Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties

An increase of global population and consequent cause of environmental concerns, significant efforts have been made to reducing the use of fossil-based precursors and chemicals. The sustainable bio-benzoxazine resins were prepared using thymolphthalein and different amines systems such as aliphatic...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Srinivasan, Harinei [verfasserIn] Arumugam, Hariharan [verfasserIn] Rimdusit, Sarawut [verfasserIn] Muthukaruppan, Alagar [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Thymolphthalein Polybenzoxazine Bio-silica Graphitic carbon nitride Thermal stability Hydrophobicity Oil-water separation Dielectric constant

Übergeordnetes Werk:	Enthalten in: Colloids and surfaces / A - Amsterdam [u.a.] : Elsevier Science, 1993, 675
Übergeordnetes Werk:	volume:675

DOI / URN:	10.1016/j.colsurfa.2023.131947

Katalog-ID:	ELV061820431

Internformat


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245	1	0	\|a Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties
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520			\|a An increase of global population and consequent cause of environmental concerns, significant efforts have been made to reducing the use of fossil-based precursors and chemicals. The sustainable bio-benzoxazine resins were prepared using thymolphthalein and different amines systems such as aliphatic amines [butylamine (ba), hexylamine (ha), 2-ethylhexylamine (eha), dodecylamine (dda), octadecylamine (oda)), aryl amines (aniline (a), 4-fluoroaniline (fa), 3-trifluoromethylaniline (tfma)], and miscellaneous amines [cyclohexyamine (cha), allylamine (aa) and furfurylamine (ffa)] with paraformaldehyde through Mannich condensation. The molecular structure of corresponding benzoxazines was analysed using FTIR and 1H NMR spectroscopic techniques. Superhydrophobic cotton cloth was prepared using aliphatic amine based benzoxazine coating. The reinforcements bio-silica from bamboo ash and graphitic carbon nitride (GCN) from melamine precursors were separately prepared and functionalized under appropriate experimental conditions, which are used as reinforcement for the development of polybenzoxazine composites. Thermal stability, morphology and hydrophobicity of cardanol functionalized-GCN and GPTMS functionalized bio-silica reinforced polybenzoxazine composites were studied using TGA, FESEM and goniometer respectively. The poly(THP-oda) coated cotton fabric possesses the value of highest water contact angle of 154°. Further the poly(THP-oda) coated cotton fabric was tested for its efficiency towards oil-water separation. The value of dielectric constant of 15 wt% of bamboo ash silica reinforced poly(THP-ffa) and 15 wt% of C-GCN reinforced poly(THP-tfma) are 1.9 and 7.9 respectively.
650		4	\|a Thymolphthalein
650		4	\|a Polybenzoxazine
650		4	\|a Bio-silica
650		4	\|a Graphitic carbon nitride
650		4	\|a Thermal stability
650		4	\|a Hydrophobicity
650		4	\|a Oil-water separation
650		4	\|a Dielectric constant
700	1		\|a Arumugam, Hariharan \|e verfasserin \|0 (orcid)0000-0002-8797-2659 \|4 aut
700	1		\|a Rimdusit, Sarawut \|e verfasserin \|4 aut
700	1		\|a Muthukaruppan, Alagar \|e verfasserin \|0 (orcid)0000-0002-1661-5726 \|4 aut
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publishDate	2023
