Synergistic adsorption-photocatalytic activity using Z-scheme based magnetic ZnFe2O4/CuWO4 heterojunction for tetracycline removal
Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40)...
Ausführliche Beschreibung
Autor*in: |
Luo, Jinhua [verfasserIn] |
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E-Artikel |
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Englisch |
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2022transfer abstract |
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Enthalten in: Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners - Jacobs, Jacquelyn A. ELSEVIER, 2017, JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics, Lausanne |
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Übergeordnetes Werk: |
volume:910 ; year:2022 ; day:25 ; month:07 ; pages:0 |
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DOI / URN: |
10.1016/j.jallcom.2022.164954 |
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ELV057538069 |
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245 | 1 | 0 | |a Synergistic adsorption-photocatalytic activity using Z-scheme based magnetic ZnFe2O4/CuWO4 heterojunction for tetracycline removal |
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520 | |a Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. | ||
520 | |a Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. | ||
650 | 7 | |a ZnFe2O4/CuWO4 |2 Elsevier | |
650 | 7 | |a Adsorption-photocatalytic |2 Elsevier | |
650 | 7 | |a ZnFe2O4 |2 Elsevier | |
650 | 7 | |a Heterojunction |2 Elsevier | |
650 | 7 | |a Tetracycline |2 Elsevier | |
700 | 1 | |a Wu, Yaohui |4 oth | |
700 | 1 | |a Chen, Xiaoyong |4 oth | |
700 | 1 | |a He, Tianpei |4 oth | |
700 | 1 | |a Zeng, Yelin |4 oth | |
700 | 1 | |a Wang, Guangjun |4 oth | |
700 | 1 | |a Wang, Yonghong |4 oth | |
700 | 1 | |a Zhao, Yunlin |4 oth | |
700 | 1 | |a Chen, Zhifen |4 oth | |
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10.1016/j.jallcom.2022.164954 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001752.pica (DE-627)ELV057538069 (ELSEVIER)S0925-8388(22)01345-7 DE-627 ger DE-627 rakwb eng 630 VZ Luo, Jinhua verfasserin aut Synergistic adsorption-photocatalytic activity using Z-scheme based magnetic ZnFe2O4/CuWO4 heterojunction for tetracycline removal 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. ZnFe2O4/CuWO4 Elsevier Adsorption-photocatalytic Elsevier ZnFe2O4 Elsevier Heterojunction Elsevier Tetracycline Elsevier Wu, Yaohui oth Chen, Xiaoyong oth He, Tianpei oth Zeng, Yelin oth Wang, Guangjun oth Wang, Yonghong oth Zhao, Yunlin oth Chen, Zhifen oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:910 year:2022 day:25 month:07 pages:0 https://doi.org/10.1016/j.jallcom.2022.164954 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 910 2022 25 0725 0 |
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10.1016/j.jallcom.2022.164954 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001752.pica (DE-627)ELV057538069 (ELSEVIER)S0925-8388(22)01345-7 DE-627 ger DE-627 rakwb eng 630 VZ Luo, Jinhua verfasserin aut Synergistic adsorption-photocatalytic activity using Z-scheme based magnetic ZnFe2O4/CuWO4 heterojunction for tetracycline removal 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. ZnFe2O4/CuWO4 Elsevier Adsorption-photocatalytic Elsevier ZnFe2O4 Elsevier Heterojunction Elsevier Tetracycline Elsevier Wu, Yaohui oth Chen, Xiaoyong oth He, Tianpei oth Zeng, Yelin oth Wang, Guangjun oth Wang, Yonghong oth Zhao, Yunlin oth Chen, Zhifen oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:910 year:2022 day:25 month:07 pages:0 https://doi.org/10.1016/j.jallcom.2022.164954 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 910 2022 25 0725 0 |
allfields_unstemmed |
10.1016/j.jallcom.2022.164954 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001752.pica (DE-627)ELV057538069 (ELSEVIER)S0925-8388(22)01345-7 DE-627 ger DE-627 rakwb eng 630 VZ Luo, Jinhua verfasserin aut Synergistic adsorption-photocatalytic activity using Z-scheme based magnetic ZnFe2O4/CuWO4 heterojunction for tetracycline removal 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. ZnFe2O4/CuWO4 Elsevier Adsorption-photocatalytic Elsevier ZnFe2O4 Elsevier Heterojunction Elsevier Tetracycline Elsevier Wu, Yaohui oth Chen, Xiaoyong oth He, Tianpei oth Zeng, Yelin oth Wang, Guangjun oth Wang, Yonghong oth Zhao, Yunlin oth Chen, Zhifen oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:910 year:2022 day:25 month:07 pages:0 https://doi.org/10.1016/j.jallcom.2022.164954 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 910 2022 25 0725 0 |
