Metallurgical investigation of aluminum anode behavior in water-in-salt electrolyte for aqueous aluminum batteries
Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a n...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Arshadi Rastabi, Shahrzad [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022transfer abstract |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method - Xiao, Hong ELSEVIER, 2013, the international journal on the science and technology of electrochemical energy systems, New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:523 ; year:2022 ; day:1 ; month:03 ; pages:0 |
| Links: |
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| DOI / URN: |
10.1016/j.jpowsour.2022.231066 |
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ELV056737335 |
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| 520 | |a Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. | ||
| 520 | |a Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. | ||
| 650 | 7 | |a Aluminum-ion battery |2 Elsevier | |
| 650 | 7 | |a Solid electrolyte interphase |2 Elsevier | |
| 650 | 7 | |a Oxide barrier |2 Elsevier | |
| 650 | 7 | |a Corrosion |2 Elsevier | |
| 650 | 7 | |a Al3Fe intermetallic phases |2 Elsevier | |
| 650 | 7 | |a Water-in-salt electrolyte |2 Elsevier | |
| 700 | 1 | |a Razaz, Ghadir |4 oth | |
| 700 | 1 | |a Hummelgård, Magnus |4 oth | |
| 700 | 1 | |a Carlberg, Torbjörn |4 oth | |
| 700 | 1 | |a Blomquist, Nicklas |4 oth | |
| 700 | 1 | |a Örtegren, Jonas |4 oth | |
| 700 | 1 | |a Olin, Håkan |4 oth | |
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10.1016/j.jpowsour.2022.231066 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001668.pica (DE-627)ELV056737335 (ELSEVIER)S0378-7753(22)00090-8 DE-627 ger DE-627 rakwb eng 690 VZ 50.92 bkl Arshadi Rastabi, Shahrzad verfasserin aut Metallurgical investigation of aluminum anode behavior in water-in-salt electrolyte for aqueous aluminum batteries 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. Aluminum-ion battery Elsevier Solid electrolyte interphase Elsevier Oxide barrier Elsevier Corrosion Elsevier Al3Fe intermetallic phases Elsevier Water-in-salt electrolyte Elsevier Razaz, Ghadir oth Hummelgård, Magnus oth Carlberg, Torbjörn oth Blomquist, Nicklas oth Örtegren, Jonas oth Olin, Håkan oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:523 year:2022 day:1 month:03 pages:0 https://doi.org/10.1016/j.jpowsour.2022.231066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 523 2022 1 0301 0 |
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10.1016/j.jpowsour.2022.231066 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001668.pica (DE-627)ELV056737335 (ELSEVIER)S0378-7753(22)00090-8 DE-627 ger DE-627 rakwb eng 690 VZ 50.92 bkl Arshadi Rastabi, Shahrzad verfasserin aut Metallurgical investigation of aluminum anode behavior in water-in-salt electrolyte for aqueous aluminum batteries 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. Aluminum-ion battery Elsevier Solid electrolyte interphase Elsevier Oxide barrier Elsevier Corrosion Elsevier Al3Fe intermetallic phases Elsevier Water-in-salt electrolyte Elsevier Razaz, Ghadir oth Hummelgård, Magnus oth Carlberg, Torbjörn oth Blomquist, Nicklas oth Örtegren, Jonas oth Olin, Håkan oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:523 year:2022 day:1 month:03 pages:0 https://doi.org/10.1016/j.jpowsour.2022.231066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 523 2022 1 0301 0 |
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10.1016/j.jpowsour.2022.231066 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001668.pica (DE-627)ELV056737335 (ELSEVIER)S0378-7753(22)00090-8 DE-627 ger DE-627 rakwb eng 690 VZ 50.92 bkl Arshadi Rastabi, Shahrzad verfasserin aut Metallurgical investigation of aluminum anode behavior in water-in-salt electrolyte for aqueous aluminum batteries 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. Aluminum-ion battery Elsevier Solid electrolyte interphase Elsevier Oxide barrier Elsevier Corrosion Elsevier Al3Fe intermetallic phases Elsevier Water-in-salt electrolyte Elsevier Razaz, Ghadir oth Hummelgård, Magnus oth Carlberg, Torbjörn oth Blomquist, Nicklas oth Örtegren, Jonas oth Olin, Håkan oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:523 year:2022 day:1 month:03 pages:0 https://doi.org/10.1016/j.jpowsour.2022.231066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 523 2022 1 0301 0 |
