Maghemite nanoparticles decorated semiconducting graphitic carbon nitride hetero-structured nanocomposite: Facile synthesis, characterizations and its visible light active photocatalytic system for removal of hazardous organic pollutants from aqueous solutions
Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineeri...
Ausführliche Beschreibung
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Baig, Umair [verfasserIn] |
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Enthalten in: Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface - Ren, Guoqing ELSEVIER, 2018, an international journal devoted to the principles and applications of colloid and interface science, Amsterdam [u.a.] |
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volume:641 ; year:2022 ; day:20 ; month:05 ; pages:0 |
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DOI / URN: |
10.1016/j.colsurfa.2022.128427 |
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520 | |a Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. | ||
520 | |a Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. | ||
650 | 7 | |a Removal of hazardous pollutants |2 Elsevier | |
650 | 7 | |a Photo-catalytic degradation |2 Elsevier | |
650 | 7 | |a Z-scheme photo-catalysis |2 Elsevier | |
650 | 7 | |a Pulsed laser fragmentation |2 Elsevier | |
650 | 7 | |a Hetero-structured nanocomposite |2 Elsevier | |
700 | 1 | |a Gondal, M.A. |4 oth | |
700 | 1 | |a Dastageer, M.A. |4 oth | |
700 | 1 | |a Sajid, Mohd |4 oth | |
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10.1016/j.colsurfa.2022.128427 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001812.pica (DE-627)ELV057146799 (ELSEVIER)S0927-7757(22)00181-9 DE-627 ger DE-627 rakwb eng 540 VZ 35.10 bkl Baig, Umair verfasserin aut Maghemite nanoparticles decorated semiconducting graphitic carbon nitride hetero-structured nanocomposite: Facile synthesis, characterizations and its visible light active photocatalytic system for removal of hazardous organic pollutants from aqueous solutions 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. Removal of hazardous pollutants Elsevier Photo-catalytic degradation Elsevier Z-scheme photo-catalysis Elsevier Pulsed laser fragmentation Elsevier Hetero-structured nanocomposite Elsevier Gondal, M.A. oth Dastageer, M.A. oth Sajid, Mohd oth Enthalten in Elsevier Science Ren, Guoqing ELSEVIER Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface 2018 an international journal devoted to the principles and applications of colloid and interface science Amsterdam [u.a.] (DE-627)ELV003763498 volume:641 year:2022 day:20 month:05 pages:0 https://doi.org/10.1016/j.colsurfa.2022.128427 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 641 2022 20 0520 0 |
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10.1016/j.colsurfa.2022.128427 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001812.pica (DE-627)ELV057146799 (ELSEVIER)S0927-7757(22)00181-9 DE-627 ger DE-627 rakwb eng 540 VZ 35.10 bkl Baig, Umair verfasserin aut Maghemite nanoparticles decorated semiconducting graphitic carbon nitride hetero-structured nanocomposite: Facile synthesis, characterizations and its visible light active photocatalytic system for removal of hazardous organic pollutants from aqueous solutions 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. Removal of hazardous pollutants Elsevier Photo-catalytic degradation Elsevier Z-scheme photo-catalysis Elsevier Pulsed laser fragmentation Elsevier Hetero-structured nanocomposite Elsevier Gondal, M.A. oth Dastageer, M.A. oth Sajid, Mohd oth Enthalten in Elsevier Science Ren, Guoqing ELSEVIER Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface 2018 an international journal devoted to the principles and applications of colloid and interface science Amsterdam [u.a.] (DE-627)ELV003763498 volume:641 year:2022 day:20 month:05 pages:0 https://doi.org/10.1016/j.colsurfa.2022.128427 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 641 2022 20 0520 0 |
allfields_unstemmed |
10.1016/j.colsurfa.2022.128427 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001812.pica (DE-627)ELV057146799 (ELSEVIER)S0927-7757(22)00181-9 DE-627 ger DE-627 rakwb eng 540 VZ 35.10 bkl Baig, Umair verfasserin aut Maghemite nanoparticles decorated semiconducting graphitic carbon nitride hetero-structured nanocomposite: Facile synthesis, characterizations and its visible light active photocatalytic system for removal of hazardous organic pollutants from aqueous solutions 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. Removal of hazardous pollutants Elsevier Photo-catalytic degradation Elsevier Z-scheme photo-catalysis Elsevier Pulsed laser fragmentation Elsevier Hetero-structured nanocomposite Elsevier Gondal, M.A. oth Dastageer, M.A. oth Sajid, Mohd oth Enthalten in Elsevier Science Ren, Guoqing ELSEVIER Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface 2018 an international journal devoted to the principles and applications of colloid and interface science Amsterdam [u.a.] (DE-627)ELV003763498 volume:641 year:2022 day:20 month:05 pages:0 https://doi.org/10.1016/j.colsurfa.2022.128427 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 641 2022 20 0520 0 |
allfieldsGer |
