Effect of heat-treatment temperature on the structure of calcium phosphate synthesized by wet precipitation
In this work, nanometric calcium phosphate (CaP) was synthesized by wet chemical precipitation using Ca(OH)2 and H3(PO4). The subsequent heat treatment was carried out varying from 25 °C to 1000 °C, to study the changes caused in the structure of the final product through XRD, FTIR, Fluorescence, Ra...
Ausführliche Beschreibung
Autor*in: |
Zampieron, Carla Irene [verfasserIn] Cesca, Karina [verfasserIn] Faita, Fabricio Luiz [verfasserIn] Immich, Ana Paula Serafini [verfasserIn] Parize, Alexandre Luis [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2023 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Ceramics international - Amsterdam [u.a.] : Elsevier Science, 1995, 49, Seite 29198-29207 |
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Übergeordnetes Werk: |
volume:49 ; pages:29198-29207 |
DOI / URN: |
10.1016/j.ceramint.2023.06.204 |
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Katalog-ID: |
ELV060907681 |
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520 | |a In this work, nanometric calcium phosphate (CaP) was synthesized by wet chemical precipitation using Ca(OH)2 and H3(PO4). The subsequent heat treatment was carried out varying from 25 °C to 1000 °C, to study the changes caused in the structure of the final product through XRD, FTIR, Fluorescence, Raman, UV–Vis, DLS, Zeta Potential, SEM and TEM/EDS analyses. Cell viability was measured via MTS assays. XRD showed that the crystallinity of the synthetic calcium phosphate obtained increases with increasing heat-treatment temperature, getting close to the structure of hydroxyapatite. In the FTIR, Raman and UV–vis spectroscopic analyses, carbonate removal from the synthesized CaP structure at high heat-treatment temperatures was observed. Samples T800 and T1000 showed greater fluorescence. DLS measurements revealed the formation of aggregates at heat-treatment temperatures lower than 800 °C. According to the Zeta Potential measurements, T1000 is the most stable colloid (−28.4 ± 1.4 mV). The thermal treatment also affected the morphology of the samples, and nanowhiskers, nanorods and nanocubes were observed. In addition, the viability assay revealed that a decrease in particle sizes in CaP samples led to a decrease in metabolic activity, showing that the correct choice of particle size is the key to producing compounds that favor cell proliferation, making it a promising material for bone tissue engineering. | ||
650 | 4 | |a Synthetic calcium phosphate | |
650 | 4 | |a Heat treatment | |
650 | 4 | |a Crystallinity | |
700 | 1 | |a Cesca, Karina |e verfasserin |0 (orcid)0000-0002-8932-919X |4 aut | |
700 | 1 | |a Faita, Fabricio Luiz |e verfasserin |4 aut | |
700 | 1 | |a Immich, Ana Paula Serafini |e verfasserin |4 aut | |
700 | 1 | |a Parize, Alexandre Luis |e verfasserin |0 (orcid)0000-0002-9986-1956 |4 aut | |
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10.1016/j.ceramint.2023.06.204 doi (DE-627)ELV060907681 (ELSEVIER)S0272-8842(23)01791-1 DE-627 ger DE-627 rda eng 670 VZ 51.60 bkl 58.45 bkl Zampieron, Carla Irene verfasserin (orcid)0000-0002-8138-5912 aut Effect of heat-treatment temperature on the structure of calcium phosphate synthesized by wet precipitation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this work, nanometric calcium phosphate (CaP) was synthesized by wet chemical precipitation using Ca(OH)2 and H3(PO4). The subsequent heat treatment was carried out varying from 25 °C to 1000 °C, to study the changes caused in the structure of the final product through XRD, FTIR, Fluorescence, Raman, UV–Vis, DLS, Zeta Potential, SEM and TEM/EDS analyses. Cell viability was measured via MTS assays. XRD showed that the crystallinity of the synthetic calcium phosphate obtained increases with increasing heat-treatment temperature, getting close to the structure of hydroxyapatite. In the FTIR, Raman and UV–vis spectroscopic analyses, carbonate