Simple preparation of two-dimensional lamellar ammonium cobalt phosphate materials derived from ZIF-L and its application in supercapacitors
Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and st...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Wang, Yanjing [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022transfer abstract |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners - Jacobs, Jacquelyn A. ELSEVIER, 2017, JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics, Lausanne |
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| Übergeordnetes Werk: |
volume:927 ; year:2022 ; day:15 ; month:12 ; pages:0 |
| Links: |
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| DOI / URN: |
10.1016/j.jallcom.2022.167030 |
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ELV059028904 |
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| 245 | 1 | 0 | |a Simple preparation of two-dimensional lamellar ammonium cobalt phosphate materials derived from ZIF-L and its application in supercapacitors |
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| 520 | |a Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. | ||
| 520 | |a Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. | ||
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| 650 | 7 | |a Nanostructured materials |2 Elsevier | |
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| 700 | 1 | |a Xu, Yanbin |4 oth | |
| 700 | 1 | |a Yin, Ping |4 oth | |
| 700 | 1 | |a Yang, Li-Xia |4 oth | |
| 700 | 1 | |a Wang, Feng |4 oth | |
| 700 | 1 | |a Guo, Xiaoling |4 oth | |
| 700 | 1 | |a Liu, Guijing |4 oth | |
| 700 | 1 | |a Yang, Zheng-Long |4 oth | |
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10.1016/j.jallcom.2022.167030 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001913.pica (DE-627)ELV059028904 (ELSEVIER)S0925-8388(22)03421-1 DE-627 ger DE-627 rakwb eng 630 VZ Wang, Yanjing verfasserin aut Simple preparation of two-dimensional lamellar ammonium cobalt phosphate materials derived from ZIF-L and its application in supercapacitors 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. Electrochemical reactions Elsevier Energy storage materials Elsevier Nanostructured materials Elsevier Fu, Zhenyu oth Xu, Yanbin oth Yin, Ping oth Yang, Li-Xia oth Wang, Feng oth Guo, Xiaoling oth Liu, Guijing oth Yang, Zheng-Long oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:927 year:2022 day:15 month:12 pages:0 https://doi.org/10.1016/j.jallcom.2022.167030 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 927 2022 15 1215 0 |
| spelling |
10.1016/j.jallcom.2022.167030 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001913.pica (DE-627)ELV059028904 (ELSEVIER)S0925-8388(22)03421-1 DE-627 ger DE-627 rakwb eng 630 VZ Wang, Yanjing verfasserin aut Simple preparation of two-dimensional lamellar ammonium cobalt phosphate materials derived from ZIF-L and its application in supercapacitors 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. Electrochemical reactions Elsevier Energy storage materials Elsevier Nanostructured materials Elsevier Fu, Zhenyu oth Xu, Yanbin oth Yin, Ping oth Yang, Li-Xia oth Wang, Feng oth Guo, Xiaoling oth Liu, Guijing oth Yang, Zheng-Long oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:927 year:2022 day:15 month:12 pages:0 https://doi.org/10.1016/j.jallcom.2022.167030 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 927 2022 15 1215 0 |
| allfields_unstemmed |
10.1016/j.jallcom.2022.167030 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001913.pica (DE-627)ELV059028904 (ELSEVIER)S0925-8388(22)03421-1 DE-627 ger DE-627 rakwb eng 630 VZ Wang, Yanjing verfasserin aut Simple preparation of two-dimensional lamellar ammonium cobalt phosphate materials derived from ZIF-L and its application in supercapacitors 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. Electrochemical reactions Elsevier Energy storage materials Elsevier Nanostructured materials Elsevier Fu, Zhenyu oth Xu, Yanbin oth Yin, Ping oth Yang, Li-Xia oth Wang, Feng oth Guo, Xiaoling oth Liu, Guijing oth Yang, Zheng-Long oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:927 year:2022 day:15 month:12 pages:0 https://doi.org/10.1016/j.jallcom.2022.167030 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 927 2022 15 1215 0 |
| allfieldsGer |
10.1016/j.jallcom.2022.167030 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001913.pica (DE-627)ELV059028904 (ELSEVIER)S0925-8388(22)03421-1 DE-627 ger DE-627 rakwb eng 630 VZ Wang, Yanjing verfasserin aut Simple preparation of two-dimensional lamellar ammonium cobalt phosphate materials derived from ZIF-L and its application in supercapacitors 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. Electrochemical reactions Elsevier Energy storage materials Elsevier Nanostructured materials Elsevier Fu, Zhenyu oth Xu, Yanbin oth Yin, Ping oth Yang, Li-Xia oth Wang, Feng oth Guo, Xiaoling oth Liu, Guijing oth Yang, Zheng-Long oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:927 year:2022 day:15 month:12 pages:0 https://doi.org/10.1016/j.jallcom.2022.167030 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 927 2022 15 1215 0 |
| allfieldsSound |
10.1016/j.jallcom.2022.167030 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000001913.pica (DE-627)ELV059028904 (ELSEVIER)S0925-8388(22)03421-1 DE-627 ger DE-627 rakwb eng 630 VZ Wang, Yanjing verfasserin aut Simple preparation of two-dimensional lamellar ammonium cobalt phosphate materials derived from ZIF-L and its application in supercapacitors 2022transfer abstract nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. Electrochemical reactions Elsevier Energy storage materials Elsevier Nanostructured materials Elsevier Fu, Zhenyu oth Xu, Yanbin oth Yin, Ping oth Yang, Li-Xia oth Wang, Feng oth Guo, Xiaoling oth Liu, Guijing oth Yang, Zheng-Long oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:927 year:2022 day:15 month:12 pages:0 https://doi.org/10.1016/j.jallcom.2022.167030 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 927 2022 15 1215 0 |
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Simple preparation of two-dimensional lamellar ammonium cobalt phosphate materials derived from ZIF-L and its application in supercapacitors |
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Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. |
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Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. |
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Supercapacitors have been widely concerned in various energy storage systems for high power density, extended life, and environmental friendliness. In this study, two-dimensional(2D) lamellar phosphate NH4CoPO4·H2O(NCP) materials were generated using Co-MOF as a template by (NH4)2HPO4 etching and stripping. The effect of etching stripping on supercapacitor morphology and energy storage performance was investigated. The two-dimensional lamellar structure, morphology, and electrochemical properties were analyzed by SEM, XRD, XPS, TEM and electrochemical characteristics. The results show that the 2D lamellar nanosheet structure of NH4CoPO4·H2O increases electroactive sites and facilitates complete connection between electrolyte and the active substances, considerably increasing the energy store ability of materials. When the time of phosphate etching is 8 h, the specific capacitance of NCP-8 h reaches 585.83 F·g−1/322.20 C·g−1 (0.6 A·g−1) and remains 457.63 F·g−1/251.69 C·g−1 (10 A·g−1). After 4000 times constant current charge-discharge cycle, the specific capacitance value is kept at 87.3% of the initial value with the current density of 10 A·g−1 under the three-electrode test system. The above demonstrated excellent energy storage performance as well as application possibilities. |
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Simple preparation of two-dimensional lamellar ammonium cobalt phosphate materials derived from ZIF-L and its application in supercapacitors |
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Fu, Zhenyu Xu, Yanbin Yin, Ping Yang, Li-Xia Wang, Feng Guo, Xiaoling Liu, Guijing Yang, Zheng-Long |
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