amsterdam [u.a.] (DE-627)ELV005093252 volume:381 year:2021 pages:576-584 extent:9 https://doi.org/10.1016/j.powtec.2020.12.038 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV 42.00 Biologie: Allgemeines VZ AR 381 2021 576-584 9 |
| allfieldsSound |
10.1016/j.powtec.2020.12.038 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001276.pica (DE-627)ELV052855686 (ELSEVIER)S0032-5910(20)31205-5 DE-627 ger DE-627 rakwb eng 630 640 580 VZ BIODIV DE-30 fid 42.00 bkl Liu, Dezhi verfasserin aut Studies on the surface oxidation and its role in the flotation of mixed Cu-Ni sulfide ore 2021transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. Zhang, Guofan oth Liu, Jianxin oth Pan, Guangjiu oth Chen, Yanfei oth Wang, Mengtao oth Enthalten in Elsevier Science Amna, Syeda ELSEVIER Role of sulfur in combating arsenic stress through upregulation of important proteins, and 2020 an international journal on the science and technology of wet and dry particulate systems Amsterdam [u.a.] (DE-627)ELV005093252 volume:381 year:2021 pages:576-584 extent:9 https://doi.org/10.1016/j.powtec.2020.12.038 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV 42.00 Biologie: Allgemeines VZ AR 381 2021 576-584 9 |
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However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. 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studies on the surface oxidation and its role in the flotation of mixed cu-ni sulfide ore |
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Studies on the surface oxidation and its role in the flotation of mixed Cu-Ni sulfide ore |
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Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. |
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Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. |
| abstract_unstemmed |
Surface oxidation has a significant influence on sulfides flotation. However, there is a little literature about the effect of surface oxidation in the flotation of mixed copper‑nickel sulfide (CuNi sulfide, mainly composed of pentlandite, chalcopyrite, pyrite and pyrrhotite). In this work, the effect of surface oxidation on the CuNi sulfide flotation was studied. Flotation results showed the surface oxidation had a stronger depression effect on CuNi sulfide flotation than that on the flotation of single pyrite and chalcopyrite mineral samples. XPS analysis results showed that the hydrophilic products sulfate and Fe/Ni oxide/hydroxide were generated on the oxidized CuNi sulfide surface, whereas no Cu oxide/hydroxide was found, indicating the occurrence of galvanic interaction, which might cause the stronger depression of oxidation on CuNi sulfide flotation. However, after the pretreatment of ultrasonic cleaning in HCl solution, the sulfate and iron hydroxide/oxide on CuNi sulfide surface decreased significantly, and then CuNi sulfide floatability was regained to some extent. Interestingly, adsorption results exhibited that the adsorption amounts of PBX on CuNi sulfide surface basically unchanged before and after oxidation, which might be caused by that chalcopyrite and pyrite were protected from oxidation as the cathode minerals in the galvanic interaction. |
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Studies on the surface oxidation and its role in the flotation of mixed Cu-Ni sulfide ore |
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