Direct amidation of ferrocenyl/ phenyl β-chlorocinnamaldehyde assisted by chalcogenide metal carbonyl cluster
Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at s...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Sharma, Deepak [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022transfer abstract |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Therapeutic Advances in Pediatric Multiple Sclerosis - 2013, the international journal for the rapid publication of full original research papers and critical reviews in organic chemistry, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:124 ; year:2022 ; day:8 ; month:10 ; pages:0 |
| Links: |
|---|
| DOI / URN: |
10.1016/j.tet.2022.133014 |
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| 520 | |a Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. | ||
| 520 | |a Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. | ||
| 650 | 7 | |a Metal carbonyl |2 Elsevier | |
| 650 | 7 | |a β-chlorocinnamaldehyde |2 Elsevier | |
| 650 | 7 | |a Chalcogen |2 Elsevier | |
| 650 | 7 | |a Clusters |2 Elsevier | |
| 650 | 7 | |a Amidation |2 Elsevier | |
| 650 | 7 | |a Ferrocene |2 Elsevier | |
| 700 | 1 | |a Tomar, Vijesh |4 oth | |
| 700 | 1 | |a Sharma, Charu |4 oth | |
| 700 | 1 | |a Nemiwal, Meena |4 oth | |
| 700 | 1 | |a Joshi, Raj K. |4 oth | |
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10.1016/j.tet.2022.133014 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001911.pica (DE-627)ELV059027932 (ELSEVIER)S0040-4020(22)00464-1 DE-627 ger DE-627 rakwb eng 610 VZ 150 VZ LING DE-30 fid 77.00 bkl Sharma, Deepak verfasserin aut Direct amidation of ferrocenyl/ phenyl β-chlorocinnamaldehyde assisted by chalcogenide metal carbonyl cluster 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. Metal carbonyl Elsevier β-chlorocinnamaldehyde Elsevier Chalcogen Elsevier Clusters Elsevier Amidation Elsevier Ferrocene Elsevier Tomar, Vijesh oth Sharma, Charu oth Nemiwal, Meena oth Joshi, Raj K. oth Enthalten in Elsevier Science Therapeutic Advances in Pediatric Multiple Sclerosis 2013 the international journal for the rapid publication of full original research papers and critical reviews in organic chemistry Amsterdam [u.a.] (DE-627)ELV011938943 volume:124 year:2022 day:8 month:10 pages:0 https://doi.org/10.1016/j.tet.2022.133014 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-LING 77.00 Psychologie: Allgemeines VZ AR 124 2022 8 1008 0 |
| spelling |
10.1016/j.tet.2022.133014 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001911.pica (DE-627)ELV059027932 (ELSEVIER)S0040-4020(22)00464-1 DE-627 ger DE-627 rakwb eng 610 VZ 150 VZ LING DE-30 fid 77.00 bkl Sharma, Deepak verfasserin aut Direct amidation of ferrocenyl/ phenyl β-chlorocinnamaldehyde assisted by chalcogenide metal carbonyl cluster 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. Metal carbonyl Elsevier β-chlorocinnamaldehyde Elsevier Chalcogen Elsevier Clusters Elsevier Amidation Elsevier Ferrocene Elsevier Tomar, Vijesh oth Sharma, Charu oth Nemiwal, Meena oth Joshi, Raj K. oth Enthalten in Elsevier Science Therapeutic Advances in Pediatric Multiple Sclerosis 2013 the international journal for the rapid publication of full original research papers and critical reviews in organic chemistry Amsterdam [u.a.] (DE-627)ELV011938943 volume:124 year:2022 day:8 month:10 pages:0 https://doi.org/10.1016/j.tet.2022.133014 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-LING 77.00 Psychologie: Allgemeines VZ AR 124 2022 8 1008 0 |
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10.1016/j.tet.2022.133014 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001911.pica (DE-627)ELV059027932 (ELSEVIER)S0040-4020(22)00464-1 DE-627 ger DE-627 rakwb eng 610 VZ 150 VZ LING DE-30 fid 77.00 bkl Sharma, Deepak verfasserin aut Direct amidation of ferrocenyl/ phenyl β-chlorocinnamaldehyde assisted by chalcogenide metal carbonyl cluster 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. Metal carbonyl Elsevier β-chlorocinnamaldehyde Elsevier Chalcogen Elsevier Clusters Elsevier Amidation Elsevier Ferrocene Elsevier Tomar, Vijesh oth Sharma, Charu oth Nemiwal, Meena oth Joshi, Raj K. oth Enthalten in Elsevier Science Therapeutic Advances in Pediatric Multiple Sclerosis 2013 the international journal for the rapid publication of full original research papers and critical reviews in organic chemistry Amsterdam [u.a.] (DE-627)ELV011938943 volume:124 year:2022 day:8 month:10 pages:0 https://doi.org/10.1016/j.tet.2022.133014 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-LING 77.00 Psychologie: Allgemeines VZ AR 124 2022 8 1008 0 |
