Extending the potential of plasma-induced luminescence spectroscopy
In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from th...
Ausführliche Beschreibung
Autor*in: |
Clavé, Elise [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2021transfer abstract |
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Übergeordnetes Werk: |
Enthalten in: Dual stimuli-responsive polypeptide-calcium phosphate hybrid nanoparticles for co-delivery of multiple drugs in cancer therapy - Li, Qiang ELSEVIER, 2021, Amsterdam [u.a.] |
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Übergeordnetes Werk: |
volume:177 ; year:2021 ; pages:0 |
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DOI / URN: |
10.1016/j.sab.2021.106111 |
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Katalog-ID: |
ELV053309782 |
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520 | |a In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. | ||
520 | |a In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. | ||
700 | 1 | |a Gaft, Michael |4 oth | |
700 | 1 | |a Motto-Ros, Vincent |4 oth | |
700 | 1 | |a Fabre, Cécile |4 oth | |
700 | 1 | |a Forni, Olivier |4 oth | |
700 | 1 | |a Beyssac, Olivier |4 oth | |
700 | 1 | |a Maurice, Sylvestre |4 oth | |
700 | 1 | |a Wiens, Roger C. |4 oth | |
700 | 1 | |a Bousquet, Bruno |4 oth | |
773 | 0 | 8 | |i Enthalten in |n Elsevier |a Li, Qiang ELSEVIER |t Dual stimuli-responsive polypeptide-calcium phosphate hybrid nanoparticles for co-delivery of multiple drugs in cancer therapy |d 2021 |g Amsterdam [u.a.] |w (DE-627)ELV005740053 |
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10.1016/j.sab.2021.106111 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001583.pica (DE-627)ELV053309782 (ELSEVIER)S0584-8547(21)00056-2 DE-627 ger DE-627 rakwb eng 540 VZ 42.15 bkl Clavé, Elise verfasserin aut Extending the potential of plasma-induced luminescence spectroscopy 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. Gaft, Michael oth Motto-Ros, Vincent oth Fabre, Cécile oth Forni, Olivier oth Beyssac, Olivier oth Maurice, Sylvestre oth Wiens, Roger C. oth Bousquet, Bruno oth Enthalten in Elsevier Li, Qiang ELSEVIER Dual stimuli-responsive polypeptide-calcium phosphate hybrid nanoparticles for co-delivery of multiple drugs in cancer therapy 2021 Amsterdam [u.a.] (DE-627)ELV005740053 volume:177 year:2021 pages:0 https://doi.org/10.1016/j.sab.2021.106111 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 42.15 Zellbiologie VZ AR 177 2021 0 |
spelling |
10.1016/j.sab.2021.106111 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001583.pica (DE-627)ELV053309782 (ELSEVIER)S0584-8547(21)00056-2 DE-627 ger DE-627 rakwb eng 540 VZ 42.15 bkl Clavé, Elise verfasserin aut Extending the potential of plasma-induced luminescence spectroscopy 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. Gaft, Michael oth Motto-Ros, Vincent oth Fabre, Cécile oth Forni, Olivier oth Beyssac, Olivier oth Maurice, Sylvestre oth Wiens, Roger C. oth Bousquet, Bruno oth Enthalten in Elsevier Li, Qiang ELSEVIER Dual stimuli-responsive polypeptide-calcium phosphate hybrid nanoparticles for co-delivery of multiple drugs in cancer therapy 2021 Amsterdam [u.a.] (DE-627)ELV005740053 volume:177 year:2021 pages:0 https://doi.org/10.1016/j.sab.2021.106111 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 42.15 Zellbiologie VZ AR 177 2021 0 |
allfields_unstemmed |
10.1016/j.sab.2021.106111 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001583.pica (DE-627)ELV053309782 (ELSEVIER)S0584-8547(21)00056-2 DE-627 ger DE-627 rakwb eng 540 VZ 42.15 bkl Clavé, Elise verfasserin aut Extending the potential of plasma-induced luminescence spectroscopy 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. Gaft, Michael oth Motto-Ros, Vincent oth Fabre, Cécile oth Forni, Olivier oth Beyssac, Olivier oth Maurice, Sylvestre oth Wiens, Roger C. oth Bousquet, Bruno oth Enthalten in Elsevier Li, Qiang ELSEVIER Dual stimuli-responsive polypeptide-calcium phosphate hybrid nanoparticles for co-delivery of multiple drugs in cancer therapy 2021 Amsterdam [u.a.] (DE-627)ELV005740053 volume:177 year:2021 pages:0 https://doi.org/10.1016/j.sab.2021.106111 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 42.15 Zellbiologie VZ AR 177 2021 0 |
allfieldsGer |
