Determination and correlation of solubility and solution thermodynamics of
Experimental solubility data of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) in three binary solvent mixtures of water + (acetic acid, acetone or DMSO) over the temperature ranges of (283.15–368.15 K) were measured with a gravimetric method under atmospheric pressure. The results all s...
Ausführliche Beschreibung
Autor*in: |
Yin, Ziping [verfasserIn] Gao, Yuan [verfasserIn] Zhang, Yu [verfasserIn] Zhu, Longyi [verfasserIn] Luo, Jun [verfasserIn] |
---|
Format: |
E-Artikel |
---|---|
Sprache: |
Englisch |
Erschienen: |
2023 |
---|
Schlagwörter: |
---|
Übergeordnetes Werk: |
Enthalten in: The journal of chemical thermodynamics - London : Academic Press, 1969, 185 |
---|---|
Übergeordnetes Werk: |
volume:185 |
DOI / URN: |
10.1016/j.jct.2023.107097 |
---|
Katalog-ID: |
ELV06076953X |
---|
LEADER | 01000caa a22002652 4500 | ||
---|---|---|---|
001 | ELV06076953X | ||
003 | DE-627 | ||
005 | 20230926161652.0 | ||
007 | cr uuu---uuuuu | ||
008 | 230722s2023 xx |||||o 00| ||eng c | ||
024 | 7 | |a 10.1016/j.jct.2023.107097 |2 doi | |
035 | |a (DE-627)ELV06076953X | ||
035 | |a (ELSEVIER)S0021-9614(23)00094-0 | ||
040 | |a DE-627 |b ger |c DE-627 |e rda | ||
041 | |a eng | ||
082 | 0 | 4 | |a 540 |q VZ |
084 | |a 35.00 |2 bkl | ||
100 | 1 | |a Yin, Ziping |e verfasserin |4 aut | |
245 | 1 | 0 | |a Determination and correlation of solubility and solution thermodynamics of |
264 | 1 | |c 2023 | |
336 | |a nicht spezifiziert |b zzz |2 rdacontent | ||
337 | |a Computermedien |b c |2 rdamedia | ||
338 | |a Online-Ressource |b cr |2 rdacarrier | ||
520 | |a Experimental solubility data of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) in three binary solvent mixtures of water + (acetic acid, acetone or DMSO) over the temperature ranges of (283.15–368.15 K) were measured with a gravimetric method under atmospheric pressure. The results all showed that the solubility of β-HMX monotonously decreases with the increase of water mole fraction except for that in mixture of water + acetic acid through all given temperatures investigated, which exhibited the trends reach maximum then descending according to the increase of water mole fraction. In the temperature ranges examined, it was found that the solubility of β-HMX in all the tested solvents increased with the rising of temperature. Furthermore, the experimental solubility data in binary solvents was correlated with the modified Apelblat equation, the CNIBS/R-K model and the Jouyban-Acree model, which all gave satisfactory results. Additionally, the mixing Gibbs free energy, enthalpy and entropy of β-HMX in those binary solvent systems were predicted with the correlation of experimental data on basis of the multicomponent NRTL model. | ||
650 | 4 | |a Solubility | |
650 | 4 | |a Thermodynamic models | |
650 | 4 | |a Dissolution thermodynamics | |
700 | 1 | |a Gao, Yuan |e verfasserin |4 aut | |
700 | 1 | |a Zhang, Yu |e verfasserin |4 aut | |
700 | 1 | |a Zhu, Longyi |e verfasserin |4 aut | |
700 | 1 | |a Luo, Jun |e verfasserin |4 aut | |
773 | 0 | 8 | |i Enthalten in |t The journal of chemical thermodynamics |d London : Academic Press, 1969 |g 185 |h Online-Ressource |w (DE-627)266891039 |w (DE-600)1469011-1 |w (DE-576)103373152 |x 0021-9614 |7 nnns |
773 | 1 | 8 | |g volume:185 |
912 | |a GBV_USEFLAG_U | ||
912 | |a GBV_ELV | ||
912 | |a SYSFLAG_U | ||
912 | |a GBV_ILN_20 | ||
912 | |a GBV_ILN_22 | ||
912 | |a GBV_ILN_23 | ||
912 | |a GBV_ILN_24 | ||
912 | |a GBV_ILN_31 | ||
912 | |a GBV_ILN_32 | ||
912 | |a GBV_ILN_40 | ||
912 | |a GBV_ILN_60 | ||
912 | |a GBV_ILN_62 | ||
912 | |a GBV_ILN_69 | ||
912 | |a GBV_ILN_70 | ||
912 | |a GBV_ILN_73 | ||
912 | |a GBV_ILN_74 | ||
912 | |a GBV_ILN_90 | ||
912 | |a GBV_ILN_95 | ||
912 | |a GBV_ILN_100 | ||
912 | |a GBV_ILN_101 | ||
912 | |a GBV_ILN_105 | ||
912 | |a GBV_ILN_110 | ||
912 | |a GBV_ILN_150 | ||
912 | |a GBV_ILN_151 | ||
912 | |a GBV_ILN_187 | ||
912 | |a GBV_ILN_213 | ||
912 | |a GBV_ILN_224 | ||
912 | |a GBV_ILN_230 | ||
