Tunable rare-earth metal−organic frameworks for ultra-high selenite capture
Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand...
Ausführliche Beschreibung
Autor*in: |
Guo, Bingbing [verfasserIn] |
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Sprache: |
Englisch |
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2022transfer abstract |
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Übergeordnetes Werk: |
Enthalten in: Summer bloom of - Moreira-González, Angel R. ELSEVIER, 2020, environmental control, risk assessment, impact and management, New York, NY [u.a.] |
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Übergeordnetes Werk: |
volume:436 ; year:2022 ; day:15 ; month:08 ; pages:0 |
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DOI / URN: |
10.1016/j.jhazmat.2022.129094 |
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520 | |a Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. | ||
520 | |a Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. | ||
650 | 7 | |a Selenite capture |2 Elsevier | |
650 | 7 | |a Nuclear regulation |2 Elsevier | |
650 | 7 | |a Stability |2 Elsevier | |
650 | 7 | |a Rare-earth metal-organic frameworks |2 Elsevier | |
650 | 7 | |a Single-crystal structure |2 Elsevier | |
700 | 1 | |a Liu, Hongyan |4 oth | |
700 | 1 | |a Pang, Jia |4 oth | |
700 | 1 | |a Lyu, Qiang |4 oth | |
700 | 1 | |a Wang, Yutong |4 oth | |
700 | 1 | |a Fan, Weidong |4 oth | |
700 | 1 | |a Lu, Xiaoqing |4 oth | |
700 | 1 | |a Sun, Daofeng |4 oth | |
773 | 0 | 8 | |i Enthalten in |n Science Direct |a Moreira-González, Angel R. ELSEVIER |t Summer bloom of |d 2020 |d environmental control, risk assessment, impact and management |g New York, NY [u.a.] |w (DE-627)ELV005292484 |
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10.1016/j.jhazmat.2022.129094 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001929.pica (DE-627)ELV058190147 (ELSEVIER)S0304-3894(22)00883-4 DE-627 ger DE-627 rakwb eng 333.7 610 VZ 43.12 bkl 43.13 bkl 44.13 bkl Guo, Bingbing verfasserin aut Tunable rare-earth metal−organic frameworks for ultra-high selenite capture 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. Selenite capture Elsevier Nuclear regulation Elsevier Stability Elsevier Rare-earth metal-organic frameworks Elsevier Single-crystal structure Elsevier Liu, Hongyan oth Pang, Jia oth Lyu, Qiang oth Wang, Yutong oth Fan, Weidong oth Lu, Xiaoqing oth Sun, Daofeng oth Enthalten in Science Direct Moreira-González, Angel R. ELSEVIER Summer bloom of 2020 environmental control, risk assessment, impact and management New York, NY [u.a.] (DE-627)ELV005292484 volume:436 year:2022 day:15 month:08 pages:0 https://doi.org/10.1016/j.jhazmat.2022.129094 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO 43.12 Umweltchemie VZ 43.13 Umwelttoxikologie VZ 44.13 Medizinische Ökologie VZ AR 436 2022 15 0815 0 |
spelling |
10.1016/j.jhazmat.2022.129094 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001929.pica (DE-627)ELV058190147 (ELSEVIER)S0304-3894(22)00883-4 DE-627 ger DE-627 rakwb eng 333.7 610 VZ 43.12 bkl 43.13 bkl 44.13 bkl Guo, Bingbing verfasserin aut Tunable rare-earth metal−organic frameworks for ultra-high selenite capture 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. Selenite capture Elsevier Nuclear regulation Elsevier Stability Elsevier Rare-earth metal-organic frameworks Elsevier Single-crystal structure Elsevier Liu, Hongyan oth Pang, Jia oth Lyu, Qiang oth Wang, Yutong oth Fan, Weidong oth Lu, Xiaoqing oth Sun, Daofeng oth Enthalten in Science Direct Moreira-González, Angel R. ELSEVIER Summer bloom of 2020 environmental control, risk assessment, impact and management New York, NY [u.a.] (DE-627)ELV005292484 volume:436 year:2022 day:15 month:08 pages:0 https://doi.org/10.1016/j.jhazmat.2022.129094 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO 43.12 Umweltchemie VZ 43.13 Umwelttoxikologie VZ 44.13 Medizinische Ökologie VZ AR 436 2022 15 0815 0 |
allfields_unstemmed |
