The influence of Ca:CO3 stoichiometry on Ca isotope fractionation: Implications for process-based models of calcite growth
The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict...
Ausführliche Beschreibung
Autor*in: |
Mills, Jennifer V. [verfasserIn] |
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Englisch |
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2021transfer abstract |
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25 |
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Enthalten in: 109 Discovery of Novel DNA Methylation Markers for the Detection of Colorectal Neoplasia: Selection by Methylome-Wide Analysis - Taylor, William R. ELSEVIER, 2014, journal of the Geochemical Society and the Meteoritical Society, New York, NY [u.a.] |
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Übergeordnetes Werk: |
volume:298 ; year:2021 ; day:1 ; month:04 ; pages:87-111 ; extent:25 |
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DOI / URN: |
10.1016/j.gca.2021.01.016 |
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245 | 1 | 4 | |a The influence of Ca:CO3 stoichiometry on Ca isotope fractionation: Implications for process-based models of calcite growth |
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520 | |a The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. | ||
520 | |a The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. | ||
650 | 7 | |a Crystal growth |2 Elsevier | |
650 | 7 | |a Calcium isotope fractionation |2 Elsevier | |
650 | 7 | |a Kinetic isotope effect |2 Elsevier | |
650 | 7 | |a Calcite |2 Elsevier | |
700 | 1 | |a DePaolo, Donald J. |4 oth | |
700 | 1 | |a Lammers, Laura N. |4 oth | |
773 | 0 | 8 | |i Enthalten in |n Elsevier |a Taylor, William R. ELSEVIER |t 109 Discovery of Novel DNA Methylation Markers for the Detection of Colorectal Neoplasia: Selection by Methylome-Wide Analysis |d 2014 |d journal of the Geochemical Society and the Meteoritical Society |g New York, NY [u.a.] |w (DE-627)ELV012653268 |
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10.1016/j.gca.2021.01.016 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001321.pica (DE-627)ELV053330773 (ELSEVIER)S0016-7037(21)00038-7 DE-627 ger DE-627 rakwb eng 610 VZ 570 VZ BIODIV DE-30 fid 35.70 bkl 42.12 bkl 42.15 bkl Mills, Jennifer V. verfasserin aut The influence of Ca:CO3 stoichiometry on Ca isotope fractionation: Implications for process-based models of calcite growth 2021transfer abstract 25 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. Crystal growth Elsevier Calcium isotope fractionation Elsevier Kinetic isotope effect Elsevier Calcite Elsevier DePaolo, Donald J. oth Lammers, Laura N. oth Enthalten in Elsevier Taylor, William R. ELSEVIER 109 Discovery of Novel DNA Methylation Markers for the Detection of Colorectal Neoplasia: Selection by Methylome-Wide Analysis 2014 journal of the Geochemical Society and the Meteoritical Society New York, NY [u.a.] (DE-627)ELV012653268 volume:298 year:2021 day:1 month:04 pages:87-111 extent:25 https://doi.org/10.1016/j.gca.2021.01.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV SSG-OLC-PHA 35.70 Biochemie: Allgemeines VZ 42.12 Biophysik VZ 42.15 Zellbiologie VZ AR 298 2021 1 0401 87-111 25 |
spelling |
10.1016/j.gca.2021.01.016 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001321.pica (DE-627)ELV053330773 (ELSEVIER)S0016-7037(21)00038-7 DE-627 ger DE-627 rakwb eng 610 VZ 570 VZ BIODIV DE-30 fid 35.70 bkl 42.12 bkl 42.15 bkl Mills, Jennifer V. verfasserin aut The influence of Ca:CO3 stoichiometry on Ca isotope fractionation: Implications for process-based models of calcite growth 2021transfer abstract 25 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. Crystal growth Elsevier Calcium isotope fractionation Elsevier Kinetic isotope effect Elsevier Calcite Elsevier DePaolo, Donald J. oth Lammers, Laura N. oth Enthalten in Elsevier Taylor, William R. ELSEVIER 109 Discovery of Novel DNA Methylation Markers for the Detection of Colorectal Neoplasia: Selection by Methylome-Wide Analysis 2014 journal of the Geochemical Society and the Meteoritical Society New York, NY [u.a.] (DE-627)ELV012653268 volume:298 year:2021 day:1 month:04 pages:87-111 extent:25 https://doi.org/10.1016/j.gca.2021.01.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV SSG-OLC-PHA 35.70 Biochemie: Allgemeines VZ 42.12 Biophysik VZ 42.15 Zellbiologie VZ AR 298 2021 1 0401 87-111 25 |
allfields_unstemmed |
10.1016/j.gca.2021.01.016 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001321.pica (DE-627)ELV053330773 (ELSEVIER)S0016-7037(21)00038-7 DE-627 ger DE-627 rakwb eng 610 VZ 570 VZ BIODIV DE-30 fid 35.70 bkl 42.12 bkl 42.15 bkl Mills, Jennifer V. verfasserin aut The influence of Ca:CO3 stoichiometry on Ca isotope fractionation: Implications for process-based models of calcite growth 2021transfer abstract 25 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. Crystal growth Elsevier Calcium isotope fractionation Elsevier Kinetic isotope effect Elsevier Calcite Elsevier DePaolo, Donald J. oth Lammers, Laura N. oth Enthalten in Elsevier Taylor, William R. ELSEVIER 109 Discovery of Novel DNA Methylation Markers for the Detection of Colorectal Neoplasia: Selection by Methylome-Wide Analysis 2014 journal of the Geochemical Society and the Meteoritical Society New York, NY [u.a.] (DE-627)ELV012653268 volume:298 year:2021 day:1 month:04 pages:87-111 extent:25 https://doi.org/10.1016/j.gca.2021.01.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV SSG-OLC-PHA 35.70 Biochemie: Allgemeines VZ 42.12 Biophysik VZ 42.15 Zellbiologie VZ AR 298 2021 1 0401 87-111 25 |
