Influence of NiMoP phase on hydrodeoxygenation pathways of jatropha oil
This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Tang, Hongbiao [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022transfer abstract |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Rheological analysis of itraconazole-polymer mixtures to determine optimal melt extrusion temperature for development of amorphous solid dispersion - Solanki, Nayan ELSEVIER, 2017, the international journal, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:243 ; year:2022 ; day:15 ; month:03 ; pages:0 |
| Links: |
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| DOI / URN: |
10.1016/j.energy.2021.123048 |
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ELV056716524 |
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| 245 | 1 | 0 | |a Influence of NiMoP phase on hydrodeoxygenation pathways of jatropha oil |
| 264 | 1 | |c 2022transfer abstract | |
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| 520 | |a This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. | ||
| 520 | |a This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. | ||
| 650 | 7 | |a Hydrodeoxygenation pathways |2 Elsevier | |
| 650 | 7 | |a Bio-jet fuel |2 Elsevier | |
| 650 | 7 | |a Supports |2 Elsevier | |
| 650 | 7 | |a Catalysts |2 Elsevier | |
| 650 | 7 | |a NiMoPx |2 Elsevier | |
| 650 | 7 | |a Jatropha oil |2 Elsevier | |
| 700 | 1 | |a Lin, Jiayu |4 oth | |
| 700 | 1 | |a Cao, Yang |4 oth | |
| 700 | 1 | |a Jibran, Khalil |4 oth | |
| 700 | 1 | |a Li, Jin |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier Science |a Solanki, Nayan ELSEVIER |t Rheological analysis of itraconazole-polymer mixtures to determine optimal melt extrusion temperature for development of amorphous solid dispersion |d 2017 |d the international journal |g Amsterdam [u.a.] |w (DE-627)ELV000529575 |
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10.1016/j.energy.2021.123048 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001665.pica (DE-627)ELV056716524 (ELSEVIER)S0360-5442(21)03297-7 DE-627 ger DE-627 rakwb eng 610 VZ 15,3 ssgn PHARM DE-84 fid 44.40 bkl Tang, Hongbiao verfasserin aut Influence of NiMoP phase on hydrodeoxygenation pathways of jatropha oil 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. Hydrodeoxygenation pathways Elsevier Bio-jet fuel Elsevier Supports Elsevier Catalysts Elsevier NiMoPx Elsevier Jatropha oil Elsevier Lin, Jiayu oth Cao, Yang oth Jibran, Khalil oth Li, Jin oth Enthalten in Elsevier Science Solanki, Nayan ELSEVIER Rheological analysis of itraconazole-polymer mixtures to determine optimal melt extrusion temperature for development of amorphous solid dispersion 2017 the international journal Amsterdam [u.a.] (DE-627)ELV000529575 volume:243 year:2022 day:15 month:03 pages:0 https://doi.org/10.1016/j.energy.2021.123048 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-PHARM SSG-OLC-PHA SSG-OPC-PHA 44.40 Pharmazie Pharmazeutika VZ AR 243 2022 15 0315 0 |
| spelling |
10.1016/j.energy.2021.123048 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001665.pica (DE-627)ELV056716524 (ELSEVIER)S0360-5442(21)03297-7 DE-627 ger DE-627 rakwb eng 610 VZ 15,3 ssgn PHARM DE-84 fid 44.40 bkl Tang, Hongbiao verfasserin aut Influence of NiMoP phase on hydrodeoxygenation pathways of jatropha oil 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. Hydrodeoxygenation pathways Elsevier Bio-jet fuel Elsevier Supports Elsevier Catalysts Elsevier NiMoPx Elsevier Jatropha oil Elsevier Lin, Jiayu oth Cao, Yang oth Jibran, Khalil oth Li, Jin oth Enthalten in Elsevier Science Solanki, Nayan ELSEVIER Rheological analysis of itraconazole-polymer mixtures to determine optimal melt extrusion temperature for development of amorphous solid dispersion 2017 the international journal Amsterdam [u.a.] (DE-627)ELV000529575 volume:243 year:2022 day:15 month:03 pages:0 https://doi.org/10.1016/j.energy.2021.123048 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-PHARM SSG-OLC-PHA SSG-OPC-PHA 44.40 Pharmazie Pharmazeutika VZ AR 243 2022 15 0315 0 |
| allfields_unstemmed |
10.1016/j.energy.2021.123048 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001665.pica (DE-627)ELV056716524 (ELSEVIER)S0360-5442(21)03297-7 DE-627 ger DE-627 rakwb eng 610 VZ 15,3 ssgn PHARM DE-84 fid 44.40 bkl Tang, Hongbiao verfasserin aut Influence of NiMoP phase on hydrodeoxygenation pathways of jatropha oil 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. Hydrodeoxygenation pathways Elsevier Bio-jet fuel Elsevier Supports Elsevier Catalysts Elsevier NiMoPx Elsevier Jatropha oil Elsevier Lin, Jiayu oth Cao, Yang oth Jibran, Khalil oth Li, Jin oth Enthalten in Elsevier Science Solanki, Nayan ELSEVIER Rheological analysis of itraconazole-polymer mixtures to determine optimal melt extrusion temperature for development of amorphous solid dispersion 2017 the international journal Amsterdam [u.a.] (DE-627)ELV000529575 volume:243 year:2022 day:15 month:03 pages:0 https://doi.org/10.1016/j.energy.2021.123048 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-PHARM SSG-OLC-PHA SSG-OPC-PHA 44.40 Pharmazie Pharmazeutika VZ AR 243 2022 15 0315 0 |
| allfieldsGer |
