Grain-size effects on the temperature-dependent elastocaloric cooling performance of polycrystalline NiTi alloy
Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelastici...
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| Autor*in: |
Chen, Junyu [verfasserIn] |
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E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022transfer abstract |
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| Übergeordnetes Werk: |
Enthalten in: Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners - Jacobs, Jacquelyn A. ELSEVIER, 2017, JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics, Lausanne |
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| Übergeordnetes Werk: |
volume:927 ; year:2022 ; day:15 ; month:12 ; pages:0 |
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| DOI / URN: |
10.1016/j.jallcom.2022.166951 |
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ELV059028599 |
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| 245 | 1 | 0 | |a Grain-size effects on the temperature-dependent elastocaloric cooling performance of polycrystalline NiTi alloy |
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| 520 | |a Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. | ||
| 520 | |a Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. | ||
| 650 | 7 | |a Grain size |2 Elsevier | |
| 650 | 7 | |a Temperature dependence |2 Elsevier | |
| 650 | 7 | |a Shape memory alloy |2 Elsevier | |
| 650 | 7 | |a Elastocaloric cooling |2 Elsevier | |
| 650 | 7 | |a Martensitic transformation |2 Elsevier | |
| 700 | 1 | |a Lei, Liping |4 oth | |
| 700 | 1 | |a Fang, Gang |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier |a Jacobs, Jacquelyn A. ELSEVIER |t Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners |d 2017 |d JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics |g Lausanne |w (DE-627)ELV001115774 |
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10.1016/j.jallcom.2022.166951 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001913.pica (DE-627)ELV059028599 (ELSEVIER)S0925-8388(22)03342-4 DE-627 ger DE-627 rakwb eng 630 VZ Chen, Junyu verfasserin aut Grain-size effects on the temperature-dependent elastocaloric cooling performance of polycrystalline NiTi alloy 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. Grain size Elsevier Temperature dependence Elsevier Shape memory alloy Elsevier Elastocaloric cooling Elsevier Martensitic transformation Elsevier Lei, Liping oth Fang, Gang oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:927 year:2022 day:15 month:12 pages:0 https://doi.org/10.1016/j.jallcom.2022.166951 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 927 2022 15 1215 0 |
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10.1016/j.jallcom.2022.166951 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001913.pica (DE-627)ELV059028599 (ELSEVIER)S0925-8388(22)03342-4 DE-627 ger DE-627 rakwb eng 630 VZ Chen, Junyu verfasserin aut Grain-size effects on the temperature-dependent elastocaloric cooling performance of polycrystalline NiTi alloy 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. Grain size Elsevier Temperature dependence Elsevier Shape memory alloy Elsevier Elastocaloric cooling Elsevier Martensitic transformation Elsevier Lei, Liping oth Fang, Gang oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:927 year:2022 day:15 month:12 pages:0 https://doi.org/10.1016/j.jallcom.2022.166951 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 927 2022 15 1215 0 |
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10.1016/j.jallcom.2022.166951 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001913.pica (DE-627)ELV059028599 (ELSEVIER)S0925-8388(22)03342-4 DE-627 ger DE-627 rakwb eng 630 VZ Chen, Junyu verfasserin aut Grain-size effects on the temperature-dependent elastocaloric cooling performance of polycrystalline NiTi alloy 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. Grain size Elsevier Temperature dependence Elsevier Shape memory alloy Elsevier Elastocaloric cooling Elsevier Martensitic transformation Elsevier Lei, Liping oth Fang, Gang oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:927 year:2022 day:15 month:12 pages:0 https://doi.org/10.1016/j.jallcom.2022.166951 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 927 2022 15 1215 0 |
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10.1016/j.jallcom.2022.166951 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001913.pica (DE-627)ELV059028599 (ELSEVIER)S0925-8388(22)03342-4 DE-627 ger DE-627 rakwb eng 630 VZ Chen, Junyu verfasserin aut Grain-size effects on the temperature-dependent elastocaloric cooling performance of polycrystalline NiTi alloy 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. Grain size Elsevier Temperature dependence Elsevier Shape memory alloy Elsevier Elastocaloric cooling Elsevier Martensitic transformation Elsevier Lei, Liping oth Fang, Gang oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:927 year:2022 day:15 month:12 pages:0 https://doi.org/10.1016/j.jallcom.2022.166951 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 927 2022 15 1215 0 |
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10.1016/j.jallcom.2022.166951 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001913.pica (DE-627)ELV059028599 (ELSEVIER)S0925-8388(22)03342-4 DE-627 ger DE-627 rakwb eng 630 VZ Chen, Junyu verfasserin aut Grain-size effects on the temperature-dependent elastocaloric cooling performance of polycrystalline NiTi alloy 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. Grain size Elsevier Temperature dependence Elsevier Shape memory alloy Elsevier Elastocaloric cooling Elsevier Martensitic transformation Elsevier Lei, Liping oth Fang, Gang oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:927 year:2022 day:15 month:12 pages:0 https://doi.org/10.1016/j.jallcom.2022.166951 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 927 2022 15 1215 0 |
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Enthalten in Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners Lausanne volume:927 year:2022 day:15 month:12 pages:0 |
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Grain-size effects on the temperature-dependent elastocaloric cooling performance of polycrystalline NiTi alloy |
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Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. |
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Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. |
| abstract_unstemmed |
Grain-size (GS) effects on the temperature-dependent elastocaloric cooling performance of NiTi with the average GS of 11, 22, 30, 45 and 70 nm are investigated over a temperature range from -50 ℃ to 80 ℃. It is found that GS refinement is conducive to improving the thermal stability of superelasticity and the associated elastocaloric effect, while the trade-off between cooling temperature drop ΔT and effective working temperature span T span, more or less, is inevitable regardless of GS. The large ΔT of the 70 nm-GS specimen, which is characterized by sharp first-order martensitic transformation and strong temperature dependence of the transformation stress dσ tr/dT (= 5.7 MPa/℃), is restricted to a narrow T span (= 19 ℃). T span can be widened by five times via reducing GS to 11 nm but at the expense of a significant sacrifice in ΔT, as the combined result of high strength and small dσ tr/dT (= 0.9 MPa/℃). Among the five microstructures, the 30 nm-GS one achieves a favorable compromise between ΔT and T span owing to the mild transformation nature together with robust mechanical properties. Consequently, its ΔT can reach 50% – 440% of that of the 70 nm-GS counterpart and the resultant cooling efficiency can be enhanced by a factor of half to six. The work demonstrates that GS engineering is a feasible approach for reconciling various elastocaloric cooling metrics of the NiTi refrigerant. |
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