Allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] with the unusual anionic 1D-coordination polymer
A novel π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] (1) with allylcytisine (Acyt) was obtained by ac-electrochemical technique. Both organic compound (Acyt) and complex 1 were structurally characterized. A distinctive feature of structure 1 is the formation of H-bonded pairs of two {Acyt...
Ausführliche Beschreibung
Gespeichert in:
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Slyvka, Yurii [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Schlagwörter: |
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Enthalten in: Resilience resources in low-income Black, Latino, and White fathers - Wilson, Dawn K. ELSEVIER, 2021, the international journal for inorganic and organometallic chemistry, Amsterdam [u.a.] |
|---|---|
| Übergeordnetes Werk: |
volume:224 ; year:2022 ; day:15 ; month:09 ; pages:0 |
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10.1016/j.poly.2022.116022 |
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| 520 | |a A novel π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] (1) with allylcytisine (Acyt) was obtained by ac-electrochemical technique. Both organic compound (Acyt) and complex 1 were structurally characterized. A distinctive feature of structure 1 is the formation of H-bonded pairs of two {Acyt(H+)} cationic conformers, showing the non-equivalent participation of its allyl group regarding to Cu+ coordination, thus forcing the organization of the acentric structure 1 with the unusually organized anionic copper(I) halide 1D-coordination polymer. | ||
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10.1016/j.poly.2022.116022 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001856.pica (DE-627)ELV058508287 (ELSEVIER)S0277-5387(22)00374-6 DE-627 ger DE-627 rakwb eng 300 610 VZ 44.06 bkl Slyvka, Yurii verfasserin aut Allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] with the unusual anionic 1D-coordination polymer 2022 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] (1) with allylcytisine (Acyt) was obtained by ac-electrochemical technique. Both organic compound (Acyt) and complex 1 were structurally characterized. A distinctive feature of structure 1 is the formation of H-bonded pairs of two {Acyt(H+)} cationic conformers, showing the non-equivalent participation of its allyl group regarding to Cu+ coordination, thus forcing the organization of the acentric structure 1 with the unusually organized anionic copper(I) halide 1D-coordination polymer. η 2-Interaction Elsevier Copper(I) Elsevier Cytisine Elsevier Allyl derivative Elsevier Crystal structure Elsevier Goreshnik, Evgeny oth Pokhodylo, Nazariy oth Morozov, Dmitry oth Tupychak, Mykola oth Mys'kiv, Marian oth Enthalten in Elsevier Science Wilson, Dawn K. ELSEVIER Resilience resources in low-income Black, Latino, and White fathers 2021 the international journal for inorganic and organometallic chemistry Amsterdam [u.a.] (DE-627)ELV006270476 volume:224 year:2022 day:15 month:09 pages:0 https://doi.org/10.1016/j.poly.2022.116022 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.06 Medizinsoziologie VZ AR 224 2022 15 0915 0 |
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10.1016/j.poly.2022.116022 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001856.pica (DE-627)ELV058508287 (ELSEVIER)S0277-5387(22)00374-6 DE-627 ger DE-627 rakwb eng 300 610 VZ 44.06 bkl Slyvka, Yurii verfasserin aut Allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] with the unusual anionic 1D-coordination polymer 2022 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] (1) with allylcytisine (Acyt) was obtained by ac-electrochemical technique. Both organic compound (Acyt) and complex 1 were structurally characterized. A distinctive feature of structure 1 is the formation of H-bonded pairs of two {Acyt(H+)} cationic conformers, showing the non-equivalent participation of its allyl group regarding to Cu+ coordination, thus forcing the organization of the acentric structure 1 with the unusually organized anionic copper(I) halide 1D-coordination polymer. η 2-Interaction Elsevier Copper(I) Elsevier Cytisine Elsevier Allyl derivative Elsevier Crystal structure Elsevier Goreshnik, Evgeny oth Pokhodylo, Nazariy oth Morozov, Dmitry oth Tupychak, Mykola oth Mys'kiv, Marian oth Enthalten in Elsevier Science Wilson, Dawn K. ELSEVIER Resilience resources in low-income Black, Latino, and White fathers 2021 the international journal for inorganic and organometallic chemistry Amsterdam [u.a.] (DE-627)ELV006270476 volume:224 year:2022 day:15 month:09 pages:0 https://doi.org/10.1016/j.poly.2022.116022 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.06 Medizinsoziologie VZ AR 224 2022 15 0915 0 |
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10.1016/j.poly.2022.116022 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001856.pica (DE-627)ELV058508287 (ELSEVIER)S0277-5387(22)00374-6 DE-627 ger DE-627 rakwb eng 300 610 VZ 44.06 bkl Slyvka, Yurii verfasserin aut Allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] with the unusual anionic 1D-coordination polymer 2022 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] (1) with allylcytisine (Acyt) was obtained by ac-electrochemical technique. Both organic compound (Acyt) and complex 1 were structurally characterized. A distinctive feature of structure 1 is the formation of H-bonded pairs of two {Acyt(H+)} cationic conformers, showing the non-equivalent participation of its allyl group regarding to Cu+ coordination, thus forcing the organization of the acentric structure 1 with the unusually organized anionic copper(I) halide 1D-coordination polymer. η 2-Interaction Elsevier Copper(I) Elsevier Cytisine Elsevier Allyl derivative Elsevier Crystal structure Elsevier Goreshnik, Evgeny oth Pokhodylo, Nazariy oth Morozov, Dmitry oth Tupychak, Mykola oth Mys'kiv, Marian oth Enthalten in Elsevier Science Wilson, Dawn K. ELSEVIER Resilience resources in low-income Black, Latino, and White fathers 2021 the international journal for inorganic and organometallic chemistry Amsterdam [u.a.] (DE-627)ELV006270476 volume:224 year:2022 day:15 month:09 pages:0 https://doi.org/10.1016/j.poly.2022.116022 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.06 Medizinsoziologie VZ AR 224 2022 15 0915 0 |