allfieldsGer |
10.1016/j.gca.2021.01.016 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001321.pica (DE-627)ELV053330773 (ELSEVIER)S0016-7037(21)00038-7 DE-627 ger DE-627 rakwb eng 610 VZ 570 VZ BIODIV DE-30 fid 35.70 bkl 42.12 bkl 42.15 bkl Mills, Jennifer V. verfasserin aut The influence of Ca:CO3 stoichiometry on Ca isotope fractionation: Implications for process-based models of calcite growth 2021transfer abstract 25 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. Crystal growth Elsevier Calcium isotope fractionation Elsevier Kinetic isotope effect Elsevier Calcite Elsevier DePaolo, Donald J. oth Lammers, Laura N. oth Enthalten in Elsevier Taylor, William R. ELSEVIER 109 Discovery of Novel DNA Methylation Markers for the Detection of Colorectal Neoplasia: Selection by Methylome-Wide Analysis 2014 journal of the Geochemical Society and the Meteoritical Society New York, NY [u.a.] (DE-627)ELV012653268 volume:298 year:2021 day:1 month:04 pages:87-111 extent:25 https://doi.org/10.1016/j.gca.2021.01.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV SSG-OLC-PHA 35.70 Biochemie: Allgemeines VZ 42.12 Biophysik VZ 42.15 Zellbiologie VZ AR 298 2021 1 0401 87-111 25 |
allfieldsSound |
10.1016/j.gca.2021.01.016 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001321.pica (DE-627)ELV053330773 (ELSEVIER)S0016-7037(21)00038-7 DE-627 ger DE-627 rakwb eng 610 VZ 570 VZ BIODIV DE-30 fid 35.70 bkl 42.12 bkl 42.15 bkl Mills, Jennifer V. verfasserin aut The influence of Ca:CO3 stoichiometry on Ca isotope fractionation: Implications for process-based models of calcite growth 2021transfer abstract 25 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. Crystal growth Elsevier Calcium isotope fractionation Elsevier Kinetic isotope effect Elsevier Calcite Elsevier DePaolo, Donald J. oth Lammers, Laura N. oth Enthalten in Elsevier Taylor, William R. ELSEVIER 109 Discovery of Novel DNA Methylation Markers for the Detection of Colorectal Neoplasia: Selection by Methylome-Wide Analysis 2014 journal of the Geochemical Society and the Meteoritical Society New York, NY [u.a.] (DE-627)ELV012653268 volume:298 year:2021 day:1 month:04 pages:87-111 extent:25 https://doi.org/10.1016/j.gca.2021.01.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV SSG-OLC-PHA 35.70 Biochemie: Allgemeines VZ 42.12 Biophysik VZ 42.15 Zellbiologie VZ AR 298 2021 1 0401 87-111 25 |
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Enthalten in 109 Discovery of Novel DNA Methylation Markers for the Detection of Colorectal Neoplasia: Selection by Methylome-Wide Analysis New York, NY [u.a.] volume:298 year:2021 day:1 month:04 pages:87-111 extent:25 |
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Enthalten in 109 Discovery of Novel DNA Methylation Markers for the Detection of Colorectal Neoplasia: Selection by Methylome-Wide Analysis New York, NY [u.a.] volume:298 year:2021 day:1 month:04 pages:87-111 extent:25 |
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109 Discovery of Novel DNA Methylation Markers for the Detection of Colorectal Neoplasia: Selection by Methylome-Wide Analysis |
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influence of ca:co3 stoichiometry on ca isotope fractionation: implications for process-based models of calcite growth |
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The influence of Ca:CO3 stoichiometry on Ca isotope fractionation: Implications for process-based models of calcite growth |
abstract |
The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. |
abstractGer |
The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. |
abstract_unstemmed |
The solution stoichiometry dependence of calcium isotope fractionation during calcite precipitation was investigated as a direct test of the conceptual model of calcium isotope discrimination driven by Ca exchange at surface sites during growth. Classical ion-by-ion models of calcite growth predict a strong solution stoichiometry influence on Δ44/40Cacalcite-fluid: In low Ca2+:CO3 2– solutions,Δ44/40Cais predicted to approach a kinetic limit (∼−2 to −4‰), while in high Ca2+:CO3 2– solutions, exchange at dominantly Ca-occupied kink sites drives Δ44/40Catowards the equilibrium fractionation (near 0‰). To test thisprediction,a series ofseeded and unseeded constant composition calcite growth experiments were performed in which all aspects of solution chemistry were held constant and the Ca2+:CO3 2– activity ratio was varied. Experiments were performed at pH 8.5, ionic strength 0.1 M (adjusted with KCl), and calcite saturation index (SI = log10({Ca2+}{CO3 2–}/Ksp)) of either 0.5 or 0.8. |
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title_short |
The influence of Ca:CO3 stoichiometry on Ca isotope fractionation: Implications for process-based models of calcite growth |
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https://doi.org/10.1016/j.gca.2021.01.016 |
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