S/Se-embedded acenaphthylene-imide-containing polycyclic heteroaromatic hydrocarbon
Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Wang, Zhichao [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022transfer abstract |
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| Umfang: |
5 |
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| Übergeordnetes Werk: |
Enthalten in: Enhanced upconversion emission and magnetization in Yb3+-Er3+/Ho3+ codoped Gd2O3 nanocrystals by introducing Zn2+ ions - Li, Daguang ELSEVIER, 2016, Beijing |
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| Übergeordnetes Werk: |
volume:33 ; year:2022 ; number:1 ; pages:271-275 ; extent:5 |
| Links: |
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| DOI / URN: |
10.1016/j.cclet.2021.06.072 |
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| 520 | |a Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. | ||
| 520 | |a Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. | ||
| 700 | 1 | |a Ma, Qianli |4 oth | |
| 700 | 1 | |a Huang, Xuan |4 oth | |
| 700 | 1 | |a Zhang, Tian |4 oth | |
| 700 | 1 | |a Shao, Jiawei |4 oth | |
| 700 | 1 | |a Zhang, Xinglin |4 oth | |
| 700 | 1 | |a Shen, Qian |4 oth | |
| 700 | 1 | |a Wang, Xiaochen |4 oth | |
| 700 | 1 | |a Shao, Jinjun |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Institute of Materia Medica |a Li, Daguang ELSEVIER |t Enhanced upconversion emission and magnetization in Yb3+-Er3+/Ho3+ codoped Gd2O3 nanocrystals by introducing Zn2+ ions |d 2016 |g Beijing |w (DE-627)ELV014303019 |
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10.1016/j.cclet.2021.06.072 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001652.pica (DE-627)ELV056590814 (ELSEVIER)S1001-8417(21)00472-1 DE-627 ger DE-627 rakwb eng 670 VZ 540 VZ 630 VZ Wang, Zhichao verfasserin aut S/Se-embedded acenaphthylene-imide-containing polycyclic heteroaromatic hydrocarbon 2022transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. Ma, Qianli oth Huang, Xuan oth Zhang, Tian oth Shao, Jiawei oth Zhang, Xinglin oth Shen, Qian oth Wang, Xiaochen oth Shao, Jinjun oth Enthalten in Institute of Materia Medica Li, Daguang ELSEVIER Enhanced upconversion emission and magnetization in Yb3+-Er3+/Ho3+ codoped Gd2O3 nanocrystals by introducing Zn2+ ions 2016 Beijing (DE-627)ELV014303019 volume:33 year:2022 number:1 pages:271-275 extent:5 https://doi.org/10.1016/j.cclet.2021.06.072 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 GBV_ILN_69 AR 33 2022 1 271-275 5 |
| spelling |
10.1016/j.cclet.2021.06.072 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001652.pica (DE-627)ELV056590814 (ELSEVIER)S1001-8417(21)00472-1 DE-627 ger DE-627 rakwb eng 670 VZ 540 VZ 630 VZ Wang, Zhichao verfasserin aut S/Se-embedded acenaphthylene-imide-containing polycyclic heteroaromatic hydrocarbon 2022transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. Ma, Qianli oth Huang, Xuan oth Zhang, Tian oth Shao, Jiawei oth Zhang, Xinglin oth Shen, Qian oth Wang, Xiaochen oth Shao, Jinjun oth Enthalten in Institute of Materia Medica Li, Daguang ELSEVIER Enhanced upconversion emission and magnetization in Yb3+-Er3+/Ho3+ codoped Gd2O3 nanocrystals by introducing Zn2+ ions 2016 Beijing (DE-627)ELV014303019 volume:33 year:2022 number:1 pages:271-275 extent:5 https://doi.org/10.1016/j.cclet.2021.06.072 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 GBV_ILN_69 AR 33 2022 1 271-275 5 |
| allfields_unstemmed |
10.1016/j.cclet.2021.06.072 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001652.pica (DE-627)ELV056590814 (ELSEVIER)S1001-8417(21)00472-1 DE-627 ger DE-627 rakwb eng 670 VZ 540 VZ 630 VZ Wang, Zhichao verfasserin aut S/Se-embedded acenaphthylene-imide-containing polycyclic heteroaromatic hydrocarbon 2022transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. Ma, Qianli oth Huang, Xuan oth Zhang, Tian oth Shao, Jiawei oth Zhang, Xinglin oth Shen, Qian oth Wang, Xiaochen oth Shao, Jinjun oth Enthalten in Institute of Materia Medica Li, Daguang ELSEVIER Enhanced upconversion emission and magnetization in Yb3+-Er3+/Ho3+ codoped Gd2O3 nanocrystals by introducing Zn2+ ions 2016 Beijing (DE-627)ELV014303019 volume:33 year:2022 number:1 pages:271-275 extent:5 https://doi.org/10.1016/j.cclet.2021.06.072 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 GBV_ILN_69 AR 33 2022 1 271-275 5 |
| allfieldsGer |
