Gas transport parameters, density and free volume of nanocrystalline poly-2,6-dimethylphenylene oxide
Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface ar...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Alentiev, A.Yu [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021transfer abstract |
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| Übergeordnetes Werk: |
Enthalten in: Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study - Fitzgerald, Emily ELSEVIER, 2020, the international journal for the science and technology of polymers, Oxford |
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| Übergeordnetes Werk: |
volume:226 ; year:2021 ; day:4 ; month:06 ; pages:0 |
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| DOI / URN: |
10.1016/j.polymer.2021.123804 |
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| 520 | |a Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. | ||
| 520 | |a Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. | ||
| 650 | 7 | |a poly(phenylene oxide) |2 Elsevier | |
| 650 | 7 | |a Semi-crystalline polymers |2 Elsevier | |
| 700 | 1 | |a Levin, I.S. |4 oth | |
| 700 | 1 | |a Buzin, M.I. |4 oth | |
| 700 | 1 | |a Belov, N.A. |4 oth | |
| 700 | 1 | |a Nikiforov, R.Yu |4 oth | |
| 700 | 1 | |a Chirkov, S.V. |4 oth | |
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| 700 | 1 | |a Kechekyan, P.A. |4 oth | |
| 700 | 1 | |a Bekeshev, V.G. |4 oth | |
| 700 | 1 | |a Ryzhikh, V.E. |4 oth | |
| 700 | 1 | |a Yampolskii, Yu.P. |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier Science |a Fitzgerald, Emily ELSEVIER |t Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study |d 2020 |d the international journal for the science and technology of polymers |g Oxford |w (DE-627)ELV005093368 |
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10.1016/j.polymer.2021.123804 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001613.pica (DE-627)ELV054119812 (ELSEVIER)S0032-3861(21)00427-4 DE-627 ger DE-627 rakwb eng 610 VZ 44.63 bkl 44.69 bkl Alentiev, A.Yu verfasserin aut Gas transport parameters, density and free volume of nanocrystalline poly-2,6-dimethylphenylene oxide 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. poly(phenylene oxide) Elsevier Semi-crystalline polymers Elsevier Levin, I.S. oth Buzin, M.I. oth Belov, N.A. oth Nikiforov, R.Yu oth Chirkov, S.V. oth Blagodatskikh, I.V. oth Kechekyan, A.S. oth Kechekyan, P.A. oth Bekeshev, V.G. oth Ryzhikh, V.E. oth Yampolskii, Yu.P. oth Enthalten in Elsevier Science Fitzgerald, Emily ELSEVIER Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study 2020 the international journal for the science and technology of polymers Oxford (DE-627)ELV005093368 volume:226 year:2021 day:4 month:06 pages:0 https://doi.org/10.1016/j.polymer.2021.123804 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.63 Krankenpflege VZ 44.69 Intensivmedizin VZ AR 226 2021 4 0604 0 |
| spelling |
10.1016/j.polymer.2021.123804 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001613.pica (DE-627)ELV054119812 (ELSEVIER)S0032-3861(21)00427-4 DE-627 ger DE-627 rakwb eng 610 VZ 44.63 bkl 44.69 bkl Alentiev, A.Yu verfasserin aut Gas transport parameters, density and free volume of nanocrystalline poly-2,6-dimethylphenylene oxide 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. poly(phenylene oxide) Elsevier Semi-crystalline polymers Elsevier Levin, I.S. oth Buzin, M.I. oth Belov, N.A. oth Nikiforov, R.Yu oth Chirkov, S.V. oth Blagodatskikh, I.V. oth Kechekyan, A.S. oth Kechekyan, P.A. oth Bekeshev, V.G. oth Ryzhikh, V.E. oth Yampolskii, Yu.P. oth Enthalten in Elsevier Science Fitzgerald, Emily ELSEVIER Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study 2020 the international journal for the science and technology of polymers Oxford (DE-627)ELV005093368 volume:226 year:2021 day:4 month:06 pages:0 https://doi.org/10.1016/j.polymer.2021.123804 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.63 Krankenpflege VZ 44.69 Intensivmedizin VZ AR 226 2021 4 0604 0 |
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10.1016/j.polymer.2021.123804 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001613.pica (DE-627)ELV054119812 (ELSEVIER)S0032-3861(21)00427-4 DE-627 ger DE-627 rakwb eng 610 VZ 44.63 bkl 44.69 bkl Alentiev, A.Yu verfasserin aut Gas transport parameters, density and free volume of nanocrystalline poly-2,6-dimethylphenylene oxide 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. poly(phenylene oxide) Elsevier Semi-crystalline polymers Elsevier Levin, I.S. oth Buzin, M.I. oth Belov, N.A. oth Nikiforov, R.Yu oth Chirkov, S.V. oth Blagodatskikh, I.V. oth Kechekyan, A.S. oth Kechekyan, P.A. oth Bekeshev, V.G. oth Ryzhikh, V.E. oth Yampolskii, Yu.P. oth Enthalten in Elsevier Science Fitzgerald, Emily ELSEVIER Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study 2020 the international journal for the science and technology of polymers Oxford (DE-627)ELV005093368 volume:226 year:2021 day:4 month:06 pages:0 https://doi.org/10.1016/j.polymer.2021.123804 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.63 Krankenpflege VZ 44.69 Intensivmedizin VZ AR 226 2021 4 0604 0 |
