Spectroscopic analyses of Er3+/Yb3+ co-doped laser sintering silica glasses
In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, impor...
Ausführliche Beschreibung
Autor*in: |
Chen, Yun [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2022transfer abstract |
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Übergeordnetes Werk: |
Enthalten in: New ablation evolution behaviors in micro-hole drilling of 2.5D C - Liu, Chang ELSEVIER, 2021, New York, NY [u.a.] |
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Übergeordnetes Werk: |
volume:245 ; year:2022 ; pages:0 |
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DOI / URN: |
10.1016/j.jlumin.2022.118764 |
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Katalog-ID: |
ELV057008116 |
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520 | |a In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. | ||
520 | |a In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. | ||
650 | 7 | |a Silica glasses |2 Elsevier | |
650 | 7 | |a Er3+/Yb3+ |2 Elsevier | |
650 | 7 | |a Spectroscopic behaviour |2 Elsevier | |
650 | 7 | |a Laser sintering technique |2 Elsevier | |
650 | 7 | |a Up-conversion |2 Elsevier | |
700 | 1 | |a Zhao, Nan |4 oth | |
700 | 1 | |a Liu, Jiantao |4 oth | |
700 | 1 | |a Li, Jiaming |4 oth | |
700 | 1 | |a Zhang, Wei |4 oth | |
700 | 1 | |a Zhou, Guiyao |4 oth | |
700 | 1 | |a Shao, Liyang |4 oth | |
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10.1016/j.jlumin.2022.118764 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001706.pica (DE-627)ELV057008116 (ELSEVIER)S0022-2313(22)00039-4 DE-627 ger DE-627 rakwb eng 670 VZ 51.60 bkl 58.45 bkl Chen, Yun verfasserin aut Spectroscopic analyses of Er3+/Yb3+ co-doped laser sintering silica glasses 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. Silica glasses Elsevier Er3+/Yb3+ Elsevier Spectroscopic behaviour Elsevier Laser sintering technique Elsevier Up-conversion Elsevier Zhao, Nan oth Liu, Jiantao oth Li, Jiaming oth Zhang, Wei oth Zhou, Guiyao oth Shao, Liyang oth Enthalten in Elsevier Liu, Chang ELSEVIER New ablation evolution behaviors in micro-hole drilling of 2.5D C 2021 New York, NY [u.a.] (DE-627)ELV00662605X volume:245 year:2022 pages:0 https://doi.org/10.1016/j.jlumin.2022.118764 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 58.45 Gesteinshüttenkunde VZ AR 245 2022 0 |
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10.1016/j.jlumin.2022.118764 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001706.pica (DE-627)ELV057008116 (ELSEVIER)S0022-2313(22)00039-4 DE-627 ger DE-627 rakwb eng 670 VZ 51.60 bkl 58.45 bkl Chen, Yun verfasserin aut Spectroscopic analyses of Er3+/Yb3+ co-doped laser sintering silica glasses 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. Silica glasses Elsevier Er3+/Yb3+ Elsevier Spectroscopic behaviour Elsevier Laser sintering technique Elsevier Up-conversion Elsevier Zhao, Nan oth Liu, Jiantao oth Li, Jiaming oth Zhang, Wei oth Zhou, Guiyao oth Shao, Liyang oth Enthalten in Elsevier Liu, Chang ELSEVIER New ablation evolution behaviors in micro-hole drilling of 2.5D C 2021 New York, NY [u.a.] (DE-627)ELV00662605X volume:245 year:2022 pages:0 https://doi.org/10.1016/j.jlumin.2022.118764 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 58.45 Gesteinshüttenkunde VZ AR 245 2022 0 |
allfields_unstemmed |
10.1016/j.jlumin.2022.118764 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001706.pica (DE-627)ELV057008116 (ELSEVIER)S0022-2313(22)00039-4 DE-627 ger DE-627 rakwb eng 670 VZ 51.60 bkl 58.45 bkl Chen, Yun verfasserin aut Spectroscopic analyses of Er3+/Yb3+ co-doped laser sintering silica glasses 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. Silica glasses Elsevier Er3+/Yb3+ Elsevier Spectroscopic behaviour Elsevier Laser sintering technique Elsevier Up-conversion Elsevier Zhao, Nan oth Liu, Jiantao oth Li, Jiaming oth Zhang, Wei oth Zhou, Guiyao oth Shao, Liyang oth Enthalten in Elsevier Liu, Chang ELSEVIER New ablation evolution behaviors in micro-hole drilling of 2.5D C 2021 New York, NY [u.a.] (DE-627)ELV00662605X volume:245 year:2022 pages:0 https://doi.org/10.1016/j.jlumin.2022.118764 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 58.45 Gesteinshüttenkunde VZ AR 245 2022 0 |