912 | |a GBV_ILN_370 | ||
912 | |a GBV_ILN_602 | ||
912 | |a GBV_ILN_702 | ||
912 | |a GBV_ILN_2001 | ||
912 | |a GBV_ILN_2003 | ||
912 | |a GBV_ILN_2004 | ||
912 | |a GBV_ILN_2005 | ||
912 | |a GBV_ILN_2007 | ||
912 | |a GBV_ILN_2009 | ||
912 | |a GBV_ILN_2010 | ||
912 | |a GBV_ILN_2011 | ||
912 | |a GBV_ILN_2014 | ||
912 | |a GBV_ILN_2015 | ||
912 | |a GBV_ILN_2020 | ||
912 | |a GBV_ILN_2021 | ||
912 | |a GBV_ILN_2025 | ||
912 | |a GBV_ILN_2026 | ||
912 | |a GBV_ILN_2027 | ||
912 | |a GBV_ILN_2034 | ||
912 | |a GBV_ILN_2044 | ||
912 | |a GBV_ILN_2048 | ||
912 | |a GBV_ILN_2049 | ||
912 | |a GBV_ILN_2050 | ||
912 | |a GBV_ILN_2055 | ||
912 | |a GBV_ILN_2056 | ||
912 | |a GBV_ILN_2059 | ||
912 | |a GBV_ILN_2061 | ||
912 | |a GBV_ILN_2064 | ||
912 | |a GBV_ILN_2106 | ||
912 | |a GBV_ILN_2110 | ||
912 | |a GBV_ILN_2111 | ||
912 | |a GBV_ILN_2112 | ||
912 | |a GBV_ILN_2122 | ||
912 | |a GBV_ILN_2129 | ||
912 | |a GBV_ILN_2143 | ||
912 | |a GBV_ILN_2152 | ||
912 | |a GBV_ILN_2153 | ||
912 | |a GBV_ILN_2190 | ||
912 | |a GBV_ILN_2232 | ||
912 | |a GBV_ILN_2336 | ||
912 | |a GBV_ILN_2470 | ||
912 | |a GBV_ILN_2507 | ||
912 | |a GBV_ILN_4035 | ||
912 | |a GBV_ILN_4037 | ||
912 | |a GBV_ILN_4112 | ||
912 | |a GBV_ILN_4125 | ||
912 | |a GBV_ILN_4242 | ||
912 | |a GBV_ILN_4249 | ||
912 | |a GBV_ILN_4251 | ||
912 | |a GBV_ILN_4305 | ||
912 | |a GBV_ILN_4306 | ||
912 | |a GBV_ILN_4307 | ||
912 | |a GBV_ILN_4313 | ||
912 | |a GBV_ILN_4322 | ||
912 | |a GBV_ILN_4323 | ||
912 | |a GBV_ILN_4324 | ||
912 | |a GBV_ILN_4326 | ||
912 | |a GBV_ILN_4333 | ||
912 | |a GBV_ILN_4334 | ||
912 | |a GBV_ILN_4338 | ||
912 | |a GBV_ILN_4393 | ||
912 | |a GBV_ILN_4700 | ||
936 | b | k | |a 35.00 |j Chemie: Allgemeines |q VZ |
951 | |a AR | ||
952 | |d 185 |
author_variant |
z y zy y g yg y z yz l z lz j l jl |
---|---|
matchkey_str |
article:00219614:2023----::eemntoadorltooslbltadoui |
hierarchy_sort_str |
2023 |
bklnumber |
35.00 |
publishDate |
2023 |
allfields |
10.1016/j.jct.2023.107097 doi (DE-627)ELV06076953X (ELSEVIER)S0021-9614(23)00094-0 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Yin, Ziping verfasserin aut Determination and correlation of solubility and solution thermodynamics of 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Experimental solubility data of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) in three binary solvent mixtures of water + (acetic acid, acetone or DMSO) over the temperature ranges of (283.15–368.15 K) were measured with a gravimetric method under atmospheric pressure. The results all showed that the solubility of β-HMX monotonously decreases with the increase of water mole fraction except for that in mixture of water + acetic acid through all given temperatures investigated, which exhibited the trends reach maximum then descending according to the increase of water mole fraction. In the temperature ranges examined, it was found that the solubility of β-HMX in all the tested solvents increased with the rising of temperature. Furthermore, the experimental solubility data in binary solvents was correlated with the modified Apelblat equation, the CNIBS/R-K model and the Jouyban-Acree model, which all gave satisfactory results. Additionally, the mixing Gibbs free energy, enthalpy and entropy of β-HMX in those binary solvent systems were predicted with the correlation of experimental data on basis of the multicomponent NRTL model. Solubility Thermodynamic models Dissolution thermodynamics Gao, Yuan verfasserin aut Zhang, Yu verfasserin aut Zhu, Longyi verfasserin aut Luo, Jun verfasserin aut Enthalten in The journal of chemical thermodynamics London : Academic Press, 1969 185 Online-Ressource (DE-627)266891039 (DE-600)1469011-1 (DE-576)103373152 0021-9614 nnns volume:185 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 185 |
spelling |