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10.1016/j.jpowsour.2022.231066 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001668.pica (DE-627)ELV056737335 (ELSEVIER)S0378-7753(22)00090-8 DE-627 ger DE-627 rakwb eng 690 VZ 50.92 bkl Arshadi Rastabi, Shahrzad verfasserin aut Metallurgical investigation of aluminum anode behavior in water-in-salt electrolyte for aqueous aluminum batteries 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. Aluminum-ion battery Elsevier Solid electrolyte interphase Elsevier Oxide barrier Elsevier Corrosion Elsevier Al3Fe intermetallic phases Elsevier Water-in-salt electrolyte Elsevier Razaz, Ghadir oth Hummelgård, Magnus oth Carlberg, Torbjörn oth Blomquist, Nicklas oth Örtegren, Jonas oth Olin, Håkan oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:523 year:2022 day:1 month:03 pages:0 https://doi.org/10.1016/j.jpowsour.2022.231066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 523 2022 1 0301 0 |
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10.1016/j.jpowsour.2022.231066 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001668.pica (DE-627)ELV056737335 (ELSEVIER)S0378-7753(22)00090-8 DE-627 ger DE-627 rakwb eng 690 VZ 50.92 bkl Arshadi Rastabi, Shahrzad verfasserin aut Metallurgical investigation of aluminum anode behavior in water-in-salt electrolyte for aqueous aluminum batteries 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. Aluminum-ion battery Elsevier Solid electrolyte interphase Elsevier Oxide barrier Elsevier Corrosion Elsevier Al3Fe intermetallic phases Elsevier Water-in-salt electrolyte Elsevier Razaz, Ghadir oth Hummelgård, Magnus oth Carlberg, Torbjörn oth Blomquist, Nicklas oth Örtegren, Jonas oth Olin, Håkan oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:523 year:2022 day:1 month:03 pages:0 https://doi.org/10.1016/j.jpowsour.2022.231066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 523 2022 1 0301 0 |
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Enthalten in Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method New York, NY [u.a.] volume:523 year:2022 day:1 month:03 pages:0 |
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Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method |
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Arshadi Rastabi, Shahrzad @@aut@@ Razaz, Ghadir @@oth@@ Hummelgård, Magnus @@oth@@ Carlberg, Torbjörn @@oth@@ Blomquist, Nicklas @@oth@@ Örtegren, Jonas @@oth@@ Olin, Håkan @@oth@@ |
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metallurgical investigation of aluminum anode behavior in water-in-salt electrolyte for aqueous aluminum batteries |
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Metallurgical investigation of aluminum anode behavior in water-in-salt electrolyte for aqueous aluminum batteries |
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Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. |
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Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. |
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Although ionic liquid electrolytes (ILs) are environmentally unfriendly, they are the most common electrolyte used in aluminum-ion batteries (AIB). Aqueous electrolytes offer a more sustainable alternative, but problem with oxide passivating barrier on Al surface becomes more profound. Recently, a new sub-class of aqueous electrolytes, water-in-salt (WIS) of (AlCl3·6H2O), has been considered, but experimental validation of the behavior of the Al electrode over cycling is required. This work investigates aluminum/graphitic cells using WIS electrolytes with a mass ratio of salt to water of 4, 8, and 12 and finds that they show similar trends in cycling performance. The degradation observed over cycling has been attributed to the formation of a detrimental solid electrolyte interphase (SEI) layer on the Al surface. It was found that WIS 4 increased Al corrosion, resulting in a slightly higher capacity and longer cycling life. Metallurgical observation showed that the Al matrix has a tendency to initiate corrosion around Al3Fe intermetallic phases in both WIS and ILs. This implies that the presence of Al3Fe particles allows the electrolyte to break the oxide barrier and access the bulk Al. These results suggests that metallurgical treatments are important to enhance the electrochemical performance of AIB. |
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