allfields	10.1016/j.colsurfa.2023.131947 doi (DE-627)ELV061820431 (ELSEVIER)S0927-7757(23)01031-2 DE-627 ger DE-627 rda eng 540 VZ 35.18 bkl 33.68 bkl 52.78 bkl 58.20 bkl Srinivasan, Harinei verfasserin (orcid)0000-0002-6258-3606 aut Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An increase of global population and consequent cause of environmental concerns, significant efforts have been made to reducing the use of fossil-based precursors and chemicals. The sustainable bio-benzoxazine resins were prepared using thymolphthalein and different amines systems such as aliphatic amines [butylamine (ba), hexylamine (ha), 2-ethylhexylamine (eha), dodecylamine (dda), octadecylamine (oda)), aryl amines (aniline (a), 4-fluoroaniline (fa), 3-trifluoromethylaniline (tfma)], and miscellaneous amines [cyclohexyamine (cha), allylamine (aa) and furfurylamine (ffa)] with paraformaldehyde through Mannich condensation. The molecular structure of corresponding benzoxazines was analysed using FTIR and 1H NMR spectroscopic techniques. Superhydrophobic cotton cloth was prepared using aliphatic amine based benzoxazine coating. The reinforcements bio-silica from bamboo ash and graphitic carbon nitride (GCN) from melamine precursors were separately prepared and functionalized under appropriate experimental conditions, which are used as reinforcement for the development of polybenzoxazine composites. Thermal stability, morphology and hydrophobicity of cardanol functionalized-GCN and GPTMS functionalized bio-silica reinforced polybenzoxazine composites were studied using TGA, FESEM and goniometer respectively. The poly(THP-oda) coated cotton fabric possesses the value of highest water contact angle of 154°. Further the poly(THP-oda) coated cotton fabric was tested for its efficiency towards oil-water separation. The value of dielectric constant of 15 wt% of bamboo ash silica reinforced poly(THP-ffa) and 15 wt% of C-GCN reinforced poly(THP-tfma) are 1.9 and 7.9 respectively. Thymolphthalein Polybenzoxazine Bio-silica Graphitic carbon nitride Thermal stability Hydrophobicity Oil-water separation Dielectric constant Arumugam, Hariharan verfasserin (orcid)0000-0002-8797-2659 aut Rimdusit, Sarawut verfasserin aut Muthukaruppan, Alagar verfasserin (orcid)0000-0002-1661-5726 aut Enthalten in Colloids and surfaces / A Amsterdam [u.a.] : Elsevier Science, 1993 675 Online-Ressource (DE-627)306659956 (DE-600)1500517-3 (DE-576)098614843 1873-4359 nnns volume:675 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 Kolloidchemie Grenzflächenchemie VZ 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 52.78 Oberflächentechnik Wärmebehandlung VZ 58.20 Chemische Technologien: Allgemeines VZ AR 675
spelling	10.1016/j.colsurfa.2023.131947 doi (DE-627)ELV061820431 (ELSEVIER)S0927-7757(23)01031-2 DE-627 ger DE-627 rda eng 540 VZ 35.18 bkl 33.68 bkl 52.78 bkl 58.20 bkl Srinivasan, Harinei verfasserin (orcid)0000-0002-6258-3606 aut Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An increase of global population and consequent cause of environmental concerns, significant efforts have been made to reducing the use of fossil-based precursors and chemicals. The sustainable bio-benzoxazine resins were prepared using thymolphthalein and different amines systems such as aliphatic amines [butylamine (ba), hexylamine (ha), 2-ethylhexylamine (eha), dodecylamine (dda), octadecylamine (oda)), aryl amines (aniline (a), 4-fluoroaniline (fa), 3-trifluoromethylaniline (tfma)], and miscellaneous amines [cyclohexyamine (cha), allylamine (aa) and furfurylamine (ffa)] with paraformaldehyde through Mannich condensation. The molecular structure of corresponding benzoxazines was analysed using FTIR and 1H NMR spectroscopic techniques. Superhydrophobic cotton cloth was prepared using aliphatic amine based benzoxazine coating. The reinforcements bio-silica from bamboo ash and graphitic carbon nitride (GCN) from melamine precursors were separately prepared and functionalized under appropriate experimental conditions, which are used as reinforcement for the development of polybenzoxazine composites. Thermal stability, morphology and hydrophobicity of cardanol functionalized-GCN and GPTMS functionalized bio-silica reinforced polybenzoxazine composites were studied using TGA, FESEM and goniometer respectively. The poly(THP-oda) coated cotton fabric possesses the value