removal from the synthesized CaP structure at high heat-treatment temperatures was observed. Samples T800 and T1000 showed greater fluorescence. DLS measurements revealed the formation of aggregates at heat-treatment temperatures lower than 800 °C. According to the Zeta Potential measurements, T1000 is the most stable colloid (−28.4 ± 1.4 mV). The thermal treatment also affected the morphology of the samples, and nanowhiskers, nanorods and nanocubes were observed. In addition, the viability assay revealed that a decrease in particle sizes in CaP samples led to a decrease in metabolic activity, showing that the correct choice of particle size is the key to producing compounds that favor cell proliferation, making it a promising material for bone tissue engineering. Synthetic calcium phosphate Heat treatment Crystallinity Cesca, Karina verfasserin (orcid)0000-0002-8932-919X aut Faita, Fabricio Luiz verfasserin aut Immich, Ana Paula Serafini verfasserin aut Parize, Alexandre Luis verfasserin (orcid)0000-0002-9986-1956 aut Enthalten in Ceramics international Amsterdam [u.a.] : Elsevier Science, 1995 49, Seite 29198-29207 Online-Ressource (DE-627)320584305 (DE-600)2018052-4 (DE-576)25523063X 0272-8842 nnns volume:49 pages:29198-29207 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 58.45 Gesteinshüttenkunde VZ AR 49 29198-29207 |
spelling |
10.1016/j.ceramint.2023.06.204 doi (DE-627)ELV060907681 (ELSEVIER)S0272-8842(23)01791-1 DE-627 ger DE-627 rda eng 670 VZ 51.60 bkl 58.45 bkl Zampieron, Carla Irene verfasserin (orcid)0000-0002-8138-5912 aut Effect of heat-treatment temperature on the structure of calcium phosphate synthesized by wet precipitation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this work, nanometric calcium phosphate (CaP) was synthesized by wet chemical precipitation using Ca(OH)2 and H3(PO4). The subsequent heat treatment was carried out varying from 25 °C to 1000 °C, to study the changes caused in the structure of the final product through XRD, FTIR, Fluorescence, Raman, UV–Vis, DLS, Zeta Potential, SEM and TEM/EDS analyses. Cell viability was measured via MTS assays. XRD showed that the crystallinity of the synthetic calcium phosphate obtained increases with increasing heat-treatment temperature, getting close to the structure of hydroxyapatite. In the FTIR, Raman and UV–vis spectroscopic analyses, carbonate removal from the synthesized CaP structure at high heat-treatment temperatures was observed. Samples T800 and T1000 showed greater fluorescence. DLS measurements revealed the formation of aggregates at heat-treatment temperatures lower than 800 °C. According to the Zeta Potential measurements, T1000 is the most stable colloid (−28.4 ± 1.4 mV). The thermal treatment also affected the morphology of the samples, and nanowhiskers, nanorods and nanocubes were observed. In addition, the viability assay revealed that a decrease in particle sizes in CaP samples led to a decrease in metabolic activity, showing that the correct choice of particle size is the key to producing compounds that favor cell proliferation, making it a promising material for bone tissue engineering. Synthetic calcium phosphate Heat treatment Crystallinity Cesca, Karina verfasserin (orcid)0000-0002-8932-919X aut Faita, Fabricio Luiz verfasserin aut Immich, Ana Paula Serafini verfasserin aut Parize, Alexandre Luis verfasserin (orcid)0000-0002-9986-1956 aut Enthalten in Ceramics international Amsterdam [u.a.] : Elsevier Science, 1995 49, Seite 29198-29207 Online-Ressource (DE-627)320584305 (DE-600)2018052-4 (DE-576)25523063X 0272-8842 nnns volume:49 pages:29198-29207 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 58.45 Gesteinshüttenkunde VZ AR 49 29198-29207 |
allfields_unstemmed |