10.1016/j.jct.2023.107097 doi (DE-627)ELV06076953X (ELSEVIER)S0021-9614(23)00094-0 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Yin, Ziping verfasserin aut Determination and correlation of solubility and solution thermodynamics of 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Experimental solubility data of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) in three binary solvent mixtures of water + (acetic acid, acetone or DMSO) over the temperature ranges of (283.15–368.15 K) were measured with a gravimetric method under atmospheric pressure. The results all showed that the solubility of β-HMX monotonously decreases with the increase of water mole fraction except for that in mixture of water + acetic acid through all given temperatures investigated, which exhibited the trends reach maximum then descending according to the increase of water mole fraction. In the temperature ranges examined, it was found that the solubility of β-HMX in all the tested solvents increased with the rising of temperature. Furthermore, the experimental solubility data in binary solvents was correlated with the modified Apelblat equation, the CNIBS/R-K model and the Jouyban-Acree model, which all gave satisfactory results. Additionally, the mixing Gibbs free energy, enthalpy and entropy of β-HMX in those binary solvent systems were predicted with the correlation of experimental data on basis of the multicomponent NRTL model. Solubility Thermodynamic models Dissolution thermodynamics Gao, Yuan verfasserin aut Zhang, Yu verfasserin aut Zhu, Longyi verfasserin aut Luo, Jun verfasserin aut Enthalten in The journal of chemical thermodynamics London : Academic Press, 1969 185 Online-Ressource (DE-627)266891039 (DE-600)1469011-1 (DE-576)103373152 0021-9614 nnns volume:185 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 185 |
allfields_unstemmed |
10.1016/j.jct.2023.107097 doi (DE-627)ELV06076953X (ELSEVIER)S0021-9614(23)00094-0 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Yin, Ziping verfasserin aut Determination and correlation of solubility and solution thermodynamics of 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Experimental solubility data of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) in three binary solvent mixtures of water + (acetic acid, acetone or DMSO) over the temperature ranges of (283.15–368.15 K) were measured with a gravimetric method under atmospheric pressure. The results all showed that the solubility of β-HMX monotonously decreases with the increase of water mole fraction except for that in mixture of water + acetic acid through all given temperatures investigated, which exhibited the trends reach maximum then descending according to the increase of water mole fraction. In the temperature ranges examined, it was found that the solubility of β-HMX in all the tested solvents increased with the rising of temperature. Furthermore, the experimental solubility data in binary solvents was correlated with the modified Apelblat equation, the CNIBS/R-K model and the Jouyban-Acree model, which all gave satisfactory results. Additionally, the mixing Gibbs free energy, enthalpy and entropy of β-HMX in those binary solvent systems were predicted with the correlation of experimental data on basis of the multicomponent NRTL model. Solubility Thermodynamic models Dissolution thermodynamics Gao, Yuan verfasserin aut Zhang, Yu verfasserin aut Zhu, Longyi verfasserin aut Luo, Jun verfasserin aut Enthalten in The journal of chemical thermodynamics London : Academic Press, 1969 185 Online-Ressource (DE-627)266891039 (DE-600)1469011-1 (DE-576)103373152 0021-9614 nnns volume:185 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 185 |
allfieldsGer |