allfieldsGer |
10.1016/j.jallcom.2022.164954 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001752.pica (DE-627)ELV057538069 (ELSEVIER)S0925-8388(22)01345-7 DE-627 ger DE-627 rakwb eng 630 VZ Luo, Jinhua verfasserin aut Synergistic adsorption-photocatalytic activity using Z-scheme based magnetic ZnFe2O4/CuWO4 heterojunction for tetracycline removal 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. ZnFe2O4/CuWO4 Elsevier Adsorption-photocatalytic Elsevier ZnFe2O4 Elsevier Heterojunction Elsevier Tetracycline Elsevier Wu, Yaohui oth Chen, Xiaoyong oth He, Tianpei oth Zeng, Yelin oth Wang, Guangjun oth Wang, Yonghong oth Zhao, Yunlin oth Chen, Zhifen oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:910 year:2022 day:25 month:07 pages:0 https://doi.org/10.1016/j.jallcom.2022.164954 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 910 2022 25 0725 0 |
allfieldsSound |
10.1016/j.jallcom.2022.164954 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001752.pica (DE-627)ELV057538069 (ELSEVIER)S0925-8388(22)01345-7 DE-627 ger DE-627 rakwb eng 630 VZ Luo, Jinhua verfasserin aut Synergistic adsorption-photocatalytic activity using Z-scheme based magnetic ZnFe2O4/CuWO4 heterojunction for tetracycline removal 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. ZnFe2O4/CuWO4 Elsevier Adsorption-photocatalytic Elsevier ZnFe2O4 Elsevier Heterojunction Elsevier Tetracycline Elsevier Wu, Yaohui oth Chen, Xiaoyong oth He, Tianpei oth Zeng, Yelin oth Wang, Guangjun oth Wang, Yonghong oth Zhao, Yunlin oth Chen, Zhifen oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:910 year:2022 day:25 month:07 pages:0 https://doi.org/10.1016/j.jallcom.2022.164954 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 910 2022 25 0725 0 |
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Synergistic adsorption-photocatalytic activity using Z-scheme based magnetic ZnFe2O4/CuWO4 heterojunction for tetracycline removal |
abstract |
Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. |
abstractGer |
Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. |
abstract_unstemmed |
Developing efficient and economical photocatalysts was considered as an efficient and economical strategy for pollution remediation. Herein, magnetically separable ZnFe2O4/CuWO4 composites (ZW) had been developed via combining ZnFe2O4 with CuWO4. The composite with a mass ratio of 40% CuWO4 (ZW-40) performed best, and the tetracycline hydrochloride (TC) removal by adsorption-photocatalysis of ZW-40 reached 86.5%. The photocatalytic degradation rated constant of it was 9.44 × 10−3 min−1, which was approximately 5.04 and 3.28 times compared to the ZnFe2O4 and CuWO4 samples, respectively. Pseudo-second-order kinetic models could describe well the TC adsorption process, in which chemisorption was the major driving factor, with the maximum adsorption at 23.56 mg g−1. The improved photo-catalytic capability owed to the formation of Z-scheme heterojunctions with ZnFe2O4 and CuWO4, which improved the intensity of visible light absorption and enhanced the separation electron-hole pairs as well as the redox capability of the composite. ZW-40 was high stability as its removal ability of TC in different water conditions slightly dropped about 15% after 5 cycles. ZW-40 could effectively remove TC in different water matrix, its removal ability for 40 mg/L was as follows: super-pure water> municipal wastewater> swine farm wastewater. Hence, the complexation of ZnFe2O4 with CuWO4 provides a valuable strategy to improve the photocatalytic potential for ZnFe2O4-based catalysts as well as providing a promising pathway for water clarification. |
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Synergistic adsorption-photocatalytic activity using Z-scheme based magnetic ZnFe2O4/CuWO4 heterojunction for tetracycline removal |
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