A sodium tantalum phosphate with a noncentrosymmetric structure: Na5Ta8P5O35
A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with mai...
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| Autor*in: |
Zhang, Qiaoxin [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022transfer abstract |
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| Übergeordnetes Werk: |
Enthalten in: Numerical analysis of wind turbines blade in deep dynamic stall - Karbasian, Hamid Reza ELSEVIER, 2022, Orlando, Fla |
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| Übergeordnetes Werk: |
volume:315 ; year:2022 ; pages:0 |
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| DOI / URN: |
10.1016/j.jssc.2022.123544 |
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ELV058941231 |
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| 245 | 1 | 0 | |a A sodium tantalum phosphate with a noncentrosymmetric structure: Na5Ta8P5O35 |
| 264 | 1 | |c 2022transfer abstract | |
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| 520 | |a A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. | ||
| 520 | |a A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. | ||
| 650 | 7 | |a Nonlinear optical property |2 Elsevier | |
| 650 | 7 | |a Tungsten bronze |2 Elsevier | |
| 650 | 7 | |a Second-order jahn-teller effect |2 Elsevier | |
| 650 | 7 | |a Sodium tantalum phosphate |2 Elsevier | |
| 650 | 7 | |a Noncentrosymmetric structure |2 Elsevier | |
| 700 | 1 | |a Li, Rukang |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Academic Press |a Karbasian, Hamid Reza ELSEVIER |t Numerical analysis of wind turbines blade in deep dynamic stall |d 2022 |g Orlando, Fla |w (DE-627)ELV008417474 |
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| 856 | 4 | 0 | |u https://doi.org/10.1016/j.jssc.2022.123544 |3 Volltext |
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10.1016/j.jssc.2022.123544 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001902.pica (DE-627)ELV058941231 (ELSEVIER)S0022-4596(22)00669-7 DE-627 ger DE-627 rakwb eng 530 620 VZ 52.56 bkl Zhang, Qiaoxin verfasserin aut A sodium tantalum phosphate with a noncentrosymmetric structure: Na5Ta8P5O35 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. Nonlinear optical property Elsevier Tungsten bronze Elsevier Second-order jahn-teller effect Elsevier Sodium tantalum phosphate Elsevier Noncentrosymmetric structure Elsevier Li, Rukang oth Enthalten in Academic Press Karbasian, Hamid Reza ELSEVIER Numerical analysis of wind turbines blade in deep dynamic stall 2022 Orlando, Fla (DE-627)ELV008417474 volume:315 year:2022 pages:0 https://doi.org/10.1016/j.jssc.2022.123544 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 52.56 Regenerative Energieformen alternative Energieformen VZ AR 315 2022 0 |
| spelling |
10.1016/j.jssc.2022.123544 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001902.pica (DE-627)ELV058941231 (ELSEVIER)S0022-4596(22)00669-7 DE-627 ger DE-627 rakwb eng 530 620 VZ 52.56 bkl Zhang, Qiaoxin verfasserin aut A sodium tantalum phosphate with a noncentrosymmetric structure: Na5Ta8P5O35 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. Nonlinear optical property Elsevier Tungsten bronze Elsevier Second-order jahn-teller effect Elsevier Sodium tantalum phosphate Elsevier Noncentrosymmetric structure Elsevier Li, Rukang oth Enthalten in Academic Press Karbasian, Hamid Reza ELSEVIER Numerical analysis of wind turbines blade in deep dynamic stall 2022 Orlando, Fla (DE-627)ELV008417474 volume:315 year:2022 pages:0 https://doi.org/10.1016/j.jssc.2022.123544 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 52.56 Regenerative Energieformen alternative Energieformen VZ AR 315 2022 0 |
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10.1016/j.jssc.2022.123544 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001902.pica (DE-627)ELV058941231 (ELSEVIER)S0022-4596(22)00669-7 DE-627 ger DE-627 rakwb eng 530 620 VZ 52.56 bkl Zhang, Qiaoxin verfasserin aut A sodium tantalum phosphate with a noncentrosymmetric structure: Na5Ta8P5O35 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. Nonlinear optical property Elsevier Tungsten bronze Elsevier Second-order jahn-teller effect Elsevier Sodium tantalum phosphate Elsevier Noncentrosymmetric structure Elsevier Li, Rukang oth Enthalten in Academic Press Karbasian, Hamid Reza ELSEVIER Numerical analysis of wind turbines blade in deep dynamic stall 2022 Orlando, Fla (DE-627)ELV008417474 volume:315 year:2022 pages:0 https://doi.org/10.1016/j.jssc.2022.123544 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 52.56 Regenerative Energieformen alternative Energieformen VZ AR 315 2022 0 |
