Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst

A low cost catalyst prepared by pyrolyzing electrode coating material from spent Li-ion battery cells was shown as an effective catalyst for the decarboxylative - dimerization of levulinic acid to a mixture of C6 and C9 fuel precursors. The highest levulinic acid conversion of 94% was observed with...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Amarasekara, Ananda S. [verfasserIn] Wang, Deping [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Levulinic acid Dimerization Metal oxide catalyst Li-ion battery Lithium nickel cobalt manganese oxide Decarboxylation

Übergeordnetes Werk:	Enthalten in: Fuel processing technology - New York, NY [u.a.] : Science Direct, 1977, 250
Übergeordnetes Werk:	volume:250

DOI / URN:	10.1016/j.fuproc.2023.107913

Katalog-ID:	ELV061913138

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245	1	0	\|a Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst
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520			\|a A low cost catalyst prepared by pyrolyzing electrode coating material from spent Li-ion battery cells was shown as an effective catalyst for the decarboxylative - dimerization of levulinic acid to a mixture of C6 and C9 fuel precursors. The highest levulinic acid conversion of 94% was observed with 10% (w/w) catalyst loading under 1.24 MPa H2 at 140 °C, 15 h. A reaction scheme was proposed to explain the novel transformation producing C9 lactone products and C6 unsaturated alcohol product through a decarboxylative pathway followed by the aldol dimerization of levulinic acid.
650		4	\|a Levulinic acid
650		4	\|a Dimerization
650		4	\|a Metal oxide catalyst
650		4	\|a Li-ion battery
650		4	\|a Lithium nickel cobalt manganese oxide
650		4	\|a Decarboxylation
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allfields	10.1016/j.fuproc.2023.107913 doi (DE-627)ELV061913138 (ELSEVIER)S0378-3820(23)00261-8 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Amarasekara, Ananda S. verfasserin aut Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A low cost catalyst prepared by pyrolyzing electrode coating material from spent Li-ion battery cells was shown as an effective catalyst for the decarboxylative - dimerization of levulinic acid to a mixture of C6 and C9 fuel precursors. The highest levulinic acid conversion of 94% was observed with 10% (w/w) catalyst loading under 1.24 MPa H2 at 140 °C, 15 h. A reaction scheme was proposed to explain the novel transformation producing C9 lactone products and C6 unsaturated alcohol product through a decarboxylative pathway followed by the aldol dimerization of levulinic acid. Levulinic acid Dimerization Metal oxide catalyst Li-ion battery Lithium nickel cobalt manganese oxide Decarboxylation Wang, Deping verfasserin aut Enthalten in Fuel processing technology New York, NY [u.a.] : Science Direct, 1977 250 Online-Ressource (DE-627)300898681 (DE-600)1483666-X (DE-576)09618860X nnns volume:250 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 250
spelling	10.1016/j.fuproc.2023.107913 doi (DE-627)ELV061913138 (ELSEVIER)S0378-3820(23)00261-8 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Amarasekara, Ananda S. verfasserin aut Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A low cost catalyst prepared by pyrolyzing electrode coating material from spent Li-ion battery cells was shown as an effective catalyst for the decarboxylative - dimerization of levulinic acid to a mixture of C6 and C9 fuel precursors. The highest levulinic acid conversion of 94% was observed with 10% (w/w) catalyst loading under 1.24 MPa H2 at 140 °C, 15 h. A reaction scheme was proposed to explain the novel transformation producing C9 lactone products and C6 unsaturated alcohol product through a decarboxylative pathway followed by the aldol dimerization of levulinic acid. Levulinic acid Dimerization Metal oxide catalyst Li-ion battery Lithium nickel cobalt manganese oxide Decarboxylation Wang, Deping verfasserin aut Enthalten in Fuel processing technology New York, NY [u.a.] : Science Direct, 1977 250 Online-Ressource (DE-627)300898681 (DE-600)1483666-X (DE-576)09618860X nnns volume:250 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 250
allfields_unstemmed	10.1016/j.fuproc.2023.107913 doi (DE-627)ELV061913138 (ELSEVIER)S0378-3820(23)00261-8 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Amarasekara, Ananda S. verfasserin aut Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A low cost catalyst prepared by pyrolyzing electrode coating material from spent Li-ion battery cells was shown as an effective catalyst for the decarboxylative - dimerization of levulinic acid to a mixture of C6 and C9 fuel precursors. The highest levulinic acid conversion of 94% was observed with 10% (w/w) catalyst loading under 1.24 MPa H2 at 140 °C, 15 h. A reaction scheme was proposed to explain the novel transformation producing C9 lactone products and C6 unsaturated alcohol product through a decarboxylative pathway followed by the aldol dimerization of levulinic acid. Levulinic acid Dimerization Metal oxide catalyst Li-ion battery Lithium nickel cobalt manganese oxide Decarboxylation Wang, Deping verfasserin aut Enthalten in Fuel processing technology New York, NY [u.a.] : Science Direct, 1977 250 Online-Ressource (DE-627)300898681 (DE-600)1483666-X (DE-576)09618860X nnns volume:250 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 250
allfieldsGer	10.1016/j.fuproc.2023.107913 doi (DE-627)ELV061913138 (ELSEVIER)S0378-3820(23)00261-8 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Amarasekara, Ananda S. verfasserin aut Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A low cost catalyst prepared by pyrolyzing electrode coating material from spent Li-ion battery cells was shown as an effective catalyst for the decarboxylative - dimerization of levulinic acid to a mixture of C6 and C9 fuel precursors. The highest levulinic acid conversion of 94% was observed with 10% (w/w) catalyst loading under 1.24 MPa H2 at 140 °C, 15 h. A reaction scheme was proposed to explain the novel transformation producing C9 lactone products and C6 unsaturated alcohol product through a decarboxylative pathway followed by the aldol dimerization of levulinic acid. Levulinic acid Dimerization Metal oxide catalyst Li-ion battery Lithium nickel cobalt manganese oxide Decarboxylation Wang, Deping verfasserin aut Enthalten in Fuel processing technology New York, NY [u.a.] : Science Direct, 1977 250 Online-Ressource (DE-627)300898681 (DE-600)1483666-X (DE-576)09618860X nnns volume:250 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 250