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10.1016/j.poly.2022.116022 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001856.pica (DE-627)ELV058508287 (ELSEVIER)S0277-5387(22)00374-6 DE-627 ger DE-627 rakwb eng 300 610 VZ 44.06 bkl Slyvka, Yurii verfasserin aut Allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] with the unusual anionic 1D-coordination polymer 2022 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] (1) with allylcytisine (Acyt) was obtained by ac-electrochemical technique. Both organic compound (Acyt) and complex 1 were structurally characterized. A distinctive feature of structure 1 is the formation of H-bonded pairs of two {Acyt(H+)} cationic conformers, showing the non-equivalent participation of its allyl group regarding to Cu+ coordination, thus forcing the organization of the acentric structure 1 with the unusually organized anionic copper(I) halide 1D-coordination polymer. η 2-Interaction Elsevier Copper(I) Elsevier Cytisine Elsevier Allyl derivative Elsevier Crystal structure Elsevier Goreshnik, Evgeny oth Pokhodylo, Nazariy oth Morozov, Dmitry oth Tupychak, Mykola oth Mys'kiv, Marian oth Enthalten in Elsevier Science Wilson, Dawn K. ELSEVIER Resilience resources in low-income Black, Latino, and White fathers 2021 the international journal for inorganic and organometallic chemistry Amsterdam [u.a.] (DE-627)ELV006270476 volume:224 year:2022 day:15 month:09 pages:0 https://doi.org/10.1016/j.poly.2022.116022 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.06 Medizinsoziologie VZ AR 224 2022 15 0915 0 |
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10.1016/j.poly.2022.116022 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001856.pica (DE-627)ELV058508287 (ELSEVIER)S0277-5387(22)00374-6 DE-627 ger DE-627 rakwb eng 300 610 VZ 44.06 bkl Slyvka, Yurii verfasserin aut Allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] with the unusual anionic 1D-coordination polymer 2022 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] (1) with allylcytisine (Acyt) was obtained by ac-electrochemical technique. Both organic compound (Acyt) and complex 1 were structurally characterized. A distinctive feature of structure 1 is the formation of H-bonded pairs of two {Acyt(H+)} cationic conformers, showing the non-equivalent participation of its allyl group regarding to Cu+ coordination, thus forcing the organization of the acentric structure 1 with the unusually organized anionic copper(I) halide 1D-coordination polymer. η 2-Interaction Elsevier Copper(I) Elsevier Cytisine Elsevier Allyl derivative Elsevier Crystal structure Elsevier Goreshnik, Evgeny oth Pokhodylo, Nazariy oth Morozov, Dmitry oth Tupychak, Mykola oth Mys'kiv, Marian oth Enthalten in Elsevier Science Wilson, Dawn K. ELSEVIER Resilience resources in low-income Black, Latino, and White fathers 2021 the international journal for inorganic and organometallic chemistry Amsterdam [u.a.] (DE-627)ELV006270476 volume:224 year:2022 day:15 month:09 pages:0 https://doi.org/10.1016/j.poly.2022.116022 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.06 Medizinsoziologie VZ AR 224 2022 15 0915 0 |
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allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {acyt(h+)}[cu8{acyt(h+)}cl10] with the unusual anionic 1d-coordination polymer |
| title_auth |
Allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] with the unusual anionic 1D-coordination polymer |
| abstract |
A novel π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] (1) with allylcytisine (Acyt) was obtained by ac-electrochemical technique. Both organic compound (Acyt) and complex 1 were structurally characterized. A distinctive feature of structure 1 is the formation of H-bonded pairs of two {Acyt(H+)} cationic conformers, showing the non-equivalent participation of its allyl group regarding to Cu+ coordination, thus forcing the organization of the acentric structure 1 with the unusually organized anionic copper(I) halide 1D-coordination polymer. |
| abstractGer |
A novel π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] (1) with allylcytisine (Acyt) was obtained by ac-electrochemical technique. Both organic compound (Acyt) and complex 1 were structurally characterized. A distinctive feature of structure 1 is the formation of H-bonded pairs of two {Acyt(H+)} cationic conformers, showing the non-equivalent participation of its allyl group regarding to Cu+ coordination, thus forcing the organization of the acentric structure 1 with the unusually organized anionic copper(I) halide 1D-coordination polymer. |
| abstract_unstemmed |
A novel π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] (1) with allylcytisine (Acyt) was obtained by ac-electrochemical technique. Both organic compound (Acyt) and complex 1 were structurally characterized. A distinctive feature of structure 1 is the formation of H-bonded pairs of two {Acyt(H+)} cationic conformers, showing the non-equivalent participation of its allyl group regarding to Cu+ coordination, thus forcing the organization of the acentric structure 1 with the unusually organized anionic copper(I) halide 1D-coordination polymer. |
| collection_details |
GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA |
| title_short |
Allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] with the unusual anionic 1D-coordination polymer |
| url |
https://doi.org/10.1016/j.poly.2022.116022 |
| remote_bool |
true |
| author2 |
Goreshnik, Evgeny Pokhodylo, Nazariy Morozov, Dmitry Tupychak, Mykola Mys'kiv, Marian |
| author2Str |
Goreshnik, Evgeny Pokhodylo, Nazariy Morozov, Dmitry Tupychak, Mykola Mys'kiv, Marian |
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ELV006270476 |
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| doi_str |
10.1016/j.poly.2022.116022 |
| up_date |
2024-07-06T19:13:43.207Z |
| _version_ |
1803858186818551808 |
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