Phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure CO

The phase behavior study of allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate in supercritical CO2 (S-CO2) is important for several industrial processes. This study investigated the binary mixture solubility curves of the three systems (allyl acetoacetate, methyl acetoacetate, and ethy...
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Gespeichert in:

Autor*in:	Lee, Hyun-Seok [verfasserIn] Ghoderao, Pradnya N.P. [verfasserIn] Soo Park, Min [verfasserIn] Byun, Hun-Soo [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Allyl acetoacetate Methyl acetoacetate Ethyl acetoacetate High pressure CO2 Phase behavior

Übergeordnetes Werk:	Enthalten in: Journal of molecular liquids - New York, NY [u.a.] : Elsevier, 1983, 387
Übergeordnetes Werk:	volume:387

DOI / URN:	10.1016/j.molliq.2023.122651

Katalog-ID:	ELV061519375

Internformat


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100	1		\|a Lee, Hyun-Seok \|e verfasserin \|0 (orcid)0009-0008-2373-1953 \|4 aut
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520			\|a The phase behavior study of allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate in supercritical CO2 (S-CO2) is important for several industrial processes. This study investigated the binary mixture solubility curves of the three systems (allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate) at five temperature sets (313.2–393.2 K) and pressures (3.09 ≤ p ≤ 20.78 MPa). In S-CO2, the three systems exhibited a critical mixture curves and the maximum point in pressure–temperature (p-T) diagram was obtained between critical point of allyl acetoacetate/methyl acetoacetate/ethyl acetoacetate and that of CO2. These characteristics of the critical mixture plot fall under the category of type-I behavior. The experimental solubility curves and critical mixture curves of above three systems are correlated using Peng-Robinson equation of state with van der Waals mixing rules using two interaction parameters. The calculated root mean square relative deviation % (RMSD %) of the allyl acetoacetate + S-CO2, methyl acetoacetate + S-CO2, and ethyl acetoacetate + S-CO2 systems for five temperature sets ranges from (1.29% − 3.63%), (1.47% − 8.95%) and (2.17% − 3.87%), respectively.
650		4	\|a Allyl acetoacetate
650		4	\|a Methyl acetoacetate
650		4	\|a Ethyl acetoacetate
650		4	\|a High pressure CO2
650		4	\|a Phase behavior
700	1		\|a Ghoderao, Pradnya N.P. \|e verfasserin \|4 aut
700	1		\|a Soo Park, Min \|e verfasserin \|4 aut
700	1		\|a Byun, Hun-Soo \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Journal of molecular liquids \|d New York, NY [u.a.] : Elsevier, 1983 \|g 387 \|h Online-Ressource \|w (DE-627)302469664 \|w (DE-600)1491496-7 \|w (DE-576)259483915 \|x 1873-3166 \|7 nnns
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912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
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912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
912			\|a GBV_ILN_4700
936	b	k	\|a 35.21 \|j Lösungen \|j Flüssigkeiten \|x Physikalische Chemie \|q VZ
951			\|a AR
952			\|d 387

