Building hybrid luminescent materials: Understanding stacking modes in aggregate structure to emission modulation
Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two C...
Ausführliche Beschreibung
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Khan, Arshad [verfasserIn] |
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Englisch |
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2022transfer abstract |
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Enthalten in: Numerical analysis of wind turbines blade in deep dynamic stall - Karbasian, Hamid Reza ELSEVIER, 2022, Orlando, Fla |
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volume:315 ; year:2022 ; pages:0 |
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DOI / URN: |
10.1016/j.jssc.2022.123441 |
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ELV058943412 |
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520 | |a Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. | ||
520 | |a Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. | ||
650 | 7 | |a Molecular packing |2 Elsevier | |
650 | 7 | |a Charge-transfer cocrystal |2 Elsevier | |
650 | 7 | |a Density functional theory |2 Elsevier | |
650 | 7 | |a Organic luminescent materials |2 Elsevier | |
650 | 7 | |a Tunable emission |2 Elsevier | |
700 | 1 | |a Fan, Hua-Jun Shawn |4 oth | |
700 | 1 | |a Usman, Rabia |4 oth | |
700 | 1 | |a Saleh, Ebraheem Abdu Musad |4 oth | |
700 | 1 | |a Refat, Moamen S. |4 oth | |
700 | 1 | |a Alsimaree, Abdulrahman A. |4 oth | |
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10.1016/j.jssc.2022.123441 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001902.pica (DE-627)ELV058943412 (ELSEVIER)S0022-4596(22)00566-7 DE-627 ger DE-627 rakwb eng 530 620 VZ 52.56 bkl Khan, Arshad verfasserin aut Building hybrid luminescent materials: Understanding stacking modes in aggregate structure to emission modulation 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. Molecular packing Elsevier Charge-transfer cocrystal Elsevier Density functional theory Elsevier Organic luminescent materials Elsevier Tunable emission Elsevier Fan, Hua-Jun Shawn oth Usman, Rabia oth Saleh, Ebraheem Abdu Musad oth Refat, Moamen S. oth Alsimaree, Abdulrahman A. oth Enthalten in Academic Press Karbasian, Hamid Reza ELSEVIER Numerical analysis of wind turbines blade in deep dynamic stall 2022 Orlando, Fla (DE-627)ELV008417474 volume:315 year:2022 pages:0 https://doi.org/10.1016/j.jssc.2022.123441 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 52.56 Regenerative Energieformen alternative Energieformen VZ AR 315 2022 0 |
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10.1016/j.jssc.2022.123441 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001902.pica (DE-627)ELV058943412 (ELSEVIER)S0022-4596(22)00566-7 DE-627 ger DE-627 rakwb eng 530 620 VZ 52.56 bkl Khan, Arshad verfasserin aut Building hybrid luminescent materials: Understanding stacking modes in aggregate structure to emission modulation 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. Molecular packing Elsevier Charge-transfer cocrystal Elsevier Density functional theory Elsevier Organic luminescent materials Elsevier Tunable emission Elsevier Fan, Hua-Jun Shawn oth Usman, Rabia oth Saleh, Ebraheem Abdu Musad oth Refat, Moamen S. oth Alsimaree, Abdulrahman A. oth Enthalten in Academic Press Karbasian, Hamid Reza ELSEVIER Numerical analysis of wind turbines blade in deep dynamic stall 2022 Orlando, Fla (DE-627)ELV008417474 volume:315 year:2022 pages:0 https://doi.org/10.1016/j.jssc.2022.123441 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 52.56 Regenerative Energieformen alternative Energieformen VZ AR 315 2022 0 |
allfields_unstemmed |
10.1016/j.jssc.2022.123441 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001902.pica (DE-627)ELV058943412 (ELSEVIER)S0022-4596(22)00566-7 DE-627 ger DE-627 rakwb eng 530 620 VZ 52.56 bkl Khan, Arshad verfasserin aut Building hybrid luminescent materials: Understanding stacking modes in aggregate structure to emission modulation 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. Molecular packing Elsevier Charge-transfer cocrystal Elsevier Density functional theory Elsevier Organic luminescent materials Elsevier Tunable emission Elsevier Fan, Hua-Jun Shawn oth Usman, Rabia oth Saleh, Ebraheem Abdu Musad oth Refat, Moamen S. oth Alsimaree, Abdulrahman A. oth Enthalten in Academic Press Karbasian, Hamid Reza ELSEVIER Numerical analysis of wind turbines blade in deep dynamic stall 2022 Orlando, Fla (DE-627)ELV008417474 volume:315 year:2022 pages:0 https://doi.org/10.1016/j.jssc.2022.123441 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 52.56 Regenerative Energieformen alternative Energieformen VZ AR 315 2022 0 |