10.1016/j.ceramint.2023.06.204 doi (DE-627)ELV060907681 (ELSEVIER)S0272-8842(23)01791-1 DE-627 ger DE-627 rda eng 670 VZ 51.60 bkl 58.45 bkl Zampieron, Carla Irene verfasserin (orcid)0000-0002-8138-5912 aut Effect of heat-treatment temperature on the structure of calcium phosphate synthesized by wet precipitation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this work, nanometric calcium phosphate (CaP) was synthesized by wet chemical precipitation using Ca(OH)2 and H3(PO4). The subsequent heat treatment was carried out varying from 25 °C to 1000 °C, to study the changes caused in the structure of the final product through XRD, FTIR, Fluorescence, Raman, UV–Vis, DLS, Zeta Potential, SEM and TEM/EDS analyses. Cell viability was measured via MTS assays. XRD showed that the crystallinity of the synthetic calcium phosphate obtained increases with increasing heat-treatment temperature, getting close to the structure of hydroxyapatite. In the FTIR, Raman and UV–vis spectroscopic analyses, carbonate removal from the synthesized CaP structure at high heat-treatment temperatures was observed. Samples T800 and T1000 showed greater fluorescence. DLS measurements revealed the formation of aggregates at heat-treatment temperatures lower than 800 °C. According to the Zeta Potential measurements, T1000 is the most stable colloid (−28.4 ± 1.4 mV). The thermal treatment also affected the morphology of the samples, and nanowhiskers, nanorods and nanocubes were observed. In addition, the viability assay revealed that a decrease in particle sizes in CaP samples led to a decrease in metabolic activity, showing that the correct choice of particle size is the key to producing compounds that favor cell proliferation, making it a promising material for bone tissue engineering. Synthetic calcium phosphate Heat treatment Crystallinity Cesca, Karina verfasserin (orcid)0000-0002-8932-919X aut Faita, Fabricio Luiz verfasserin aut Immich, Ana Paula Serafini verfasserin aut Parize, Alexandre Luis verfasserin (orcid)0000-0002-9986-1956 aut Enthalten in Ceramics international Amsterdam [u.a.] : Elsevier Science, 1995 49, Seite 29198-29207 Online-Ressource (DE-627)320584305 (DE-600)2018052-4 (DE-576)25523063X 0272-8842 nnns volume:49 pages:29198-29207 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 58.45 Gesteinshüttenkunde VZ AR 49 29198-29207 |
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10.1016/j.ceramint.2023.06.204 doi (DE-627)ELV060907681 (ELSEVIER)S0272-8842(23)01791-1 DE-627 ger DE-627 rda eng 670 VZ 51.60 bkl 58.45 bkl Zampieron, Carla Irene verfasserin (orcid)0000-0002-8138-5912 aut Effect of heat-treatment temperature on the structure of calcium phosphate synthesized by wet precipitation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this work, nanometric calcium phosphate (CaP) was synthesized by wet chemical precipitation using Ca(OH)2 and H3(PO4). The subsequent heat treatment was carried out varying from 25 °C to 1000 °C, to study the changes caused in the structure of the final product through XRD, FTIR, Fluorescence, Raman, UV–Vis, DLS, Zeta Potential, SEM and TEM/EDS analyses. Cell viability was measured via MTS assays. XRD showed that the crystallinity of the synthetic calcium phosphate obtained increases with increasing heat-treatment temperature, getting close to the structure of hydroxyapatite. In the FTIR, Raman and UV–vis spectroscopic analyses, carbonate removal from the synthesized CaP structure at high heat-treatment temperatures was observed. Samples T800 and T1000 showed greater fluorescence. DLS measurements revealed the formation of aggregates at heat-treatment temperatures lower than 800 °C. According to the Zeta Potential measurements, T1000 is the most stable colloid (−28.4 ± 1.4 mV). The thermal treatment also affected the morphology of the samples, and nanowhiskers, nanorods and nanocubes were observed. In addition, the viability assay revealed that a decrease in particle sizes in CaP samples led to a decrease in metabolic activity, showing that the correct choice of particle size is the key to producing compounds that favor cell proliferation, making it a promising material for bone tissue engineering. Synthetic calcium phosphate Heat treatment Crystallinity Cesca, Karina verfasserin (orcid)0000-0002-8932-919X aut Faita, Fabricio Luiz verfasserin aut Immich, Ana Paula Serafini verfasserin aut Parize, Alexandre Luis verfasserin (orcid)0000-0002-9986-1956 aut Enthalten in Ceramics international Amsterdam [u.a.] : Elsevier Science, 1995 49, Seite 29198-29207 Online-Ressource (DE-627)320584305 (DE-600)2018052-4 (DE-576)25523063X 0272-8842 nnns volume:49 pages:29198-29207 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 58.45 Gesteinshüttenkunde VZ AR 49 29198-29207 |