10.1016/j.jct.2023.107097 doi (DE-627)ELV06076953X (ELSEVIER)S0021-9614(23)00094-0 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Yin, Ziping verfasserin aut Determination and correlation of solubility and solution thermodynamics of 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Experimental solubility data of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) in three binary solvent mixtures of water + (acetic acid, acetone or DMSO) over the temperature ranges of (283.15–368.15 K) were measured with a gravimetric method under atmospheric pressure. The results all showed that the solubility of β-HMX monotonously decreases with the increase of water mole fraction except for that in mixture of water + acetic acid through all given temperatures investigated, which exhibited the trends reach maximum then descending according to the increase of water mole fraction. In the temperature ranges examined, it was found that the solubility of β-HMX in all the tested solvents increased with the rising of temperature. Furthermore, the experimental solubility data in binary solvents was correlated with the modified Apelblat equation, the CNIBS/R-K model and the Jouyban-Acree model, which all gave satisfactory results. Additionally, the mixing Gibbs free energy, enthalpy and entropy of β-HMX in those binary solvent systems were predicted with the correlation of experimental data on basis of the multicomponent NRTL model. Solubility Thermodynamic models Dissolution thermodynamics Gao, Yuan verfasserin aut Zhang, Yu verfasserin aut Zhu, Longyi verfasserin aut Luo, Jun verfasserin aut Enthalten in The journal of chemical thermodynamics London : Academic Press, 1969 185 Online-Ressource (DE-627)266891039 (DE-600)1469011-1 (DE-576)103373152 0021-9614 nnns volume:185 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 185 |
allfieldsSound |
10.1016/j.jct.2023.107097 doi (DE-627)ELV06076953X (ELSEVIER)S0021-9614(23)00094-0 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Yin, Ziping verfasserin aut Determination and correlation of solubility and solution thermodynamics of 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Experimental solubility data of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) in three binary solvent mixtures of water + (acetic acid, acetone or DMSO) over the temperature ranges of (283.15–368.15 K) were measured with a gravimetric method under atmospheric pressure. The results all showed that the solubility of β-HMX monotonously decreases with the increase of water mole fraction except for that in mixture of water + acetic acid through all given temperatures investigated, which exhibited the trends reach maximum then descending according to the increase of water mole fraction. In the temperature ranges examined, it was found that the solubility of β-HMX in all the tested solvents increased with the rising of temperature. Furthermore, the experimental solubility data in binary solvents was correlated with the modified Apelblat equation, the CNIBS/R-K model and the Jouyban-Acree model, which all gave satisfactory results. Additionally, the mixing Gibbs free energy, enthalpy and entropy of β-HMX in those binary solvent systems were predicted with the correlation of experimental data on basis of the multicomponent NRTL model. Solubility Thermodynamic models Dissolution thermodynamics Gao, Yuan verfasserin aut Zhang, Yu verfasserin aut Zhu, Longyi verfasserin aut Luo, Jun verfasserin aut Enthalten in The journal of chemical thermodynamics London : Academic Press, 1969 185 Online-Ressource (DE-627)266891039 (DE-600)1469011-1 (DE-576)103373152 0021-9614 nnns volume:185 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 185 |
language |
English |
source |
Enthalten in The journal of chemical thermodynamics 185 volume:185 |
sourceStr |
Enthalten in The journal of chemical thermodynamics 185 volume:185 |
format_phy_str_mv |
Article |
bklname |
Chemie: Allgemeines |
institution |
findex.gbv.de |
topic_facet |
Solubility Thermodynamic models Dissolution thermodynamics |
dewey-raw |
540 |
isfreeaccess_bool |
false |
container_title |
The journal of chemical thermodynamics |
authorswithroles_txt_mv |
Yin, Ziping @@aut@@ Gao, Yuan @@aut@@ Zhang, Yu @@aut@@ Zhu, Longyi @@aut@@ Luo, Jun @@aut@@ |
publishDateDaySort_date |
2023-01-01T00:00:00Z |
hierarchy_top_id |
266891039 |
dewey-sort |
3540 |
id |
ELV06076953X |
language_de |
englisch |
fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV06076953X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230926161652.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230722s2023 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.jct.2023.107097</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV06076953X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0021-9614(23)00094-0</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Yin, Ziping</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Determination and correlation of solubility and solution thermodynamics of</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Experimental solubility data of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) in three binary solvent mixtures of water + (acetic acid, acetone or DMSO) over the temperature ranges of (283.15–368.15 K) were measured with a gravimetric method under atmospheric pressure. The results all showed that the solubility of β-HMX monotonously decreases with the increase of water mole fraction except for that in mixture of water + acetic acid through all given temperatures investigated, which exhibited the trends reach maximum then descending according to the increase of water mole fraction. In the temperature ranges examined, it was found that the solubility of β-HMX in all the tested solvents increased with the rising of temperature. Furthermore, the experimental solubility data in binary solvents was correlated with the modified Apelblat equation, the CNIBS/R-K model and the Jouyban-Acree model, which all gave satisfactory results. Additionally, the mixing Gibbs free energy, enthalpy and entropy of β-HMX in those binary solvent systems were predicted with the correlation of experimental data on basis of the multicomponent NRTL model.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Solubility</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thermodynamic models</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Dissolution thermodynamics</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Gao, Yuan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Yu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhu, Longyi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Luo, Jun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">The journal of chemical thermodynamics</subfield><subfield code="d">London : Academic Press, 1969</subfield><subfield code="g">185</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)266891039</subfield><subfield code="w">(DE-600)1469011-1</subfield><subfield code="w">(DE-576)103373152</subfield><subfield code="x">0021-9614</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:185</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_101</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.00</subfield><subfield code="j">Chemie: Allgemeines</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">185</subfield></datafield></record></collection>
|
author |
Yin, Ziping |
spellingShingle |
Yin, Ziping ddc 540 bkl 35.00 misc Solubility misc Thermodynamic models misc Dissolution thermodynamics Determination and correlation of solubility and solution thermodynamics of |
authorStr |
Yin, Ziping |
ppnlink_with_tag_str_mv |
@@773@@(DE-627)266891039 |
format |
electronic Article |
dewey-ones |
540 - Chemistry & allied sciences |
delete_txt_mv |
keep |
author_role |
aut aut aut aut aut |
collection |
elsevier |
remote_str |
true |
illustrated |
Not Illustrated |
issn |
0021-9614 |
topic_title |
540 VZ 35.00 bkl Determination and correlation of solubility and solution thermodynamics of Solubility Thermodynamic models Dissolution thermodynamics |
topic |
ddc 540 bkl 35.00 misc Solubility misc Thermodynamic models misc Dissolution thermodynamics |
topic_unstemmed |
ddc 540 bkl 35.00 misc Solubility misc Thermodynamic models misc Dissolution thermodynamics |
topic_browse |
ddc 540 bkl 35.00 misc Solubility misc Thermodynamic models misc Dissolution thermodynamics |
format_facet |
Elektronische Aufsätze Aufsätze Elektronische Ressource |
format_main_str_mv |
Text Zeitschrift/Artikel |
carriertype_str_mv |
cr |
hierarchy_parent_title |
The journal of chemical thermodynamics |
hierarchy_parent_id |
266891039 |
dewey-tens |
540 - Chemistry |