allfieldsGer |
10.1016/j.jlumin.2022.118764 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001706.pica (DE-627)ELV057008116 (ELSEVIER)S0022-2313(22)00039-4 DE-627 ger DE-627 rakwb eng 670 VZ 51.60 bkl 58.45 bkl Chen, Yun verfasserin aut Spectroscopic analyses of Er3+/Yb3+ co-doped laser sintering silica glasses 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. Silica glasses Elsevier Er3+/Yb3+ Elsevier Spectroscopic behaviour Elsevier Laser sintering technique Elsevier Up-conversion Elsevier Zhao, Nan oth Liu, Jiantao oth Li, Jiaming oth Zhang, Wei oth Zhou, Guiyao oth Shao, Liyang oth Enthalten in Elsevier Liu, Chang ELSEVIER New ablation evolution behaviors in micro-hole drilling of 2.5D C 2021 New York, NY [u.a.] (DE-627)ELV00662605X volume:245 year:2022 pages:0 https://doi.org/10.1016/j.jlumin.2022.118764 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 58.45 Gesteinshüttenkunde VZ AR 245 2022 0 |
allfieldsSound |
10.1016/j.jlumin.2022.118764 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001706.pica (DE-627)ELV057008116 (ELSEVIER)S0022-2313(22)00039-4 DE-627 ger DE-627 rakwb eng 670 VZ 51.60 bkl 58.45 bkl Chen, Yun verfasserin aut Spectroscopic analyses of Er3+/Yb3+ co-doped laser sintering silica glasses 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. Silica glasses Elsevier Er3+/Yb3+ Elsevier Spectroscopic behaviour Elsevier Laser sintering technique Elsevier Up-conversion Elsevier Zhao, Nan oth Liu, Jiantao oth Li, Jiaming oth Zhang, Wei oth Zhou, Guiyao oth Shao, Liyang oth Enthalten in Elsevier Liu, Chang ELSEVIER New ablation evolution behaviors in micro-hole drilling of 2.5D C 2021 New York, NY [u.a.] (DE-627)ELV00662605X volume:245 year:2022 pages:0 https://doi.org/10.1016/j.jlumin.2022.118764 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 58.45 Gesteinshüttenkunde VZ AR 245 2022 0 |
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spectroscopic analyses of er3+/yb3+ co-doped laser sintering silica glasses |
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Spectroscopic analyses of Er3+/Yb3+ co-doped laser sintering silica glasses |
abstract |
In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. |
abstractGer |
In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. |
abstract_unstemmed |
In this study, the laser sintering technique was used to obtain Er3+/Yb3+ co-doped silica glasses for up-conversion (UC) luminescence for the first time. Further, structural analysis of the glass sample was conducted via XRD, SEM and EDS measurements. Based on the measured absorption spectrum, important spectroscopic parameters including three intensity parameters Ω t (t = 2, 4 and 6), theoretical and experimental line strengths, spontaneous transition probabilities, branching ratios and radiative lifetimes, were calculated using the Judd-Ofelt (J-O) theory. The UC properties of Er3+/Yb3+ co-doped silica glasses were investigated upon the excitation of a 976 nm laser. It has been experimentally confirmed that the green and red UC luminescences corresponding to the radiative transitions of Er3+: 2H11/2 → 4I15/2 (green), 4S3/2 → 4I15/2 (green) and 4F9/2 → 4I15/2 (red) were achieved. This result is consistent with those of the J-O theoretical analysis. Additionally, the energy transfer mechanism between Er3+ and Yb3+, which is responsible for the UC process, was discussed based on their dependence on the pump power. The obtained results indicated that the Er3+/Yb3+ co-doped silica glasses manufactured using the laser sintering technique can be promising for the application of short-wavelength lasers. |
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