Indexfelder

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publishDate	2023
allfields	10.1016/j.molliq.2023.122651 doi (DE-627)ELV061519375 (ELSEVIER)S0167-7322(23)01455-1 DE-627 ger DE-627 rda eng 540 VZ 35.21 bkl Lee, Hyun-Seok verfasserin (orcid)0009-0008-2373-1953 aut Phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure CO 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The phase behavior study of allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate in supercritical CO2 (S-CO2) is important for several industrial processes. This study investigated the binary mixture solubility curves of the three systems (allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate) at five temperature sets (313.2–393.2 K) and pressures (3.09 ≤ p ≤ 20.78 MPa). In S-CO2, the three systems exhibited a critical mixture curves and the maximum point in pressure–temperature (p-T) diagram was obtained between critical point of allyl acetoacetate/methyl acetoacetate/ethyl acetoacetate and that of CO2. These characteristics of the critical mixture plot fall under the category of type-I behavior. The experimental solubility curves and critical mixture curves of above three systems are correlated using Peng-Robinson equation of state with van der Waals mixing rules using two interaction parameters. The calculated root mean square relative deviation % (RMSD %) of the allyl acetoacetate + S-CO2, methyl acetoacetate + S-CO2, and ethyl acetoacetate + S-CO2 systems for five temperature sets ranges from (1.29% − 3.63%), (1.47% − 8.95%) and (2.17% − 3.87%), respectively. Allyl acetoacetate Methyl acetoacetate Ethyl acetoacetate High pressure CO2 Phase behavior Ghoderao, Pradnya N.P. verfasserin aut Soo Park, Min verfasserin aut Byun, Hun-Soo verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 387 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:387 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.21 Lösungen Flüssigkeiten Physikalische Chemie VZ AR 387
spelling	10.1016/j.molliq.2023.122651 doi (DE-627)ELV061519375 (ELSEVIER)S0167-7322(23)01455-1 DE-627 ger DE-627 rda eng 540 VZ 35.21 bkl Lee, Hyun-Seok verfasserin (orcid)0009-0008-2373-1953 aut Phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure CO 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The phase behavior study of allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate in supercritical CO2 (S-CO2) is important for several industrial processes. This study investigated the binary mixture solubility curves of the three systems (allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate) at five temperature sets (313.2–393.2 K) and pressures (3.09 ≤ p ≤ 20.78 MPa). In S-CO2, the three systems exhibited a critical mixture curves and the maximum point in pressure–temperature (p-T) diagram was obtained between critical point of allyl acetoacetate/methyl acetoacetate/ethyl acetoacetate and that of CO2. These characteristics of the critical mixture plot fall under the category of type-I behavior. The experimental solubility curves and critical mixture curves of above three systems are correlated using Peng-Robinson equation of state with van der Waals mixing rules using two interaction parameters. The calculated root mean square relative deviation % (RMSD %) of the allyl acetoacetate + S-CO2, methyl acetoacetate + S-CO2, and ethyl acetoacetate + S-CO2 systems for five temperature sets ranges from (1.29% − 3.63%), (1.47% − 8.95%) and (2.17% − 3.87%), respectively. Allyl acetoacetate Methyl acetoacetate Ethyl acetoacetate High pressure CO2 Phase behavior Ghoderao, Pradnya N.P. verfasserin aut Soo Park, Min verfasserin aut Byun, Hun-Soo verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 387 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:387 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.21 Lösungen Flüssigkeiten Physikalische Chemie VZ AR 387
allfields_unstemmed	10.1016/j.molliq.2023.122651 doi (DE-627)ELV061519375 (ELSEVIER)S0167-7322(23)01455-1 DE-627 ger DE-627 rda eng 540 VZ 35.21 bkl Lee, Hyun-Seok verfasserin (orcid)0009-0008-2373-1953 aut Phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure CO 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The phase behavior study of allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate in supercritical CO2 (S-CO2) is important for several industrial processes. This study investigated the binary mixture solubility curves of the three systems (allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate) at five temperature sets (313.2–393.2 K) and pressures (3.09 ≤ p ≤ 20.78 MPa). In S-CO2, the three systems exhibited a critical mixture curves and the maximum point in pressure–temperature (p-T) diagram was obtained between critical point of allyl acetoacetate/methyl acetoacetate/ethyl acetoacetate and that of CO2. These characteristics of the critical mixture plot fall under the category of type-I behavior. The experimental solubility curves and critical mixture curves of above three systems are correlated using Peng-Robinson equation of state with van der Waals mixing rules using two interaction parameters. The calculated root mean square relative deviation % (RMSD %) of the allyl acetoacetate + S-CO2, methyl acetoacetate + S-CO2, and ethyl acetoacetate + S-CO2 systems for five temperature sets ranges from (1.29% − 3.63%), (1.47% − 8.95%) and (2.17% − 3.87%), respectively. Allyl acetoacetate Methyl acetoacetate Ethyl acetoacetate High pressure CO2 Phase behavior Ghoderao, Pradnya N.P. verfasserin aut Soo Park, Min verfasserin aut Byun, Hun-Soo verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 387 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:387 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.21 Lösungen Flüssigkeiten Physikalische Chemie VZ AR 387