hierarchy_top_title |
The journal of chemical thermodynamics |
isfreeaccess_txt |
false |
familylinks_str_mv |
(DE-627)266891039 (DE-600)1469011-1 (DE-576)103373152 |
title |
Determination and correlation of solubility and solution thermodynamics of |
ctrlnum |
(DE-627)ELV06076953X (ELSEVIER)S0021-9614(23)00094-0 |
title_full |
Determination and correlation of solubility and solution thermodynamics of |
author_sort |
Yin, Ziping |
journal |
The journal of chemical thermodynamics |
journalStr |
The journal of chemical thermodynamics |
lang_code |
eng |
isOA_bool |
false |
dewey-hundreds |
500 - Science |
recordtype |
marc |
publishDateSort |
2023 |
contenttype_str_mv |
zzz |
author_browse |
Yin, Ziping Gao, Yuan Zhang, Yu Zhu, Longyi Luo, Jun |
container_volume |
185 |
class |
540 VZ 35.00 bkl |
format_se |
Elektronische Aufsätze |
author-letter |
Yin, Ziping |
doi_str_mv |
10.1016/j.jct.2023.107097 |
dewey-full |
540 |
author2-role |
verfasserin |
title_sort |
determination and correlation of solubility and solution thermodynamics of |
title_auth |
Determination and correlation of solubility and solution thermodynamics of |
abstract |
Experimental solubility data of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) in three binary solvent mixtures of water + (acetic acid, acetone or DMSO) over the temperature ranges of (283.15–368.15 K) were measured with a gravimetric method under atmospheric pressure. The results all showed that the solubility of β-HMX monotonously decreases with the increase of water mole fraction except for that in mixture of water + acetic acid through all given temperatures investigated, which exhibited the trends reach maximum then descending according to the increase of water mole fraction. In the temperature ranges examined, it was found that the solubility of β-HMX in all the tested solvents increased with the rising of temperature. Furthermore, the experimental solubility data in binary solvents was correlated with the modified Apelblat equation, the CNIBS/R-K model and the Jouyban-Acree model, which all gave satisfactory results. Additionally, the mixing Gibbs free energy, enthalpy and entropy of β-HMX in those binary solvent systems were predicted with the correlation of experimental data on basis of the multicomponent NRTL model. |
abstractGer |
Experimental solubility data of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) in three binary solvent mixtures of water + (acetic acid, acetone or DMSO) over the temperature ranges of (283.15–368.15 K) were measured with a gravimetric method under atmospheric pressure. The results all showed that the solubility of β-HMX monotonously decreases with the increase of water mole fraction except for that in mixture of water + acetic acid through all given temperatures investigated, which exhibited the trends reach maximum then descending according to the increase of water mole fraction. In the temperature ranges examined, it was found that the solubility of β-HMX in all the tested solvents increased with the rising of temperature. Furthermore, the experimental solubility data in binary solvents was correlated with the modified Apelblat equation, the CNIBS/R-K model and the Jouyban-Acree model, which all gave satisfactory results. Additionally, the mixing Gibbs free energy, enthalpy and entropy of β-HMX in those binary solvent systems were predicted with the correlation of experimental data on basis of the multicomponent NRTL model. |
abstract_unstemmed |
Experimental solubility data of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) in three binary solvent mixtures of water + (acetic acid, acetone or DMSO) over the temperature ranges of (283.15–368.15 K) were measured with a gravimetric method under atmospheric pressure. The results all showed that the solubility of β-HMX monotonously decreases with the increase of water mole fraction except for that in mixture of water + acetic acid through all given temperatures investigated, which exhibited the trends reach maximum then descending according to the increase of water mole fraction. In the temperature ranges examined, it was found that the solubility of β-HMX in all the tested solvents increased with the rising of temperature. Furthermore, the experimental solubility data in binary solvents was correlated with the modified Apelblat equation, the CNIBS/R-K model and the Jouyban-Acree model, which all gave satisfactory results. Additionally, the mixing Gibbs free energy, enthalpy and entropy of β-HMX in those binary solvent systems were predicted with the correlation of experimental data on basis of the multicomponent NRTL model. |
