First approaches for hydrogen production by the depolarized electrolysis of SO2 using phosphoric acid doped polybenzimidazole membranes
Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high tem...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Díaz-Abad, Sergio [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021transfer abstract |
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| Schlagwörter: |
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| Umfang: |
11 |
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| Übergeordnetes Werk: |
Enthalten in: External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs - Dedhia, Kavita ELSEVIER, 2018, official journal of the International Association for Hydrogen Energy, New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:46 ; year:2021 ; number:58 ; day:23 ; month:08 ; pages:29763-29773 ; extent:11 |
| Links: |
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| DOI / URN: |
10.1016/j.ijhydene.2021.06.117 |
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| 245 | 1 | 0 | |a First approaches for hydrogen production by the depolarized electrolysis of SO2 using phosphoric acid doped polybenzimidazole membranes |
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| 520 | |a Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. | ||
| 520 | |a Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. | ||
| 650 | 7 | |a Hydrogen |2 Elsevier | |
| 650 | 7 | |a Ohmic resistance |2 Elsevier | |
| 650 | 7 | |a Polybenzimidazole (PBI) |2 Elsevier | |
| 650 | 7 | |a SO2 electrolysis |2 Elsevier | |
| 700 | 1 | |a Rodrigo, Manuel A. |4 oth | |
| 700 | 1 | |a Lobato, Justo |4 oth | |
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10.1016/j.ijhydene.2021.06.117 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001479.pica (DE-627)ELV054861853 (ELSEVIER)S0360-3199(21)02321-1 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Díaz-Abad, Sergio verfasserin aut First approaches for hydrogen production by the depolarized electrolysis of SO2 using phosphoric acid doped polybenzimidazole membranes 2021transfer abstract 11 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. Hydrogen Elsevier Ohmic resistance Elsevier Polybenzimidazole (PBI) Elsevier SO2 electrolysis Elsevier Rodrigo, Manuel A. oth Lobato, Justo oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:46 year:2021 number:58 day:23 month:08 pages:29763-29773 extent:11 https://doi.org/10.1016/j.ijhydene.2021.06.117 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 46 2021 58 23 0823 29763-29773 11 |
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10.1016/j.ijhydene.2021.06.117 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001479.pica (DE-627)ELV054861853 (ELSEVIER)S0360-3199(21)02321-1 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Díaz-Abad, Sergio verfasserin aut First approaches for hydrogen production by the depolarized electrolysis of SO2 using phosphoric acid doped polybenzimidazole membranes 2021transfer abstract 11 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. Hydrogen Elsevier Ohmic resistance Elsevier Polybenzimidazole (PBI) Elsevier SO2 electrolysis Elsevier Rodrigo, Manuel A. oth Lobato, Justo oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:46 year:2021 number:58 day:23 month:08 pages:29763-29773 extent:11 https://doi.org/10.1016/j.ijhydene.2021.06.117 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 46 2021 58 23 0823 29763-29773 11 |
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10.1016/j.ijhydene.2021.06.117 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001479.pica (DE-627)ELV054861853 (ELSEVIER)S0360-3199(21)02321-1 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Díaz-Abad, Sergio verfasserin aut First approaches for hydrogen production by the depolarized electrolysis of SO2 using phosphoric acid doped polybenzimidazole membranes 2021transfer abstract 11 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. Hydrogen Elsevier Ohmic resistance Elsevier Polybenzimidazole (PBI) Elsevier SO2 electrolysis Elsevier Rodrigo, Manuel A. oth Lobato, Justo oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:46 year:2021 number:58 day:23 month:08 pages:29763-29773 extent:11 https://doi.org/10.1016/j.ijhydene.2021.06.117 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 46 2021 58 23 0823 29763-29773 11 |
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10.1016/j.ijhydene.2021.06.117 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001479.pica (DE-627)ELV054861853 (ELSEVIER)S0360-3199(21)02321-1 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Díaz-Abad, Sergio verfasserin aut First approaches for hydrogen production by the depolarized electrolysis of SO2 using phosphoric acid doped polybenzimidazole membranes 2021transfer abstract 11 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. Hydrogen Elsevier Ohmic resistance Elsevier Polybenzimidazole (PBI) Elsevier SO2 electrolysis Elsevier Rodrigo, Manuel A. oth Lobato, Justo oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:46 year:2021 number:58 day:23 month:08 pages:29763-29773 extent:11 https://doi.org/10.1016/j.ijhydene.2021.06.117 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 46 2021 58 23 0823 29763-29773 11 |
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10.1016/j.ijhydene.2021.06.117 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001479.pica (DE-627)ELV054861853 (ELSEVIER)S0360-3199(21)02321-1 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Díaz-Abad, Sergio verfasserin aut First approaches for hydrogen production by the depolarized electrolysis of SO2 using phosphoric acid doped polybenzimidazole membranes 2021transfer abstract 11 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. Hydrogen Elsevier Ohmic resistance Elsevier Polybenzimidazole (PBI) Elsevier SO2 electrolysis Elsevier Rodrigo, Manuel A. oth Lobato, Justo oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:46 year:2021 number:58 day:23 month:08 pages:29763-29773 extent:11 https://doi.org/10.1016/j.ijhydene.2021.06.117 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 46 2021 58 23 0823 29763-29773 11 |
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Enthalten in External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs New York, NY [u.a.] volume:46 year:2021 number:58 day:23 month:08 pages:29763-29773 extent:11 |
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Enthalten in External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs New York, NY [u.a.] volume:46 year:2021 number:58 day:23 month:08 pages:29763-29773 extent:11 |
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Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. 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First approaches for hydrogen production by the depolarized electrolysis of SO2 using phosphoric acid doped polybenzimidazole membranes |
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Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. |
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Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. |
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Renewable energy storage and conversion is nowadays a major target for the scientific community. Their conversion into hydrogen is a clear and clean alternative for their storage. This work shows, for the first time, the results of the SO2 depolarized electrolysis for hydrogen production at high temperature (120–170 °C) using phosphoric acid doped polybenzimidazole (PBI) membranes. A standard and a thermally cure PBI membrane doped with phosphoric acid were used for manufacturing the MEA of two electrolyzers. The benefit of the temperature was demonstrated but an unexpected behavior occurs at voltages higher than 0.8 V when temperature increases. Moreover, the thermally cured membrane shows a superior performance as compared with the standard one. Production of sulfur by reduction of SO2 becomes an important drawback and advices not operating above 130 °C. Results show that PBI membranes doped with phosphoric acid are suitable for high temperature operation for the sulfur dioxide depolarized electrolysis. Increasing temperature is beneficial up to a certain value of potential, showing a considerable influence in the charge transfer resistance of the system. |
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