allfieldsGer	10.1016/j.molliq.2023.122651 doi (DE-627)ELV061519375 (ELSEVIER)S0167-7322(23)01455-1 DE-627 ger DE-627 rda eng 540 VZ 35.21 bkl Lee, Hyun-Seok verfasserin (orcid)0009-0008-2373-1953 aut Phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure CO 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The phase behavior study of allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate in supercritical CO2 (S-CO2) is important for several industrial processes. This study investigated the binary mixture solubility curves of the three systems (allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate) at five temperature sets (313.2–393.2 K) and pressures (3.09 ≤ p ≤ 20.78 MPa). In S-CO2, the three systems exhibited a critical mixture curves and the maximum point in pressure–temperature (p-T) diagram was obtained between critical point of allyl acetoacetate/methyl acetoacetate/ethyl acetoacetate and that of CO2. These characteristics of the critical mixture plot fall under the category of type-I behavior. The experimental solubility curves and critical mixture curves of above three systems are correlated using Peng-Robinson equation of state with van der Waals mixing rules using two interaction parameters. The calculated root mean square relative deviation % (RMSD %) of the allyl acetoacetate + S-CO2, methyl acetoacetate + S-CO2, and ethyl acetoacetate + S-CO2 systems for five temperature sets ranges from (1.29% − 3.63%), (1.47% − 8.95%) and (2.17% − 3.87%), respectively. Allyl acetoacetate Methyl acetoacetate Ethyl acetoacetate High pressure CO2 Phase behavior Ghoderao, Pradnya N.P. verfasserin aut Soo Park, Min verfasserin aut Byun, Hun-Soo verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 387 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:387 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.21 Lösungen Flüssigkeiten Physikalische Chemie VZ AR 387
allfieldsSound	10.1016/j.molliq.2023.122651 doi (DE-627)ELV061519375 (ELSEVIER)S0167-7322(23)01455-1 DE-627 ger DE-627 rda eng 540 VZ 35.21 bkl Lee, Hyun-Seok verfasserin (orcid)0009-0008-2373-1953 aut Phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure CO 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The phase behavior study of allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate in supercritical CO2 (S-CO2) is important for several industrial processes. This study investigated the binary mixture solubility curves of the three systems (allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate) at five temperature sets (313.2–393.2 K) and pressures (3.09 ≤ p ≤ 20.78 MPa). In S-CO2, the three systems exhibited a critical mixture curves and the maximum point in pressure–temperature (p-T) diagram was obtained between critical point of allyl acetoacetate/methyl acetoacetate/ethyl acetoacetate and that of CO2. These characteristics of the critical mixture plot fall under the category of type-I behavior. The experimental solubility curves and critical mixture curves of above three systems are correlated using Peng-Robinson equation of state with van der Waals mixing rules using two interaction parameters. The calculated root mean square relative deviation % (RMSD %) of the allyl acetoacetate + S-CO2, methyl acetoacetate + S-CO2, and ethyl acetoacetate + S-CO2 systems for five temperature sets ranges from (1.29% − 3.63%), (1.47% − 8.95%) and (2.17% − 3.87%), respectively. Allyl acetoacetate Methyl acetoacetate Ethyl acetoacetate High pressure CO2 Phase behavior Ghoderao, Pradnya N.P. verfasserin aut Soo Park, Min verfasserin aut Byun, Hun-Soo verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 387 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:387 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.21 Lösungen Flüssigkeiten Physikalische Chemie VZ AR 387
language	English
source	Enthalten in Journal of molecular liquids 387 volume:387
sourceStr	Enthalten in Journal of molecular liquids 387 volume:387
format_phy_str_mv	Article
bklname	Lösungen Flüssigkeiten
institution	findex.gbv.de
topic_facet	Allyl acetoacetate Methyl acetoacetate Ethyl acetoacetate High pressure CO2 Phase behavior
dewey-raw	540
isfreeaccess_bool	false
container_title	Journal of molecular liquids
authorswithroles_txt_mv	Lee, Hyun-Seok @@aut@@ Ghoderao, Pradnya N.P. @@aut@@ Soo Park, Min @@aut@@ Byun, Hun-Soo @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	302469664
dewey-sort	3540
id	ELV061519375
language_de	englisch
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author	Lee, Hyun-Seok
spellingShingle	Lee, Hyun-Seok ddc 540 bkl 35.21 misc Allyl acetoacetate misc Methyl acetoacetate misc Ethyl acetoacetate misc High pressure CO2 misc Phase behavior Phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure CO
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topic_title	540 VZ 35.21 bkl Phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure CO Allyl acetoacetate Methyl acetoacetate Ethyl acetoacetate High pressure CO2 Phase behavior