collection_details |
GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 |
title_short |
Determination and correlation of solubility and solution thermodynamics of |
remote_bool |
true |
author2 |
Gao, Yuan Zhang, Yu Zhu, Longyi Luo, Jun |
author2Str |
Gao, Yuan Zhang, Yu Zhu, Longyi Luo, Jun |
ppnlink |
266891039 |
mediatype_str_mv |
c |
isOA_txt |
false |
hochschulschrift_bool |
false |
doi_str |
10.1016/j.jct.2023.107097 |
up_date |
2024-07-06T16:48:37.095Z |
_version_ |
1803849057798455296 |
fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV06076953X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230926161652.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230722s2023 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.jct.2023.107097</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV06076953X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0021-9614(23)00094-0</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Yin, Ziping</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Determination and correlation of solubility and solution thermodynamics of</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Experimental solubility data of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) in three binary solvent mixtures of water + (acetic acid, acetone or DMSO) over the temperature ranges of (283.15–368.15 K) were measured with a gravimetric method under atmospheric pressure. The results all showed that the solubility of β-HMX monotonously decreases with the increase of water mole fraction except for that in mixture of water + acetic acid through all given temperatures investigated, which exhibited the trends reach maximum then descending according to the increase of water mole fraction. In the temperature ranges examined, it was found that the solubility of β-HMX in all the tested solvents increased with the rising of temperature. Furthermore, the experimental solubility data in binary solvents was correlated with the modified Apelblat equation, the CNIBS/R-K model and the Jouyban-Acree model, which all gave satisfactory results. Additionally, the mixing Gibbs free energy, enthalpy and entropy of β-HMX in those binary solvent systems were predicted with the correlation of experimental data on basis of the multicomponent NRTL model.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Solubility</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thermodynamic models</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Dissolution thermodynamics</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Gao, Yuan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Yu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhu, Longyi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Luo, Jun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">The journal of chemical thermodynamics</subfield><subfield code="d">London : Academic Press, 1969</subfield><subfield code="g">185</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)266891039</subfield><subfield code="w">(DE-600)1469011-1</subfield><subfield code="w">(DE-576)103373152</subfield><subfield code="x">0021-9614</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:185</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_101</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.00</subfield><subfield code="j">Chemie: Allgemeines</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">185</subfield></datafield></record></collection>
|
score |
7.399131 |