10.1016/j.cclet.2021.06.072 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001652.pica (DE-627)ELV056590814 (ELSEVIER)S1001-8417(21)00472-1 DE-627 ger DE-627 rakwb eng 670 VZ 540 VZ 630 VZ Wang, Zhichao verfasserin aut S/Se-embedded acenaphthylene-imide-containing polycyclic heteroaromatic hydrocarbon 2022transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. Ma, Qianli oth Huang, Xuan oth Zhang, Tian oth Shao, Jiawei oth Zhang, Xinglin oth Shen, Qian oth Wang, Xiaochen oth Shao, Jinjun oth Enthalten in Institute of Materia Medica Li, Daguang ELSEVIER Enhanced upconversion emission and magnetization in Yb3+-Er3+/Ho3+ codoped Gd2O3 nanocrystals by introducing Zn2+ ions 2016 Beijing (DE-627)ELV014303019 volume:33 year:2022 number:1 pages:271-275 extent:5 https://doi.org/10.1016/j.cclet.2021.06.072 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 GBV_ILN_69 AR 33 2022 1 271-275 5 |
| allfieldsSound |
10.1016/j.cclet.2021.06.072 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001652.pica (DE-627)ELV056590814 (ELSEVIER)S1001-8417(21)00472-1 DE-627 ger DE-627 rakwb eng 670 VZ 540 VZ 630 VZ Wang, Zhichao verfasserin aut S/Se-embedded acenaphthylene-imide-containing polycyclic heteroaromatic hydrocarbon 2022transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. Ma, Qianli oth Huang, Xuan oth Zhang, Tian oth Shao, Jiawei oth Zhang, Xinglin oth Shen, Qian oth Wang, Xiaochen oth Shao, Jinjun oth Enthalten in Institute of Materia Medica Li, Daguang ELSEVIER Enhanced upconversion emission and magnetization in Yb3+-Er3+/Ho3+ codoped Gd2O3 nanocrystals by introducing Zn2+ ions 2016 Beijing (DE-627)ELV014303019 volume:33 year:2022 number:1 pages:271-275 extent:5 https://doi.org/10.1016/j.cclet.2021.06.072 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 GBV_ILN_69 AR 33 2022 1 271-275 5 |
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English |
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Enthalten in Enhanced upconversion emission and magnetization in Yb3+-Er3+/Ho3+ codoped Gd2O3 nanocrystals by introducing Zn2+ ions Beijing volume:33 year:2022 number:1 pages:271-275 extent:5 |
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Enthalten in Enhanced upconversion emission and magnetization in Yb3+-Er3+/Ho3+ codoped Gd2O3 nanocrystals by introducing Zn2+ ions Beijing volume:33 year:2022 number:1 pages:271-275 extent:5 |
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Enhanced upconversion emission and magnetization in Yb3+-Er3+/Ho3+ codoped Gd2O3 nanocrystals by introducing Zn2+ ions |
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Wang, Zhichao @@aut@@ Ma, Qianli @@oth@@ Huang, Xuan @@oth@@ Zhang, Tian @@oth@@ Shao, Jiawei @@oth@@ Zhang, Xinglin @@oth@@ Shen, Qian @@oth@@ Wang, Xiaochen @@oth@@ Shao, Jinjun @@oth@@ |
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Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. 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s/se-embedded acenaphthylene-imide-containing polycyclic heteroaromatic hydrocarbon |
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Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. |
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Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. |
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Acenapththylene-imide (AnI), similar to naphthalene diimide (NDI), is an outstanding building block for organic functional materials and has gained a lot of research attention. Herein, Sulphur and Selenium-embedded AnI-containing polycyclic aromatic hydrocarbon molecules, AnI-SQ and AnI-SeQ, with [1,2,5]thiadiazolo[3,4-g]quinoxaline (SQ) and [1,2,5]selenadiazolo[3,4-g]quinoxaline (SeQ) are designed and synthesized with low-lying LUMO energy levels. The absorption and emission of AnI-SQ and AnI-SeQ displayed a bathochromic shift upon protonation of the C = N bond. Besides, theoretical calculation indicates remarkable rigid planar backbones for both AnI-SQ and AnI-SeQ. Through self-assembly with polymeric Pluronic® F-127, corresponding hydrophilic nanoparticles (NPs) were prepared with low cytotoxicity. And AnI-SQ NPs could be applied for in vitro two-photon fluorescence imaging. |
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Ma, Qianli Huang, Xuan Zhang, Tian Shao, Jiawei Zhang, Xinglin Shen, Qian Wang, Xiaochen Shao, Jinjun |
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