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10.1016/j.ceramint.2023.06.204 doi (DE-627)ELV060907681 (ELSEVIER)S0272-8842(23)01791-1 DE-627 ger DE-627 rda eng 670 VZ 51.60 bkl 58.45 bkl Zampieron, Carla Irene verfasserin (orcid)0000-0002-8138-5912 aut Effect of heat-treatment temperature on the structure of calcium phosphate synthesized by wet precipitation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this work, nanometric calcium phosphate (CaP) was synthesized by wet chemical precipitation using Ca(OH)2 and H3(PO4). The subsequent heat treatment was carried out varying from 25 °C to 1000 °C, to study the changes caused in the structure of the final product through XRD, FTIR, Fluorescence, Raman, UV–Vis, DLS, Zeta Potential, SEM and TEM/EDS analyses. Cell viability was measured via MTS assays. XRD showed that the crystallinity of the synthetic calcium phosphate obtained increases with increasing heat-treatment temperature, getting close to the structure of hydroxyapatite. In the FTIR, Raman and UV–vis spectroscopic analyses, carbonate removal from the synthesized CaP structure at high heat-treatment temperatures was observed. Samples T800 and T1000 showed greater fluorescence. DLS measurements revealed the formation of aggregates at heat-treatment temperatures lower than 800 °C. According to the Zeta Potential measurements, T1000 is the most stable colloid (−28.4 ± 1.4 mV). The thermal treatment also affected the morphology of the samples, and nanowhiskers, nanorods and nanocubes were observed. In addition, the viability assay revealed that a decrease in particle sizes in CaP samples led to a decrease in metabolic activity, showing that the correct choice of particle size is the key to producing compounds that favor cell proliferation, making it a promising material for bone tissue engineering. Synthetic calcium phosphate Heat treatment Crystallinity Cesca, Karina verfasserin (orcid)0000-0002-8932-919X aut Faita, Fabricio Luiz verfasserin aut Immich, Ana Paula Serafini verfasserin aut Parize, Alexandre Luis verfasserin (orcid)0000-0002-9986-1956 aut Enthalten in Ceramics international Amsterdam [u.a.] : Elsevier Science, 1995 49, Seite 29198-29207 Online-Ressource (DE-627)320584305 (DE-600)2018052-4 (DE-576)25523063X 0272-8842 nnns volume:49 pages:29198-29207 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 58.45 Gesteinshüttenkunde VZ AR 49 29198-29207 |
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670 VZ 51.60 bkl 58.45 bkl Effect of heat-treatment temperature on the structure of calcium phosphate synthesized by wet precipitation Synthetic calcium phosphate Heat treatment Crystallinity |
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Effect of heat-treatment temperature on the structure of calcium phosphate synthesized by wet precipitation |
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effect of heat-treatment temperature on the structure of calcium phosphate synthesized by wet precipitation |
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Effect of heat-treatment temperature on the structure of calcium phosphate synthesized by wet precipitation |
abstract |