10.1016/j.sab.2021.106111 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001583.pica (DE-627)ELV053309782 (ELSEVIER)S0584-8547(21)00056-2 DE-627 ger DE-627 rakwb eng 540 VZ 42.15 bkl Clavé, Elise verfasserin aut Extending the potential of plasma-induced luminescence spectroscopy 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. Gaft, Michael oth Motto-Ros, Vincent oth Fabre, Cécile oth Forni, Olivier oth Beyssac, Olivier oth Maurice, Sylvestre oth Wiens, Roger C. oth Bousquet, Bruno oth Enthalten in Elsevier Li, Qiang ELSEVIER Dual stimuli-responsive polypeptide-calcium phosphate hybrid nanoparticles for co-delivery of multiple drugs in cancer therapy 2021 Amsterdam [u.a.] (DE-627)ELV005740053 volume:177 year:2021 pages:0 https://doi.org/10.1016/j.sab.2021.106111 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 42.15 Zellbiologie VZ AR 177 2021 0 |
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10.1016/j.sab.2021.106111 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001583.pica (DE-627)ELV053309782 (ELSEVIER)S0584-8547(21)00056-2 DE-627 ger DE-627 rakwb eng 540 VZ 42.15 bkl Clavé, Elise verfasserin aut Extending the potential of plasma-induced luminescence spectroscopy 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. Gaft, Michael oth Motto-Ros, Vincent oth Fabre, Cécile oth Forni, Olivier oth Beyssac, Olivier oth Maurice, Sylvestre oth Wiens, Roger C. oth Bousquet, Bruno oth Enthalten in Elsevier Li, Qiang ELSEVIER Dual stimuli-responsive polypeptide-calcium phosphate hybrid nanoparticles for co-delivery of multiple drugs in cancer therapy 2021 Amsterdam [u.a.] (DE-627)ELV005740053 volume:177 year:2021 pages:0 https://doi.org/10.1016/j.sab.2021.106111 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 42.15 Zellbiologie VZ AR 177 2021 0 |
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Clavé, Elise @@aut@@ Gaft, Michael @@oth@@ Motto-Ros, Vincent @@oth@@ Fabre, Cécile @@oth@@ Forni, Olivier @@oth@@ Beyssac, Olivier @@oth@@ Maurice, Sylvestre @@oth@@ Wiens, Roger C. @@oth@@ Bousquet, Bruno @@oth@@ |
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This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. 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extending the potential of plasma-induced luminescence spectroscopy |
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Extending the potential of plasma-induced luminescence spectroscopy |
abstract |
In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. |
abstractGer |
In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. |
abstract_unstemmed |
In the context of laser-induced breakdown spectroscopy (LIBS), plasma-induced luminescence (PIL) may be observed by tuning the temporal acquisition parameters (delay and gate). This approach provides useful information about minor elements in a sample. The broad range of excitation resulting from the laser-induced plasma enables the simultaneous observation of multiple luminescence emission bands. However, PIL results in damage to the sample due to laser ablation. Moreover, time resolution only enables the separation of emission signatures with different decay times; as a consequence, only luminescence signatures with long decay times may be observed separately from plasma emissions. In this study, we propose a new experimental approach to extend the potential of PIL spectroscopy. Our main idea is to generate a laser-induced plasma on a separate ablation target adjacent to the luminescent sample, which is hence protected from laser ablation. Moreover, the ablation target can be selected to ensure a stable plasma for PIL excitation. We also show that this setup enables the further study of the excitation mechanisms of PIL itself by varying the nature of the excitation source of PIL. Finally, we propose a new experimental setup that enables the study of the luminescence features of short decay times. We successfully tested this new approach on both artificial and natural crystals, showing luminescence emission bands of varying decay times. |
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Extending the potential of plasma-induced luminescence spectroscopy |
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https://doi.org/10.1016/j.sab.2021.106111 |
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Gaft, Michael Motto-Ros, Vincent Fabre, Cécile Forni, Olivier Beyssac, Olivier Maurice, Sylvestre Wiens, Roger C. Bousquet, Bruno |
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