| allfieldsGer |
10.1016/j.polymer.2021.123804 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001613.pica (DE-627)ELV054119812 (ELSEVIER)S0032-3861(21)00427-4 DE-627 ger DE-627 rakwb eng 610 VZ 44.63 bkl 44.69 bkl Alentiev, A.Yu verfasserin aut Gas transport parameters, density and free volume of nanocrystalline poly-2,6-dimethylphenylene oxide 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. poly(phenylene oxide) Elsevier Semi-crystalline polymers Elsevier Levin, I.S. oth Buzin, M.I. oth Belov, N.A. oth Nikiforov, R.Yu oth Chirkov, S.V. oth Blagodatskikh, I.V. oth Kechekyan, A.S. oth Kechekyan, P.A. oth Bekeshev, V.G. oth Ryzhikh, V.E. oth Yampolskii, Yu.P. oth Enthalten in Elsevier Science Fitzgerald, Emily ELSEVIER Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study 2020 the international journal for the science and technology of polymers Oxford (DE-627)ELV005093368 volume:226 year:2021 day:4 month:06 pages:0 https://doi.org/10.1016/j.polymer.2021.123804 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.63 Krankenpflege VZ 44.69 Intensivmedizin VZ AR 226 2021 4 0604 0 |
| allfieldsSound |
10.1016/j.polymer.2021.123804 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001613.pica (DE-627)ELV054119812 (ELSEVIER)S0032-3861(21)00427-4 DE-627 ger DE-627 rakwb eng 610 VZ 44.63 bkl 44.69 bkl Alentiev, A.Yu verfasserin aut Gas transport parameters, density and free volume of nanocrystalline poly-2,6-dimethylphenylene oxide 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. poly(phenylene oxide) Elsevier Semi-crystalline polymers Elsevier Levin, I.S. oth Buzin, M.I. oth Belov, N.A. oth Nikiforov, R.Yu oth Chirkov, S.V. oth Blagodatskikh, I.V. oth Kechekyan, A.S. oth Kechekyan, P.A. oth Bekeshev, V.G. oth Ryzhikh, V.E. oth Yampolskii, Yu.P. oth Enthalten in Elsevier Science Fitzgerald, Emily ELSEVIER Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study 2020 the international journal for the science and technology of polymers Oxford (DE-627)ELV005093368 volume:226 year:2021 day:4 month:06 pages:0 https://doi.org/10.1016/j.polymer.2021.123804 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.63 Krankenpflege VZ 44.69 Intensivmedizin VZ AR 226 2021 4 0604 0 |
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Enthalten in Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study Oxford volume:226 year:2021 day:4 month:06 pages:0 |
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Enthalten in Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study Oxford volume:226 year:2021 day:4 month:06 pages:0 |
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Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study |
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Alentiev, A.Yu @@aut@@ Levin, I.S. @@oth@@ Buzin, M.I. @@oth@@ Belov, N.A. @@oth@@ Nikiforov, R.Yu @@oth@@ Chirkov, S.V. @@oth@@ Blagodatskikh, I.V. @@oth@@ Kechekyan, A.S. @@oth@@ Kechekyan, P.A. @@oth@@ Bekeshev, V.G. @@oth@@ Ryzhikh, V.E. @@oth@@ Yampolskii, Yu.P. @@oth@@ |
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Gas transport parameters, density and free volume of nanocrystalline poly-2,6-dimethylphenylene oxide |
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Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. |
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Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. |
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Poly(2,6-dimethylphenylene oxide-1,4) (PPO) belongs to a fairly investigated group of polymers that, nevertheless, provokes permanent research interest. The current study is focused on a combination of various physicochemical methods of polymer testing (DSC; molecular weight distribution; surface area by low-temperature adsorption isotherms of nitrogen and carbon dioxide; X-Ray diffraction analysis; hydrostatic measurement of density; gas permeability and diffusion measurement) with variation of molecular weight and different states of polymer samples (amorphous, semi-crystalline, biaxial-oriented). The alteration of the density, gas permeability and diffusion parameters is evaluated through modeling of PPO as a polymer-polymer blend material with amorphous, nano-sized crystalline (≤7 nm), and so-called rigid amorphous fraction (RAF) phases. The estimation of the phase properties of PPO samples allows to conclude that the permeability and diffusion characteristics decline in a row crystalline > amorphous > RAF. |
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