10.1016/j.jhazmat.2022.129094 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001929.pica (DE-627)ELV058190147 (ELSEVIER)S0304-3894(22)00883-4 DE-627 ger DE-627 rakwb eng 333.7 610 VZ 43.12 bkl 43.13 bkl 44.13 bkl Guo, Bingbing verfasserin aut Tunable rare-earth metal−organic frameworks for ultra-high selenite capture 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. Selenite capture Elsevier Nuclear regulation Elsevier Stability Elsevier Rare-earth metal-organic frameworks Elsevier Single-crystal structure Elsevier Liu, Hongyan oth Pang, Jia oth Lyu, Qiang oth Wang, Yutong oth Fan, Weidong oth Lu, Xiaoqing oth Sun, Daofeng oth Enthalten in Science Direct Moreira-González, Angel R. ELSEVIER Summer bloom of 2020 environmental control, risk assessment, impact and management New York, NY [u.a.] (DE-627)ELV005292484 volume:436 year:2022 day:15 month:08 pages:0 https://doi.org/10.1016/j.jhazmat.2022.129094 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO 43.12 Umweltchemie VZ 43.13 Umwelttoxikologie VZ 44.13 Medizinische Ökologie VZ AR 436 2022 15 0815 0 |
allfieldsGer |
10.1016/j.jhazmat.2022.129094 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001929.pica (DE-627)ELV058190147 (ELSEVIER)S0304-3894(22)00883-4 DE-627 ger DE-627 rakwb eng 333.7 610 VZ 43.12 bkl 43.13 bkl 44.13 bkl Guo, Bingbing verfasserin aut Tunable rare-earth metal−organic frameworks for ultra-high selenite capture 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. Selenite capture Elsevier Nuclear regulation Elsevier Stability Elsevier Rare-earth metal-organic frameworks Elsevier Single-crystal structure Elsevier Liu, Hongyan oth Pang, Jia oth Lyu, Qiang oth Wang, Yutong oth Fan, Weidong oth Lu, Xiaoqing oth Sun, Daofeng oth Enthalten in Science Direct Moreira-González, Angel R. ELSEVIER Summer bloom of 2020 environmental control, risk assessment, impact and management New York, NY [u.a.] (DE-627)ELV005292484 volume:436 year:2022 day:15 month:08 pages:0 https://doi.org/10.1016/j.jhazmat.2022.129094 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO 43.12 Umweltchemie VZ 43.13 Umwelttoxikologie VZ 44.13 Medizinische Ökologie VZ AR 436 2022 15 0815 0 |
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10.1016/j.jhazmat.2022.129094 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001929.pica (DE-627)ELV058190147 (ELSEVIER)S0304-3894(22)00883-4 DE-627 ger DE-627 rakwb eng 333.7 610 VZ 43.12 bkl 43.13 bkl 44.13 bkl Guo, Bingbing verfasserin aut Tunable rare-earth metal−organic frameworks for ultra-high selenite capture 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. Selenite capture Elsevier Nuclear regulation Elsevier Stability Elsevier Rare-earth metal-organic frameworks Elsevier Single-crystal structure Elsevier Liu, Hongyan oth Pang, Jia oth Lyu, Qiang oth Wang, Yutong oth Fan, Weidong oth Lu, Xiaoqing oth Sun, Daofeng oth Enthalten in Science Direct Moreira-González, Angel R. ELSEVIER Summer bloom of 2020 environmental control, risk assessment, impact and management New York, NY [u.a.] (DE-627)ELV005292484 volume:436 year:2022 day:15 month:08 pages:0 https://doi.org/10.1016/j.jhazmat.2022.129094 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO 43.12 Umweltchemie VZ 43.13 Umwelttoxikologie VZ 44.13 Medizinische Ökologie VZ AR 436 2022 15 0815 0 |
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Tunable rare-earth metal−organic frameworks for ultra-high selenite capture |
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Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. |
abstractGer |
Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. |
abstract_unstemmed |
Linkers and clusters with various conformations present challenges for the design and prediction of highly porous and stable rare-earth metal−organic frameworks (RE-MOFs) for trapping toxic ions in aqueous solutions. Herein, we designed and synthesized a series of RE-MOFs based on a malleable ligand to explore the effects of ligands, clusters, and configurations on structural stability. The results showed that the nonanuclear high-connected UPC-183 exhibited better stability than the hexanuclear low-connected RE-MOF (UPC-181/182 series). Due to the syngenetic effect of chemi- and physisorption, the adsorption capacity of UPC-183-Eu for selenite (SeO3 2-) is as high as 308.39 mg/g, recorded one of the highest ever reported for MOFs. Furthermore, we accurately analyzed the adsorption site of UPC-183-Eu for SeO3 2- through single-crystal structure and theoretical simulation. The ultra-high selenite adsorption capacity and removal efficiency endow UPC-183-Eu an excellent porous adsorbent for removing pollutants. |
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Tunable rare-earth metal−organic frameworks for ultra-high selenite capture |
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