of highest water contact angle of 154°. Further the poly(THP-oda) coated cotton fabric was tested for its efficiency towards oil-water separation. The value of dielectric constant of 15 wt% of bamboo ash silica reinforced poly(THP-ffa) and 15 wt% of C-GCN reinforced poly(THP-tfma) are 1.9 and 7.9 respectively. Thymolphthalein Polybenzoxazine Bio-silica Graphitic carbon nitride Thermal stability Hydrophobicity Oil-water separation Dielectric constant Arumugam, Hariharan verfasserin (orcid)0000-0002-8797-2659 aut Rimdusit, Sarawut verfasserin aut Muthukaruppan, Alagar verfasserin (orcid)0000-0002-1661-5726 aut Enthalten in Colloids and surfaces / A Amsterdam [u.a.] : Elsevier Science, 1993 675 Online-Ressource (DE-627)306659956 (DE-600)1500517-3 (DE-576)098614843 1873-4359 nnns volume:675 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 Kolloidchemie Grenzflächenchemie VZ 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 52.78 Oberflächentechnik Wärmebehandlung VZ 58.20 Chemische Technologien: Allgemeines VZ AR 675
allfields_unstemmed	10.1016/j.colsurfa.2023.131947 doi (DE-627)ELV061820431 (ELSEVIER)S0927-7757(23)01031-2 DE-627 ger DE-627 rda eng 540 VZ 35.18 bkl 33.68 bkl 52.78 bkl 58.20 bkl Srinivasan, Harinei verfasserin (orcid)0000-0002-6258-3606 aut Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An increase of global population and consequent cause of environmental concerns, significant efforts have been made to reducing the use of fossil-based precursors and chemicals. The sustainable bio-benzoxazine resins were prepared using thymolphthalein and different amines systems such as aliphatic amines [butylamine (ba), hexylamine (ha), 2-ethylhexylamine (eha), dodecylamine (dda), octadecylamine (oda)), aryl amines (aniline (a), 4-fluoroaniline (fa), 3-trifluoromethylaniline (tfma)], and miscellaneous amines [cyclohexyamine (cha), allylamine (aa) and furfurylamine (ffa)] with paraformaldehyde through Mannich condensation. The molecular structure of corresponding benzoxazines was analysed using FTIR and 1H NMR spectroscopic techniques. Superhydrophobic cotton cloth was prepared using aliphatic amine based benzoxazine coating. The reinforcements bio-silica from bamboo ash and graphitic carbon nitride (GCN) from melamine precursors were separately prepared and functionalized under appropriate experimental conditions, which are used as reinforcement for the development of polybenzoxazine composites. Thermal stability, morphology and hydrophobicity of cardanol functionalized-GCN and GPTMS functionalized bio-silica reinforced polybenzoxazine composites were studied using TGA, FESEM and goniometer respectively. The poly(THP-oda) coated cotton fabric possesses the value of highest water contact angle of 154°. Further the poly(THP-oda) coated cotton fabric was tested for its efficiency towards oil-water separation. The value of dielectric constant of 15 wt% of bamboo ash silica reinforced poly(THP-ffa) and 15 wt% of C-GCN reinforced poly(THP-tfma) are 1.9 and 7.9 respectively. Thymolphthalein Polybenzoxazine Bio-silica Graphitic carbon nitride Thermal stability Hydrophobicity Oil-water separation Dielectric constant Arumugam, Hariharan verfasserin (orcid)0000-0002-8797-2659 aut Rimdusit, Sarawut verfasserin aut Muthukaruppan, Alagar verfasserin (orcid)0000-0002-1661-5726 aut Enthalten in Colloids and surfaces / A Amsterdam [u.a.] : Elsevier Science, 1993 675 Online-Ressource (DE-627)306659956 (DE-600)1500517-3 (DE-576)098614843 1873-4359 nnns volume:675 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 Kolloidchemie Grenzflächenchemie VZ 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 52.78 Oberflächentechnik Wärmebehandlung VZ 58.20 Chemische Technologien: Allgemeines VZ AR 675