allfieldsGer |
10.1016/j.jssc.2022.123441 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001902.pica (DE-627)ELV058943412 (ELSEVIER)S0022-4596(22)00566-7 DE-627 ger DE-627 rakwb eng 530 620 VZ 52.56 bkl Khan, Arshad verfasserin aut Building hybrid luminescent materials: Understanding stacking modes in aggregate structure to emission modulation 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. Molecular packing Elsevier Charge-transfer cocrystal Elsevier Density functional theory Elsevier Organic luminescent materials Elsevier Tunable emission Elsevier Fan, Hua-Jun Shawn oth Usman, Rabia oth Saleh, Ebraheem Abdu Musad oth Refat, Moamen S. oth Alsimaree, Abdulrahman A. oth Enthalten in Academic Press Karbasian, Hamid Reza ELSEVIER Numerical analysis of wind turbines blade in deep dynamic stall 2022 Orlando, Fla (DE-627)ELV008417474 volume:315 year:2022 pages:0 https://doi.org/10.1016/j.jssc.2022.123441 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 52.56 Regenerative Energieformen alternative Energieformen VZ AR 315 2022 0 |
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10.1016/j.jssc.2022.123441 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001902.pica (DE-627)ELV058943412 (ELSEVIER)S0022-4596(22)00566-7 DE-627 ger DE-627 rakwb eng 530 620 VZ 52.56 bkl Khan, Arshad verfasserin aut Building hybrid luminescent materials: Understanding stacking modes in aggregate structure to emission modulation 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. Molecular packing Elsevier Charge-transfer cocrystal Elsevier Density functional theory Elsevier Organic luminescent materials Elsevier Tunable emission Elsevier Fan, Hua-Jun Shawn oth Usman, Rabia oth Saleh, Ebraheem Abdu Musad oth Refat, Moamen S. oth Alsimaree, Abdulrahman A. oth Enthalten in Academic Press Karbasian, Hamid Reza ELSEVIER Numerical analysis of wind turbines blade in deep dynamic stall 2022 Orlando, Fla (DE-627)ELV008417474 volume:315 year:2022 pages:0 https://doi.org/10.1016/j.jssc.2022.123441 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 52.56 Regenerative Energieformen alternative Energieformen VZ AR 315 2022 0 |
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Building hybrid luminescent materials: Understanding stacking modes in aggregate structure to emission modulation |
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Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. |
abstractGer |
Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. |
abstract_unstemmed |
Two charge transfer (CT) complexes A1 and A2 with tunable emissions were explored by diluting anthracene functionalized stilbene as donors with 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor unit. The effect of substituent tailoring on the supramolecular packing and optical properties of the two CT products was accomplished by various solid-state characterization and theoretical calculations. It was found that these binary CT cocrystals exhibit two types of alternatively sandwiched face-to-face patterns (A1 (DADA), A2 (DAD··DAD), and red-shifted emissions relative to their monomers through π-π interactions accompanied by hydrogen bonds as indicated by the structural analysis. The two crystalline aggregates feature molar ratios of 1:1 or 1:2 and molecular packing-dependent emissions, induced by different dihedral angles attributed to the substituent effect, thereby leading to diverse π-π interactions and charge transfer effects respectively, which further results in tunable photophysical properties. These results suggest that the marriage of substituent engineering and cocrystal engineering is a promising molecular design strategy that will help to understand the relationship between emission property and molecular packing with the aim to guide further the development of novel organic solid luminescent materials. |
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Building hybrid luminescent materials: Understanding stacking modes in aggregate structure to emission modulation |
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