Photoemission and photofragmentation of butanoic, hexanoic and octanoic acids in the gas phase
The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening o...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Sa’adeh, Hanan [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022transfer abstract |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Self-healing hydrogels and their action mechanism in oil–gas drilling and development engineering: A systematic review and prospect - Bai, Yingrui ELSEVIER, 2021, the international journal on theoretical, experimental and applied aspects of electron spectroscopy, New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:256 ; year:2022 ; pages:0 |
| Links: |
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| DOI / URN: |
10.1016/j.elspec.2022.147172 |
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| 520 | |a The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. | ||
| 520 | |a The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. | ||
| 650 | 7 | |a Octanoic Acid |2 Elsevier | |
| 650 | 7 | |a Photoelectron Spectroscopy |2 Elsevier | |
| 650 | 7 | |a NEXAFS |2 Elsevier | |
| 650 | 7 | |a Butanoic Acid |2 Elsevier | |
| 650 | 7 | |a Hexanoic Acid |2 Elsevier | |
| 650 | 7 | |a PEPICO |2 Elsevier | |
| 700 | 1 | |a Masič, Maša |4 oth | |
| 700 | 1 | |a Bolognesi, Paola |4 oth | |
| 700 | 1 | |a Richter, Robert |4 oth | |
| 700 | 1 | |a Prince, Kevin C. |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier |a Bai, Yingrui ELSEVIER |t Self-healing hydrogels and their action mechanism in oil–gas drilling and development engineering: A systematic review and prospect |d 2021 |d the international journal on theoretical, experimental and applied aspects of electron spectroscopy |g New York, NY [u.a.] |w (DE-627)ELV007031580 |
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10.1016/j.elspec.2022.147172 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001760.pica (DE-627)ELV057314853 (ELSEVIER)S0368-2048(22)00015-9 DE-627 ger DE-627 rakwb eng 660 VZ Sa’adeh, Hanan verfasserin aut Photoemission and photofragmentation of butanoic, hexanoic and octanoic acids in the gas phase 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. Octanoic Acid Elsevier Photoelectron Spectroscopy Elsevier NEXAFS Elsevier Butanoic Acid Elsevier Hexanoic Acid Elsevier PEPICO Elsevier Masič, Maša oth Bolognesi, Paola oth Richter, Robert oth Prince, Kevin C. oth Enthalten in Elsevier Bai, Yingrui ELSEVIER Self-healing hydrogels and their action mechanism in oil–gas drilling and development engineering: A systematic review and prospect 2021 the international journal on theoretical, experimental and applied aspects of electron spectroscopy New York, NY [u.a.] (DE-627)ELV007031580 volume:256 year:2022 pages:0 https://doi.org/10.1016/j.elspec.2022.147172 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 256 2022 0 |
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10.1016/j.elspec.2022.147172 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001760.pica (DE-627)ELV057314853 (ELSEVIER)S0368-2048(22)00015-9 DE-627 ger DE-627 rakwb eng 660 VZ Sa’adeh, Hanan verfasserin aut Photoemission and photofragmentation of butanoic, hexanoic and octanoic acids in the gas phase 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. Octanoic Acid Elsevier Photoelectron Spectroscopy Elsevier NEXAFS Elsevier Butanoic Acid Elsevier Hexanoic Acid Elsevier PEPICO Elsevier Masič, Maša oth Bolognesi, Paola oth Richter, Robert oth Prince, Kevin C. oth Enthalten in Elsevier Bai, Yingrui ELSEVIER Self-healing hydrogels and their action mechanism in oil–gas drilling and development engineering: A systematic review and prospect 2021 the international journal on theoretical, experimental and applied aspects of electron spectroscopy New York, NY [u.a.] (DE-627)ELV007031580 volume:256 year:2022 pages:0 https://doi.org/10.1016/j.elspec.2022.147172 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 256 2022 0 |
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10.1016/j.elspec.2022.147172 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001760.pica (DE-627)ELV057314853 (ELSEVIER)S0368-2048(22)00015-9 DE-627 ger DE-627 rakwb eng 660 VZ Sa’adeh, Hanan verfasserin aut Photoemission and photofragmentation of butanoic, hexanoic and octanoic acids in the gas phase 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. Octanoic Acid Elsevier Photoelectron Spectroscopy Elsevier NEXAFS Elsevier Butanoic Acid Elsevier Hexanoic Acid Elsevier PEPICO Elsevier Masič, Maša oth Bolognesi, Paola oth Richter, Robert oth Prince, Kevin C. oth Enthalten in Elsevier Bai, Yingrui ELSEVIER Self-healing hydrogels and their action mechanism in oil–gas drilling and development engineering: A systematic review and prospect 2021 the international journal on theoretical, experimental and applied aspects of electron spectroscopy New York, NY [u.a.] (DE-627)ELV007031580 volume:256 year:2022 pages:0 https://doi.org/10.1016/j.elspec.2022.147172 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 256 2022 0 |