allfieldsGer	10.1016/j.colsurfa.2023.131947 doi (DE-627)ELV061820431 (ELSEVIER)S0927-7757(23)01031-2 DE-627 ger DE-627 rda eng 540 VZ 35.18 bkl 33.68 bkl 52.78 bkl 58.20 bkl Srinivasan, Harinei verfasserin (orcid)0000-0002-6258-3606 aut Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An increase of global population and consequent cause of environmental concerns, significant efforts have been made to reducing the use of fossil-based precursors and chemicals. The sustainable bio-benzoxazine resins were prepared using thymolphthalein and different amines systems such as aliphatic amines [butylamine (ba), hexylamine (ha), 2-ethylhexylamine (eha), dodecylamine (dda), octadecylamine (oda)), aryl amines (aniline (a), 4-fluoroaniline (fa), 3-trifluoromethylaniline (tfma)], and miscellaneous amines [cyclohexyamine (cha), allylamine (aa) and furfurylamine (ffa)] with paraformaldehyde through Mannich condensation. The molecular structure of corresponding benzoxazines was analysed using FTIR and 1H NMR spectroscopic techniques. Superhydrophobic cotton cloth was prepared using aliphatic amine based benzoxazine coating. The reinforcements bio-silica from bamboo ash and graphitic carbon nitride (GCN) from melamine precursors were separately prepared and functionalized under appropriate experimental conditions, which are used as reinforcement for the development of polybenzoxazine composites. Thermal stability, morphology and hydrophobicity of cardanol functionalized-GCN and GPTMS functionalized bio-silica reinforced polybenzoxazine composites were studied using TGA, FESEM and goniometer respectively. The poly(THP-oda) coated cotton fabric possesses the value of highest water contact angle of 154°. Further the poly(THP-oda) coated cotton fabric was tested for its efficiency towards oil-water separation. The value of dielectric constant of 15 wt% of bamboo ash silica reinforced poly(THP-ffa) and 15 wt% of C-GCN reinforced poly(THP-tfma) are 1.9 and 7.9 respectively. Thymolphthalein Polybenzoxazine Bio-silica Graphitic carbon nitride Thermal stability Hydrophobicity Oil-water separation Dielectric constant Arumugam, Hariharan verfasserin (orcid)0000-0002-8797-2659 aut Rimdusit, Sarawut verfasserin aut Muthukaruppan, Alagar verfasserin (orcid)0000-0002-1661-5726 aut Enthalten in Colloids and surfaces / A Amsterdam [u.a.] : Elsevier Science, 1993 675 Online-Ressource (DE-627)306659956 (DE-600)1500517-3 (DE-576)098614843 1873-4359 nnns volume:675 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 Kolloidchemie Grenzflächenchemie VZ 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 52.78 Oberflächentechnik Wärmebehandlung VZ 58.20 Chemische Technologien: Allgemeines VZ AR 675
allfieldsSound	10.1016/j.colsurfa.2023.131947 doi (DE-627)ELV061820431 (ELSEVIER)S0927-7757(23)01031-2 DE-627 ger DE-627 rda eng 540 VZ 35.18 bkl 33.68 bkl 52.78 bkl 58.20 bkl Srinivasan, Harinei verfasserin (orcid)0000-0002-6258-3606 aut Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An increase of global population and consequent cause of environmental concerns, significant efforts have been made to reducing the use of fossil-based precursors and chemicals. The sustainable bio-benzoxazine resins were prepared using thymolphthalein and different amines systems such as aliphatic amines [butylamine (ba), hexylamine (ha), 2-ethylhexylamine (eha), dodecylamine (dda), octadecylamine (oda)), aryl amines (aniline (a), 4-fluoroaniline (fa), 3-trifluoromethylaniline (tfma)], and miscellaneous amines [cyclohexyamine (cha), allylamine (aa) and furfurylamine (ffa)] with paraformaldehyde through Mannich condensation. The molecular structure of corresponding benzoxazines was analysed using FTIR and 1H NMR spectroscopic techniques. Superhydrophobic cotton cloth was prepared using aliphatic amine based benzoxazine coating. The reinforcements bio-silica from bamboo ash and graphitic carbon nitride (GCN) from melamine precursors were separately prepared and functionalized