10.1016/j.energy.2021.123048 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001665.pica (DE-627)ELV056716524 (ELSEVIER)S0360-5442(21)03297-7 DE-627 ger DE-627 rakwb eng 610 VZ 15,3 ssgn PHARM DE-84 fid 44.40 bkl Tang, Hongbiao verfasserin aut Influence of NiMoP phase on hydrodeoxygenation pathways of jatropha oil 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. Hydrodeoxygenation pathways Elsevier Bio-jet fuel Elsevier Supports Elsevier Catalysts Elsevier NiMoPx Elsevier Jatropha oil Elsevier Lin, Jiayu oth Cao, Yang oth Jibran, Khalil oth Li, Jin oth Enthalten in Elsevier Science Solanki, Nayan ELSEVIER Rheological analysis of itraconazole-polymer mixtures to determine optimal melt extrusion temperature for development of amorphous solid dispersion 2017 the international journal Amsterdam [u.a.] (DE-627)ELV000529575 volume:243 year:2022 day:15 month:03 pages:0 https://doi.org/10.1016/j.energy.2021.123048 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-PHARM SSG-OLC-PHA SSG-OPC-PHA 44.40 Pharmazie Pharmazeutika VZ AR 243 2022 15 0315 0 |
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10.1016/j.energy.2021.123048 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001665.pica (DE-627)ELV056716524 (ELSEVIER)S0360-5442(21)03297-7 DE-627 ger DE-627 rakwb eng 610 VZ 15,3 ssgn PHARM DE-84 fid 44.40 bkl Tang, Hongbiao verfasserin aut Influence of NiMoP phase on hydrodeoxygenation pathways of jatropha oil 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. Hydrodeoxygenation pathways Elsevier Bio-jet fuel Elsevier Supports Elsevier Catalysts Elsevier NiMoPx Elsevier Jatropha oil Elsevier Lin, Jiayu oth Cao, Yang oth Jibran, Khalil oth Li, Jin oth Enthalten in Elsevier Science Solanki, Nayan ELSEVIER Rheological analysis of itraconazole-polymer mixtures to determine optimal melt extrusion temperature for development of amorphous solid dispersion 2017 the international journal Amsterdam [u.a.] (DE-627)ELV000529575 volume:243 year:2022 day:15 month:03 pages:0 https://doi.org/10.1016/j.energy.2021.123048 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-PHARM SSG-OLC-PHA SSG-OPC-PHA 44.40 Pharmazie Pharmazeutika VZ AR 243 2022 15 0315 0 |
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Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. 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Influence of NiMoP phase on hydrodeoxygenation pathways of jatropha oil |
| abstract |
This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. |
| abstractGer |
This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. |
| abstract_unstemmed |
This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst. |
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Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">This work investigates the conversion pathway of jatropha oil to C16 + C18 by a one-pot method regulated by different moles of phosphorus and supports. Preferential direct deoxygenation is of interest for the carbon atom economy. Herein, SAPO-11, ZSM-5, and Zr-SBA-15 as supports, a series of nickel molybdenum phosphide catalysts were prepared, characterized, and used to hydrodeoxygenation (HDO) of jatropha oil in an autoclave. Our results showed that different supports affect the formation of the active phase of nickel molybdenum phosphide and its acid sites, thus affecting the catalytic performance, resulting in different HDO pathway ratios. The HDO pathway ratios of different n(Ni–Mo)/n(P) catalysts on the same support differed. Compared with the NiMo catalysts, the NiMoP2/Zr-SBA-15 catalyst showed the most remarkable HDO performance, with C15 + C17/C16 + C18 decreasing from 6.95 to 2.24. The presence of P in the catalyst promotes direct deoxygenation, while inhibiting decarboxylation and decarbonylation. In addition, the NiMoP phase exhibited excellent catalytic activity, with more than 90% deoxidization. Refined oil contains high levels of jet fuel components, with C8–C16 alkanes account for more than 50% and naphthenes reaching more than 20%. The catalysts were tested at 360 °C, 30 bar, and 4 h, and results showed that the NiMoP phase plays an important role in inhibiting coke deposition on the catalyst.</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Hydrodeoxygenation pathways</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Bio-jet fuel</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Supports</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Catalysts</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">NiMoPx</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Jatropha oil</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lin, Jiayu</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Cao, Yang</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Jibran, Khalil</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Jin</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="n">Elsevier Science</subfield><subfield code="a">Solanki, Nayan ELSEVIER</subfield><subfield code="t">Rheological analysis of itraconazole-polymer mixtures to determine optimal melt extrusion temperature for development of amorphous solid dispersion</subfield><subfield code="d">2017</subfield><subfield code="d">the international journal</subfield><subfield code="g">Amsterdam [u.a.]</subfield><subfield code="w">(DE-627)ELV000529575</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:243</subfield><subfield code="g">year:2022</subfield><subfield code="g">day:15</subfield><subfield code="g">month:03</subfield><subfield code="g">pages:0</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.1016/j.energy.2021.123048</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">FID-PHARM</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OPC-PHA</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">44.40</subfield><subfield code="j">Pharmazie</subfield><subfield code="j">Pharmazeutika</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">243</subfield><subfield code="j">2022</subfield><subfield code="b">15</subfield><subfield code="c">0315</subfield><subfield code="h">0</subfield></datafield></record></collection>
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