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10.1016/j.elspec.2022.147172 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001760.pica (DE-627)ELV057314853 (ELSEVIER)S0368-2048(22)00015-9 DE-627 ger DE-627 rakwb eng 660 VZ Sa’adeh, Hanan verfasserin aut Photoemission and photofragmentation of butanoic, hexanoic and octanoic acids in the gas phase 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. Octanoic Acid Elsevier Photoelectron Spectroscopy Elsevier NEXAFS Elsevier Butanoic Acid Elsevier Hexanoic Acid Elsevier PEPICO Elsevier Masič, Maša oth Bolognesi, Paola oth Richter, Robert oth Prince, Kevin C. oth Enthalten in Elsevier Bai, Yingrui ELSEVIER Self-healing hydrogels and their action mechanism in oil–gas drilling and development engineering: A systematic review and prospect 2021 the international journal on theoretical, experimental and applied aspects of electron spectroscopy New York, NY [u.a.] (DE-627)ELV007031580 volume:256 year:2022 pages:0 https://doi.org/10.1016/j.elspec.2022.147172 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 256 2022 0 |
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10.1016/j.elspec.2022.147172 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001760.pica (DE-627)ELV057314853 (ELSEVIER)S0368-2048(22)00015-9 DE-627 ger DE-627 rakwb eng 660 VZ Sa’adeh, Hanan verfasserin aut Photoemission and photofragmentation of butanoic, hexanoic and octanoic acids in the gas phase 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. Octanoic Acid Elsevier Photoelectron Spectroscopy Elsevier NEXAFS Elsevier Butanoic Acid Elsevier Hexanoic Acid Elsevier PEPICO Elsevier Masič, Maša oth Bolognesi, Paola oth Richter, Robert oth Prince, Kevin C. oth Enthalten in Elsevier Bai, Yingrui ELSEVIER Self-healing hydrogels and their action mechanism in oil–gas drilling and development engineering: A systematic review and prospect 2021 the international journal on theoretical, experimental and applied aspects of electron spectroscopy New York, NY [u.a.] (DE-627)ELV007031580 volume:256 year:2022 pages:0 https://doi.org/10.1016/j.elspec.2022.147172 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 256 2022 0 |
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Enthalten in Self-healing hydrogels and their action mechanism in oil–gas drilling and development engineering: A systematic review and prospect New York, NY [u.a.] volume:256 year:2022 pages:0 |
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Enthalten in Self-healing hydrogels and their action mechanism in oil–gas drilling and development engineering: A systematic review and prospect New York, NY [u.a.] volume:256 year:2022 pages:0 |
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Self-healing hydrogels and their action mechanism in oil–gas drilling and development engineering: A systematic review and prospect |
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Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. 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photoemission and photofragmentation of butanoic, hexanoic and octanoic acids in the gas phase |
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Photoemission and photofragmentation of butanoic, hexanoic and octanoic acids in the gas phase |
| abstract |
The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. |
| abstractGer |
The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. |
| abstract_unstemmed |
The valence and C 1 s core photoelectron spectra of three carboxylic acids (butanoic, hexanoic and octanoic) as well as the near-edge absorption fine structure spectra and photo-electron photo-ion coincidence spectra have been measured. Changes in the valence spectra are related to the lengthening of the aliphatic chains, and the core spectra have been assigned. Small shifts of the carboxylic carbon 1 s binding energy are related to screening of the core hole by the aliphatic group. The C K edge near-edge absorption fine structure spectra probe the unoccupied density of states and the main changes in the spectra are due to increasing length of the aliphatic chain and related Rydberg states. The coincidence spectra show that soft (near threshold) ionization of all compounds leads to parent ion formation for butanoic and octanoic acids. For hexanoic acid, both parent ions and fragments are produced for near threshold ionization. Fragmentation occurs at the C2C3 bond for all carboxylic acids at the lowest energies, and other channels open for higher internal energy. |
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Photoemission and photofragmentation of butanoic, hexanoic and octanoic acids in the gas phase |
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