under appropriate experimental conditions, which are used as reinforcement for the development of polybenzoxazine composites. Thermal stability, morphology and hydrophobicity of cardanol functionalized-GCN and GPTMS functionalized bio-silica reinforced polybenzoxazine composites were studied using TGA, FESEM and goniometer respectively. The poly(THP-oda) coated cotton fabric possesses the value of highest water contact angle of 154°. Further the poly(THP-oda) coated cotton fabric was tested for its efficiency towards oil-water separation. The value of dielectric constant of 15 wt% of bamboo ash silica reinforced poly(THP-ffa) and 15 wt% of C-GCN reinforced poly(THP-tfma) are 1.9 and 7.9 respectively. Thymolphthalein Polybenzoxazine Bio-silica Graphitic carbon nitride Thermal stability Hydrophobicity Oil-water separation Dielectric constant Arumugam, Hariharan verfasserin (orcid)0000-0002-8797-2659 aut Rimdusit, Sarawut verfasserin aut Muthukaruppan, Alagar verfasserin (orcid)0000-0002-1661-5726 aut Enthalten in Colloids and surfaces / A Amsterdam [u.a.] : Elsevier Science, 1993 675 Online-Ressource (DE-627)306659956 (DE-600)1500517-3 (DE-576)098614843 1873-4359 nnns volume:675 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 Kolloidchemie Grenzflächenchemie VZ 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 52.78 Oberflächentechnik Wärmebehandlung VZ 58.20 Chemische Technologien: Allgemeines VZ AR 675
language	English
source	Enthalten in Colloids and surfaces / A 675 volume:675
sourceStr	Enthalten in Colloids and surfaces / A 675 volume:675
format_phy_str_mv	Article
bklname	Kolloidchemie Grenzflächenchemie Oberflächen Dünne Schichten Grenzflächen Oberflächentechnik Wärmebehandlung Chemische Technologien: Allgemeines
institution	findex.gbv.de
topic_facet	Thymolphthalein Polybenzoxazine Bio-silica Graphitic carbon nitride Thermal stability Hydrophobicity Oil-water separation Dielectric constant
dewey-raw	540
isfreeaccess_bool	false
container_title	Colloids and surfaces / A
authorswithroles_txt_mv	Srinivasan, Harinei @@aut@@ Arumugam, Hariharan @@aut@@ Rimdusit, Sarawut @@aut@@ Muthukaruppan, Alagar @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	306659956
dewey-sort	3540
id	ELV061820431
language_de	englisch
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author	Srinivasan, Harinei
spellingShingle	Srinivasan, Harinei ddc 540 bkl 35.18 bkl 33.68 bkl 52.78 bkl 58.20 misc Thymolphthalein misc Polybenzoxazine misc Bio-silica misc Graphitic carbon nitride misc Thermal stability misc Hydrophobicity misc Oil-water separation misc Dielectric constant Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties
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topic_title	540 VZ 35.18 bkl 33.68 bkl 52.78 bkl 58.20 bkl Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties Thymolphthalein Polybenzoxazine Bio-silica Graphitic carbon nitride Thermal stability Hydrophobicity Oil-water separation Dielectric constant
topic	ddc 540 bkl 35.18 bkl 33.68 bkl 52.78 bkl 58.20 misc Thymolphthalein misc Polybenzoxazine misc Bio-silica misc Graphitic carbon nitride misc Thermal stability misc Hydrophobicity misc Oil-water separation misc Dielectric constant
topic_unstemmed	ddc 540 bkl 35.18 bkl 33.68 bkl 52.78 bkl 58.20 misc Thymolphthalein misc Polybenzoxazine misc Bio-silica misc Graphitic carbon nitride misc Thermal stability misc Hydrophobicity misc Oil-water separation misc Dielectric constant
topic_browse	ddc 540 bkl 35.18 bkl 33.68 bkl 52.78 bkl 58.20 misc Thymolphthalein misc Polybenzoxazine misc Bio-silica misc Graphitic carbon nitride misc Thermal stability misc Hydrophobicity misc Oil-water separation misc Dielectric constant
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title	Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties
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title_full	Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties
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author_browse	Srinivasan, Harinei Arumugam, Hariharan Rimdusit, Sarawut Muthukaruppan, Alagar
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title_sort	bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: thermal, superhydrophobic and dielectric properties
title_auth	Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties
abstract	An increase of global population and consequent cause of environmental concerns, significant efforts have been made to reducing the use of fossil-based precursors and chemicals. The sustainable bio-benzoxazine resins were prepared using thymolphthalein and different amines systems such as aliphatic amines [butylamine (ba), hexylamine (ha), 2-ethylhexylamine (eha), dodecylamine (dda), octadecylamine (oda)), aryl amines (aniline (a), 4-fluoroaniline (fa), 3-trifluoromethylaniline (tfma)], and miscellaneous amines [cyclohexyamine (cha), allylamine (aa) and furfurylamine (ffa)] with paraformaldehyde through Mannich condensation. The molecular structure of corresponding benzoxazines was analysed using FTIR and 1H NMR spectroscopic techniques. Superhydrophobic cotton cloth was prepared using aliphatic amine based benzoxazine coating. The reinforcements bio-silica from bamboo ash and graphitic carbon nitride (GCN) from melamine precursors were separately prepared and functionalized under appropriate experimental conditions, which are used as reinforcement for the development of polybenzoxazine composites. Thermal stability, morphology and hydrophobicity of cardanol functionalized-GCN and GPTMS functionalized bio-silica reinforced polybenzoxazine composites were studied using TGA, FESEM and goniometer respectively. The poly(THP-oda) coated cotton fabric possesses the value of highest water contact angle of 154°. Further the poly(THP-oda) coated cotton fabric was tested for its efficiency towards oil-water separation. The value of dielectric constant of 15 wt% of bamboo ash silica reinforced poly(THP-ffa) and 15 wt% of C-GCN reinforced poly(THP-tfma) are 1.9 and 7.9 respectively.
abstractGer	An increase of global population and consequent cause of environmental concerns, significant efforts have been made to reducing the use of fossil-based precursors and chemicals. The sustainable bio-benzoxazine resins were prepared using thymolphthalein and different amines systems such as aliphatic amines [butylamine (ba), hexylamine (ha), 2-ethylhexylamine (eha), dodecylamine (dda), octadecylamine (oda)), aryl amines (aniline (a), 4-fluoroaniline (fa), 3-trifluoromethylaniline (tfma)], and miscellaneous amines [cyclohexyamine (cha), allylamine (aa) and furfurylamine (ffa)] with paraformaldehyde through Mannich condensation. The molecular structure of corresponding benzoxazines was analysed using FTIR and 1H NMR spectroscopic techniques. Superhydrophobic cotton cloth was prepared using aliphatic amine based benzoxazine coating. The reinforcements bio-silica from bamboo ash and graphitic carbon nitride (GCN) from melamine precursors were separately prepared and functionalized under appropriate experimental conditions, which are used as reinforcement for the development of polybenzoxazine composites. Thermal stability, morphology and hydrophobicity of cardanol functionalized-GCN and GPTMS functionalized bio-silica reinforced polybenzoxazine composites were studied using TGA, FESEM and goniometer respectively. The poly(THP-oda) coated cotton fabric possesses the value of highest water contact angle of 154°. Further the poly(THP-oda) coated cotton fabric was tested for its efficiency towards oil-water separation. The value of dielectric constant of 15 wt% of bamboo ash silica reinforced poly(THP-ffa) and 15 wt% of C-GCN reinforced poly(THP-tfma) are 1.9 and 7.9 respectively.