topic	ddc 540 bkl 35.21 misc Allyl acetoacetate misc Methyl acetoacetate misc Ethyl acetoacetate misc High pressure CO2 misc Phase behavior
topic_unstemmed	ddc 540 bkl 35.21 misc Allyl acetoacetate misc Methyl acetoacetate misc Ethyl acetoacetate misc High pressure CO2 misc Phase behavior
topic_browse	ddc 540 bkl 35.21 misc Allyl acetoacetate misc Methyl acetoacetate misc Ethyl acetoacetate misc High pressure CO2 misc Phase behavior
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title	Phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure CO
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title_full	Phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure CO
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author_browse	Lee, Hyun-Seok Ghoderao, Pradnya N.P. Soo Park, Min Byun, Hun-Soo
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author-letter	Lee, Hyun-Seok
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title_sort	phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure co
title_auth	Phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure CO
abstract	The phase behavior study of allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate in supercritical CO2 (S-CO2) is important for several industrial processes. This study investigated the binary mixture solubility curves of the three systems (allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate) at five temperature sets (313.2–393.2 K) and pressures (3.09 ≤ p ≤ 20.78 MPa). In S-CO2, the three systems exhibited a critical mixture curves and the maximum point in pressure–temperature (p-T) diagram was obtained between critical point of allyl acetoacetate/methyl acetoacetate/ethyl acetoacetate and that of CO2. These characteristics of the critical mixture plot fall under the category of type-I behavior. The experimental solubility curves and critical mixture curves of above three systems are correlated using Peng-Robinson equation of state with van der Waals mixing rules using two interaction parameters. The calculated root mean square relative deviation % (RMSD %) of the allyl acetoacetate + S-CO2, methyl acetoacetate + S-CO2, and ethyl acetoacetate + S-CO2 systems for five temperature sets ranges from (1.29% − 3.63%), (1.47% − 8.95%) and (2.17% − 3.87%), respectively.
abstractGer	The phase behavior study of allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate in supercritical CO2 (S-CO2) is important for several industrial processes. This study investigated the binary mixture solubility curves of the three systems (allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate) at five temperature sets (313.2–393.2 K) and pressures (3.09 ≤ p ≤ 20.78 MPa). In S-CO2, the three systems exhibited a critical mixture curves and the maximum point in pressure–temperature (p-T) diagram was obtained between critical point of allyl acetoacetate/methyl acetoacetate/ethyl acetoacetate and that of CO2. These characteristics of the critical mixture plot fall under the category of type-I behavior. The experimental solubility curves and critical mixture curves of above three systems are correlated using Peng-Robinson equation of state with van der Waals mixing rules using two interaction parameters. The calculated root mean square relative deviation % (RMSD %) of the allyl acetoacetate + S-CO2, methyl acetoacetate + S-CO2, and ethyl acetoacetate + S-CO2 systems for five temperature sets ranges from (1.29% − 3.63%), (1.47% − 8.95%) and (2.17% − 3.87%), respectively.
abstract_unstemmed	The phase behavior study of allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate in supercritical CO2 (S-CO2) is important for several industrial processes. This study investigated the binary mixture solubility curves of the three systems (allyl acetoacetate, methyl acetoacetate, and ethyl acetoacetate) at five temperature sets (313.2–393.2 K) and pressures (3.09 ≤ p ≤ 20.78 MPa). In S-CO2, the three systems exhibited a critical mixture curves and the maximum point in pressure–temperature (p-T) diagram was obtained between critical point of allyl acetoacetate/methyl acetoacetate/ethyl acetoacetate and that of CO2. These characteristics of the critical mixture plot fall under the category of type-I behavior. The experimental solubility curves and critical mixture curves of above three systems are correlated using Peng-Robinson equation of state with van der Waals mixing rules using two interaction parameters. The calculated root mean square relative deviation % (RMSD %) of the allyl acetoacetate + S-CO2, methyl acetoacetate + S-CO2, and ethyl acetoacetate + S-CO2 systems for five temperature sets ranges from (1.29% − 3.63%), (1.47% − 8.95%) and (2.17% − 3.87%), respectively.
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title_short	Phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure CO
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author2	Ghoderao, Pradnya N.P. Soo Park, Min Byun, Hun-Soo
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up_date	2024-07-06T17:45:21.418Z
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Phase equilibria for the two-component systems of allyl acetoacetate, methyl acetoacetate and ethyl acetoacetate under high-pressure CO

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