In this work, nanometric calcium phosphate (CaP) was synthesized by wet chemical precipitation using Ca(OH)2 and H3(PO4). The subsequent heat treatment was carried out varying from 25 °C to 1000 °C, to study the changes caused in the structure of the final product through XRD, FTIR, Fluorescence, Raman, UV–Vis, DLS, Zeta Potential, SEM and TEM/EDS analyses. Cell viability was measured via MTS assays. XRD showed that the crystallinity of the synthetic calcium phosphate obtained increases with increasing heat-treatment temperature, getting close to the structure of hydroxyapatite. In the FTIR, Raman and UV–vis spectroscopic analyses, carbonate removal from the synthesized CaP structure at high heat-treatment temperatures was observed. Samples T800 and T1000 showed greater fluorescence. DLS measurements revealed the formation of aggregates at heat-treatment temperatures lower than 800 °C. According to the Zeta Potential measurements, T1000 is the most stable colloid (−28.4 ± 1.4 mV). The thermal treatment also affected the morphology of the samples, and nanowhiskers, nanorods and nanocubes were observed. In addition, the viability assay revealed that a decrease in particle sizes in CaP samples led to a decrease in metabolic activity, showing that the correct choice of particle size is the key to producing compounds that favor cell proliferation, making it a promising material for bone tissue engineering. |
abstractGer |
In this work, nanometric calcium phosphate (CaP) was synthesized by wet chemical precipitation using Ca(OH)2 and H3(PO4). The subsequent heat treatment was carried out varying from 25 °C to 1000 °C, to study the changes caused in the structure of the final product through XRD, FTIR, Fluorescence, Raman, UV–Vis, DLS, Zeta Potential, SEM and TEM/EDS analyses. Cell viability was measured via MTS assays. XRD showed that the crystallinity of the synthetic calcium phosphate obtained increases with increasing heat-treatment temperature, getting close to the structure of hydroxyapatite. In the FTIR, Raman and UV–vis spectroscopic analyses, carbonate removal from the synthesized CaP structure at high heat-treatment temperatures was observed. Samples T800 and T1000 showed greater fluorescence. DLS measurements revealed the formation of aggregates at heat-treatment temperatures lower than 800 °C. According to the Zeta Potential measurements, T1000 is the most stable colloid (−28.4 ± 1.4 mV). The thermal treatment also affected the morphology of the samples, and nanowhiskers, nanorods and nanocubes were observed. In addition, the viability assay revealed that a decrease in particle sizes in CaP samples led to a decrease in metabolic activity, showing that the correct choice of particle size is the key to producing compounds that favor cell proliferation, making it a promising material for bone tissue engineering. |
abstract_unstemmed |
In this work, nanometric calcium phosphate (CaP) was synthesized by wet chemical precipitation using Ca(OH)2 and H3(PO4). The subsequent heat treatment was carried out varying from 25 °C to 1000 °C, to study the changes caused in the structure of the final product through XRD, FTIR, Fluorescence, Raman, UV–Vis, DLS, Zeta Potential, SEM and TEM/EDS analyses. Cell viability was measured via MTS assays. XRD showed that the crystallinity of the synthetic calcium phosphate obtained increases with increasing heat-treatment temperature, getting close to the structure of hydroxyapatite. In the FTIR, Raman and UV–vis spectroscopic analyses, carbonate removal from the synthesized CaP structure at high heat-treatment temperatures was observed. Samples T800 and T1000 showed greater fluorescence. DLS measurements revealed the formation of aggregates at heat-treatment temperatures lower than 800 °C. According to the Zeta Potential measurements, T1000 is the most stable colloid (−28.4 ± 1.4 mV). The thermal treatment also affected the morphology of the samples, and nanowhiskers, nanorods and nanocubes were observed. In addition, the viability assay revealed that a decrease in particle sizes in CaP samples led to a decrease in metabolic activity, showing that the correct choice of particle size is the key to producing compounds that favor cell proliferation, making it a promising material for bone tissue engineering. |
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