abstract_unstemmed	An increase of global population and consequent cause of environmental concerns, significant efforts have been made to reducing the use of fossil-based precursors and chemicals. The sustainable bio-benzoxazine resins were prepared using thymolphthalein and different amines systems such as aliphatic amines [butylamine (ba), hexylamine (ha), 2-ethylhexylamine (eha), dodecylamine (dda), octadecylamine (oda)), aryl amines (aniline (a), 4-fluoroaniline (fa), 3-trifluoromethylaniline (tfma)], and miscellaneous amines [cyclohexyamine (cha), allylamine (aa) and furfurylamine (ffa)] with paraformaldehyde through Mannich condensation. The molecular structure of corresponding benzoxazines was analysed using FTIR and 1H NMR spectroscopic techniques. Superhydrophobic cotton cloth was prepared using aliphatic amine based benzoxazine coating. The reinforcements bio-silica from bamboo ash and graphitic carbon nitride (GCN) from melamine precursors were separately prepared and functionalized under appropriate experimental conditions, which are used as reinforcement for the development of polybenzoxazine composites. Thermal stability, morphology and hydrophobicity of cardanol functionalized-GCN and GPTMS functionalized bio-silica reinforced polybenzoxazine composites were studied using TGA, FESEM and goniometer respectively. The poly(THP-oda) coated cotton fabric possesses the value of highest water contact angle of 154°. Further the poly(THP-oda) coated cotton fabric was tested for its efficiency towards oil-water separation. The value of dielectric constant of 15 wt% of bamboo ash silica reinforced poly(THP-ffa) and 15 wt% of C-GCN reinforced poly(THP-tfma) are 1.9 and 7.9 respectively.
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title_short	Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties
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author2	Arumugam, Hariharan Rimdusit, Sarawut Muthukaruppan, Alagar
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doi_str	10.1016/j.colsurfa.2023.131947
up_date	2024-07-06T18:05:28.188Z
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The sustainable bio-benzoxazine resins were prepared using thymolphthalein and different amines systems such as aliphatic amines [butylamine (ba), hexylamine (ha), 2-ethylhexylamine (eha), dodecylamine (dda), octadecylamine (oda)), aryl amines (aniline (a), 4-fluoroaniline (fa), 3-trifluoromethylaniline (tfma)], and miscellaneous amines [cyclohexyamine (cha), allylamine (aa) and furfurylamine (ffa)] with paraformaldehyde through Mannich condensation. The molecular structure of corresponding benzoxazines was analysed using FTIR and 1H NMR spectroscopic techniques. Superhydrophobic cotton cloth was prepared using aliphatic amine based benzoxazine coating. The reinforcements bio-silica from bamboo ash and graphitic carbon nitride (GCN) from melamine precursors were separately prepared and functionalized under appropriate experimental conditions, which are used as reinforcement for the development of polybenzoxazine composites. Thermal stability, morphology and hydrophobicity of cardanol functionalized-GCN and GPTMS functionalized bio-silica reinforced polybenzoxazine composites were studied using TGA, FESEM and goniometer respectively. The poly(THP-oda) coated cotton fabric possesses the value of highest water contact angle of 154°. Further the poly(THP-oda) coated cotton fabric was tested for its efficiency towards oil-water separation. 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Bio-thymol containing new high-performance thymolphthalein based polybenzoxazine: Thermal, superhydrophobic and dielectric properties

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