10.1016/j.colsurfa.2022.128427 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001812.pica (DE-627)ELV057146799 (ELSEVIER)S0927-7757(22)00181-9 DE-627 ger DE-627 rakwb eng 540 VZ 35.10 bkl Baig, Umair verfasserin aut Maghemite nanoparticles decorated semiconducting graphitic carbon nitride hetero-structured nanocomposite: Facile synthesis, characterizations and its visible light active photocatalytic system for removal of hazardous organic pollutants from aqueous solutions 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. Removal of hazardous pollutants Elsevier Photo-catalytic degradation Elsevier Z-scheme photo-catalysis Elsevier Pulsed laser fragmentation Elsevier Hetero-structured nanocomposite Elsevier Gondal, M.A. oth Dastageer, M.A. oth Sajid, Mohd oth Enthalten in Elsevier Science Ren, Guoqing ELSEVIER Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface 2018 an international journal devoted to the principles and applications of colloid and interface science Amsterdam [u.a.] (DE-627)ELV003763498 volume:641 year:2022 day:20 month:05 pages:0 https://doi.org/10.1016/j.colsurfa.2022.128427 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 641 2022 20 0520 0 |
allfieldsSound |
10.1016/j.colsurfa.2022.128427 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001812.pica (DE-627)ELV057146799 (ELSEVIER)S0927-7757(22)00181-9 DE-627 ger DE-627 rakwb eng 540 VZ 35.10 bkl Baig, Umair verfasserin aut Maghemite nanoparticles decorated semiconducting graphitic carbon nitride hetero-structured nanocomposite: Facile synthesis, characterizations and its visible light active photocatalytic system for removal of hazardous organic pollutants from aqueous solutions 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. Removal of hazardous pollutants Elsevier Photo-catalytic degradation Elsevier Z-scheme photo-catalysis Elsevier Pulsed laser fragmentation Elsevier Hetero-structured nanocomposite Elsevier Gondal, M.A. oth Dastageer, M.A. oth Sajid, Mohd oth Enthalten in Elsevier Science Ren, Guoqing ELSEVIER Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface 2018 an international journal devoted to the principles and applications of colloid and interface science Amsterdam [u.a.] (DE-627)ELV003763498 volume:641 year:2022 day:20 month:05 pages:0 https://doi.org/10.1016/j.colsurfa.2022.128427 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 641 2022 20 0520 0 |
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Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu(1 1 1) surface |
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maghemite nanoparticles decorated semiconducting graphitic carbon nitride hetero-structured nanocomposite: facile synthesis, characterizations and its visible light active photocatalytic system for removal of hazardous organic pollutants from aqueous solutions |
title_auth |
Maghemite nanoparticles decorated semiconducting graphitic carbon nitride hetero-structured nanocomposite: Facile synthesis, characterizations and its visible light active photocatalytic system for removal of hazardous organic pollutants from aqueous solutions |
abstract |
Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. |
abstractGer |
Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. |
abstract_unstemmed |
Hetero-structured nanocomposite consisting of graphitic carbon nitride host, decorated by γ-phase iron oxide, maghemite (γ-Fe2O3G-CN) was synthesized in different mass contents of γ-Fe2O3 (5%, 10% and 20%) in the composite, by the method of nanosecond pulsed laser fragmentation, and defect engineering in liquid for the removal of hazardous organic pollutants from aqueous solutions. The elemental, structural, and morphological characterizations of the synthesized nanocomposites by XPS, XRD, TEM, and HR-TEM exhibited the proper anchoring of γ-Fe2O3 on the graphitic carbon nitride polymeric network. Also, the diffuse reflectance spectra, and the room temperature photoluminescence spectra respectively revealed that the presence of γ-Fe2O3 in graphitic carbon nitride brought about the enhanced and extended visible light absorption, and reduced recombination of photo induced electron hole pairs, the characteristics desired in a good photo-catalyst. Moreover, this composite material exhibited the z-scheme photo catalytic mechanism, where the more energetic electrons and holes in the composite band structure mediate the redox reaction in the photo-catalysis. The photo-catalytic efficiency of γ-Fe2O3@G-CN nanocomposite was evaluated in the photo-catalytic degradation of methyl blue (MB), and rhodamine-B (Rh-B) cationic dyes under visible light irradiations. For both the degradation processes, all the variants of γ-Fe2O3@G-CN nanocomposite consistently showed the enhanced photocatalytic efficiency with respect to pure GCN, with the maximum efficiency recorded for 10% γ-Fe2O3 in γ-Fe2O3@G-CN nanocomposite. |
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Maghemite nanoparticles decorated semiconducting graphitic carbon nitride hetero-structured nanocomposite: Facile synthesis, characterizations and its visible light active photocatalytic system for removal of hazardous organic pollutants from aqueous solutions |
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