Fluorescent and mechanical properties of UiO-66/PA composite membrane
The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of t...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Yang, Fan [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021transfer abstract |
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| Übergeordnetes Werk: |
Enthalten in: Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface - Ren, Guoqing ELSEVIER, 2018, an international journal devoted to the principles and applications of colloid and interface science, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:627 ; year:2021 ; day:20 ; month:10 ; pages:0 |
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| DOI / URN: |
10.1016/j.colsurfa.2021.127083 |
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| 520 | |a The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. | ||
| 520 | |a The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. | ||
| 650 | 7 | |a Fluorescence properties |2 Elsevier | |
| 650 | 7 | |a Mechanical properties |2 Elsevier | |
| 650 | 7 | |a MOFs |2 Elsevier | |
| 650 | 7 | |a Polyacrylate |2 Elsevier | |
| 700 | 1 | |a Ma, Jianzhong |4 oth | |
| 700 | 1 | |a Zhu, Qian |4 oth | |
| 700 | 1 | |a Qin, Jianbin |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier Science |a Ren, Guoqing ELSEVIER |t Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface |d 2018 |d an international journal devoted to the principles and applications of colloid and interface science |g Amsterdam [u.a.] |w (DE-627)ELV003763498 |
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10.1016/j.colsurfa.2021.127083 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001586.pica (DE-627)ELV05516854X (ELSEVIER)S0927-7757(21)00952-3 DE-627 ger DE-627 rakwb eng 540 VZ 35.10 bkl Yang, Fan verfasserin aut Fluorescent and mechanical properties of UiO-66/PA composite membrane 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. Fluorescence properties Elsevier Mechanical properties Elsevier MOFs Elsevier Polyacrylate Elsevier Ma, Jianzhong oth Zhu, Qian oth Qin, Jianbin oth Enthalten in Elsevier Science Ren, Guoqing ELSEVIER Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface 2018 an international journal devoted to the principles and applications of colloid and interface science Amsterdam [u.a.] (DE-627)ELV003763498 volume:627 year:2021 day:20 month:10 pages:0 https://doi.org/10.1016/j.colsurfa.2021.127083 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 627 2021 20 1020 0 |
| spelling |
10.1016/j.colsurfa.2021.127083 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001586.pica (DE-627)ELV05516854X (ELSEVIER)S0927-7757(21)00952-3 DE-627 ger DE-627 rakwb eng 540 VZ 35.10 bkl Yang, Fan verfasserin aut Fluorescent and mechanical properties of UiO-66/PA composite membrane 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. Fluorescence properties Elsevier Mechanical properties Elsevier MOFs Elsevier Polyacrylate Elsevier Ma, Jianzhong oth Zhu, Qian oth Qin, Jianbin oth Enthalten in Elsevier Science Ren, Guoqing ELSEVIER Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface 2018 an international journal devoted to the principles and applications of colloid and interface science Amsterdam [u.a.] (DE-627)ELV003763498 volume:627 year:2021 day:20 month:10 pages:0 https://doi.org/10.1016/j.colsurfa.2021.127083 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 627 2021 20 1020 0 |
| allfields_unstemmed |
10.1016/j.colsurfa.2021.127083 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001586.pica (DE-627)ELV05516854X (ELSEVIER)S0927-7757(21)00952-3 DE-627 ger DE-627 rakwb eng 540 VZ 35.10 bkl Yang, Fan verfasserin aut Fluorescent and mechanical properties of UiO-66/PA composite membrane 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. Fluorescence properties Elsevier Mechanical properties Elsevier MOFs Elsevier Polyacrylate Elsevier Ma, Jianzhong oth Zhu, Qian oth Qin, Jianbin oth Enthalten in Elsevier Science Ren, Guoqing ELSEVIER Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface 2018 an international journal devoted to the principles and applications of colloid and interface science Amsterdam [u.a.] (DE-627)ELV003763498 volume:627 year:2021 day:20 month:10 pages:0 https://doi.org/10.1016/j.colsurfa.2021.127083 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 627 2021 20 1020 0 |
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10.1016/j.colsurfa.2021.127083 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001586.pica (DE-627)ELV05516854X (ELSEVIER)S0927-7757(21)00952-3 DE-627 ger DE-627 rakwb eng 540 VZ 35.10 bkl Yang, Fan verfasserin aut Fluorescent and mechanical properties of UiO-66/PA composite membrane 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. Fluorescence properties Elsevier Mechanical properties Elsevier MOFs Elsevier Polyacrylate Elsevier Ma, Jianzhong oth Zhu, Qian oth Qin, Jianbin oth Enthalten in Elsevier Science Ren, Guoqing ELSEVIER Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface 2018 an international journal devoted to the principles and applications of colloid and interface science Amsterdam [u.a.] (DE-627)ELV003763498 volume:627 year:2021 day:20 month:10 pages:0 https://doi.org/10.1016/j.colsurfa.2021.127083 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 627 2021 20 1020 0 |
| allfieldsSound |
10.1016/j.colsurfa.2021.127083 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001586.pica (DE-627)ELV05516854X (ELSEVIER)S0927-7757(21)00952-3 DE-627 ger DE-627 rakwb eng 540 VZ 35.10 bkl Yang, Fan verfasserin aut Fluorescent and mechanical properties of UiO-66/PA composite membrane 2021transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. Fluorescence properties Elsevier Mechanical properties Elsevier MOFs Elsevier Polyacrylate Elsevier Ma, Jianzhong oth Zhu, Qian oth Qin, Jianbin oth Enthalten in Elsevier Science Ren, Guoqing ELSEVIER Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface 2018 an international journal devoted to the principles and applications of colloid and interface science Amsterdam [u.a.] (DE-627)ELV003763498 volume:627 year:2021 day:20 month:10 pages:0 https://doi.org/10.1016/j.colsurfa.2021.127083 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 627 2021 20 1020 0 |
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Enthalten in Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface Amsterdam [u.a.] volume:627 year:2021 day:20 month:10 pages:0 |
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In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. 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Fluorescent and mechanical properties of UiO-66/PA composite membrane |
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The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. |
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The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. |
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The narrow use and poor mechanical properties of flexible polymers limit its further development. In this paper, the addition of a new type of MOFs material UiO-66 to the flexible polyacrylate polymer not only gives the polymer fluorescence properties but also enhances the mechanical properties of the polymer. This paper mainly studies the effects of different functional groups on the fluorescence properties of UiO-66 and the influence of the interface between UiO-66 and the polymer matrix. The experimental analysis of morphology and chemical structure showed that UiO-66-x and its composite membranes with different functional groups were successfully prepared. A series of comprehensive studies have shown that the fluorescence properties of UiO-66-x with different functional groups are different, which is mainly due to the different conjugated structure of the system. The composite film introduced with UiO-66-x not only has fluorescent properties, but also has excellent mechanical properties, thermal stability and solvent stability. The increase in mechanical properties is mainly attributed to the interaction between nanoparticles and polymers. Finally, molecular dynamics simulations are used to confirm the interaction between nanoparticles and polymers. At the same time, the current work can provide a convenient example for the application of metal organic framework (MOF) in enhancing the fluorescence and mechanical properties of polymers. |
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