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10.1016/j.jssc.2022.123544 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001902.pica (DE-627)ELV058941231 (ELSEVIER)S0022-4596(22)00669-7 DE-627 ger DE-627 rakwb eng 530 620 VZ 52.56 bkl Zhang, Qiaoxin verfasserin aut A sodium tantalum phosphate with a noncentrosymmetric structure: Na5Ta8P5O35 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. Nonlinear optical property Elsevier Tungsten bronze Elsevier Second-order jahn-teller effect Elsevier Sodium tantalum phosphate Elsevier Noncentrosymmetric structure Elsevier Li, Rukang oth Enthalten in Academic Press Karbasian, Hamid Reza ELSEVIER Numerical analysis of wind turbines blade in deep dynamic stall 2022 Orlando, Fla (DE-627)ELV008417474 volume:315 year:2022 pages:0 https://doi.org/10.1016/j.jssc.2022.123544 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 52.56 Regenerative Energieformen alternative Energieformen VZ AR 315 2022 0 |
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10.1016/j.jssc.2022.123544 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001902.pica (DE-627)ELV058941231 (ELSEVIER)S0022-4596(22)00669-7 DE-627 ger DE-627 rakwb eng 530 620 VZ 52.56 bkl Zhang, Qiaoxin verfasserin aut A sodium tantalum phosphate with a noncentrosymmetric structure: Na5Ta8P5O35 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. Nonlinear optical property Elsevier Tungsten bronze Elsevier Second-order jahn-teller effect Elsevier Sodium tantalum phosphate Elsevier Noncentrosymmetric structure Elsevier Li, Rukang oth Enthalten in Academic Press Karbasian, Hamid Reza ELSEVIER Numerical analysis of wind turbines blade in deep dynamic stall 2022 Orlando, Fla (DE-627)ELV008417474 volume:315 year:2022 pages:0 https://doi.org/10.1016/j.jssc.2022.123544 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 52.56 Regenerative Energieformen alternative Energieformen VZ AR 315 2022 0 |
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Enthalten in Numerical analysis of wind turbines blade in deep dynamic stall Orlando, Fla volume:315 year:2022 pages:0 |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV058941231</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230626051911.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">221103s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.jssc.2022.123544</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">/cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001902.pica</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV058941231</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0022-4596(22)00669-7</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">530</subfield><subfield code="a">620</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">52.56</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Zhang, Qiaoxin</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">A sodium tantalum phosphate with a noncentrosymmetric structure: Na5Ta8P5O35</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022transfer abstract</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. 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a sodium tantalum phosphate with a noncentrosymmetric structure: na5ta8p5o35 |
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A sodium tantalum phosphate with a noncentrosymmetric structure: Na5Ta8P5O35 |
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A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. |
| abstractGer |
A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. |
| abstract_unstemmed |
A sodium tantalum phosphate Na5Ta8P5O35 has been successfully obtained by spontaneous crystallization in high temperature solution. It belongs to the noncentrosymmetric R32 space group with a = 8.895 (2) Å, c = 29.992 (12) Å and Z = 3. The structure resembles those of tungsten bronzes with main building blocks of the [Ta6O27] unit composed of 2 × 3 corner-sharing Ta1O6 octahedra. [Ta6O27] units are joined by two P1O4 tetrahedra and two Ta2O6 octahedra forming a [Ta8P2O29]∞ layer in the bc plane. Those layers are further connected via P2O4 groups along the c direction leaving triangular and pentagonal tunnels in the 3-dimensional framework. Both sodium atoms reside in the pentagonal tunnel with Na1 (9d) site partially occupied (2/3). The Ta5+ ions show second-order Jahn-Teller effects with TaO6 distortions that are favorable to obtain large hyperpolarizabilities. Powder Kurtz-Perry test and reflectance spectroscopy studies reveal that it exhibits moderate second harmonic effect of about 0.5 × KH2PO4 and an optical band gap of 3.93 eV. |
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A sodium tantalum phosphate with a noncentrosymmetric structure: Na5Ta8P5O35 |
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