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10.1016/j.tet.2022.133014 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001911.pica (DE-627)ELV059027932 (ELSEVIER)S0040-4020(22)00464-1 DE-627 ger DE-627 rakwb eng 610 VZ 150 VZ LING DE-30 fid 77.00 bkl Sharma, Deepak verfasserin aut Direct amidation of ferrocenyl/ phenyl β-chlorocinnamaldehyde assisted by chalcogenide metal carbonyl cluster 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. Metal carbonyl Elsevier β-chlorocinnamaldehyde Elsevier Chalcogen Elsevier Clusters Elsevier Amidation Elsevier Ferrocene Elsevier Tomar, Vijesh oth Sharma, Charu oth Nemiwal, Meena oth Joshi, Raj K. oth Enthalten in Elsevier Science Therapeutic Advances in Pediatric Multiple Sclerosis 2013 the international journal for the rapid publication of full original research papers and critical reviews in organic chemistry Amsterdam [u.a.] (DE-627)ELV011938943 volume:124 year:2022 day:8 month:10 pages:0 https://doi.org/10.1016/j.tet.2022.133014 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-LING 77.00 Psychologie: Allgemeines VZ AR 124 2022 8 1008 0 |
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10.1016/j.tet.2022.133014 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001911.pica (DE-627)ELV059027932 (ELSEVIER)S0040-4020(22)00464-1 DE-627 ger DE-627 rakwb eng 610 VZ 150 VZ LING DE-30 fid 77.00 bkl Sharma, Deepak verfasserin aut Direct amidation of ferrocenyl/ phenyl β-chlorocinnamaldehyde assisted by chalcogenide metal carbonyl cluster 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. Metal carbonyl Elsevier β-chlorocinnamaldehyde Elsevier Chalcogen Elsevier Clusters Elsevier Amidation Elsevier Ferrocene Elsevier Tomar, Vijesh oth Sharma, Charu oth Nemiwal, Meena oth Joshi, Raj K. oth Enthalten in Elsevier Science Therapeutic Advances in Pediatric Multiple Sclerosis 2013 the international journal for the rapid publication of full original research papers and critical reviews in organic chemistry Amsterdam [u.a.] (DE-627)ELV011938943 volume:124 year:2022 day:8 month:10 pages:0 https://doi.org/10.1016/j.tet.2022.133014 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-LING 77.00 Psychologie: Allgemeines VZ AR 124 2022 8 1008 0 |
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Direct amidation of ferrocenyl/ phenyl β-chlorocinnamaldehyde assisted by chalcogenide metal carbonyl cluster |
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Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. |
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Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. |
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Herein, we report a direct amidation reaction of ferrocenyl/phenyl substituted β-chlorocinnamaldehyde in presence of a robust and chalcogen stabilized iron selenide carbonyl cluster Fe3Se2(CO)9. The amidation of vinylic Csp 2-Cl and amides was established and Csp 2-N bond formation was obtained at strongly feasible reaction conditions. The wide substrate scope of the reaction has been investigated for functionally different amides and β-chloro derivatives. The present method was found to be superior in terms of the time duration, substrate scope, and use of inexpensive metal. Moreover, 2 mol % of cluster Fe3Se2(CO)9 was found to be highly efficient to couple various substituted primary amides (aliphatic, hetero, aromatics) with β-chlorocinnamaldehyde in just 4 h under aerobic conditions. To the best of our minds, it is the first report where the α, β-unsaturated derivatives of ferrocene have been explored for direct amidation reaction. |
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