allfieldsSound	10.1016/j.fuproc.2023.107913 doi (DE-627)ELV061913138 (ELSEVIER)S0378-3820(23)00261-8 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Amarasekara, Ananda S. verfasserin aut Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A low cost catalyst prepared by pyrolyzing electrode coating material from spent Li-ion battery cells was shown as an effective catalyst for the decarboxylative - dimerization of levulinic acid to a mixture of C6 and C9 fuel precursors. The highest levulinic acid conversion of 94% was observed with 10% (w/w) catalyst loading under 1.24 MPa H2 at 140 °C, 15 h. A reaction scheme was proposed to explain the novel transformation producing C9 lactone products and C6 unsaturated alcohol product through a decarboxylative pathway followed by the aldol dimerization of levulinic acid. Levulinic acid Dimerization Metal oxide catalyst Li-ion battery Lithium nickel cobalt manganese oxide Decarboxylation Wang, Deping verfasserin aut Enthalten in Fuel processing technology New York, NY [u.a.] : Science Direct, 1977 250 Online-Ressource (DE-627)300898681 (DE-600)1483666-X (DE-576)09618860X nnns volume:250 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 250
language	English
source	Enthalten in Fuel processing technology 250 volume:250
sourceStr	Enthalten in Fuel processing technology 250 volume:250
format_phy_str_mv	Article
bklname	Brennstoffe Kraftstoffe Explosivstoffe
institution	findex.gbv.de
topic_facet	Levulinic acid Dimerization Metal oxide catalyst Li-ion battery Lithium nickel cobalt manganese oxide Decarboxylation
dewey-raw	660
isfreeaccess_bool	false
container_title	Fuel processing technology
authorswithroles_txt_mv	Amarasekara, Ananda S. @@aut@@ Wang, Deping @@aut@@
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author	Amarasekara, Ananda S.
spellingShingle	Amarasekara, Ananda S. ddc 660 bkl 58.21 misc Levulinic acid misc Dimerization misc Metal oxide catalyst misc Li-ion battery misc Lithium nickel cobalt manganese oxide misc Decarboxylation Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst
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topic_title	660 VZ 58.21 bkl Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst Levulinic acid Dimerization Metal oxide catalyst Li-ion battery Lithium nickel cobalt manganese oxide Decarboxylation
topic	ddc 660 bkl 58.21 misc Levulinic acid misc Dimerization misc Metal oxide catalyst misc Li-ion battery misc Lithium nickel cobalt manganese oxide misc Decarboxylation
topic_unstemmed	ddc 660 bkl 58.21 misc Levulinic acid misc Dimerization misc Metal oxide catalyst misc Li-ion battery misc Lithium nickel cobalt manganese oxide misc Decarboxylation
topic_browse	ddc 660 bkl 58.21 misc Levulinic acid misc Dimerization misc Metal oxide catalyst misc Li-ion battery misc Lithium nickel cobalt manganese oxide misc Decarboxylation
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title	Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst
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title_full	Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst
author_sort	Amarasekara, Ananda S.
journal	Fuel processing technology
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author_browse	Amarasekara, Ananda S. Wang, Deping
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title_sort	decarboxylative - dimerization of levulinic acid using spent li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst
title_auth	Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst
abstract	A low cost catalyst prepared by pyrolyzing electrode coating material from spent Li-ion battery cells was shown as an effective catalyst for the decarboxylative - dimerization of levulinic acid to a mixture of C6 and C9 fuel precursors. The highest levulinic acid conversion of 94% was observed with 10% (w/w) catalyst loading under 1.24 MPa H2 at 140 °C, 15 h. A reaction scheme was proposed to explain the novel transformation producing C9 lactone products and C6 unsaturated alcohol product through a decarboxylative pathway followed by the aldol dimerization of levulinic acid.
abstractGer	A low cost catalyst prepared by pyrolyzing electrode coating material from spent Li-ion battery cells was shown as an effective catalyst for the decarboxylative - dimerization of levulinic acid to a mixture of C6 and C9 fuel precursors. The highest levulinic acid conversion of 94% was observed with 10% (w/w) catalyst loading under 1.24 MPa H2 at 140 °C, 15 h. A reaction scheme was proposed to explain the novel transformation producing C9 lactone products and C6 unsaturated alcohol product through a decarboxylative pathway followed by the aldol dimerization of levulinic acid.
abstract_unstemmed	A low cost catalyst prepared by pyrolyzing electrode coating material from spent Li-ion battery cells was shown as an effective catalyst for the decarboxylative - dimerization of levulinic acid to a mixture of C6 and C9 fuel precursors. The highest levulinic acid conversion of 94% was observed with 10% (w/w) catalyst loading under 1.24 MPa H2 at 140 °C, 15 h. A reaction scheme was proposed to explain the novel transformation producing C9 lactone products and C6 unsaturated alcohol product through a decarboxylative pathway followed by the aldol dimerization of levulinic acid.
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title_short	Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst
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doi_str	10.1016/j.fuproc.2023.107913
up_date	2024-07-06T18:12:01.922Z
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Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst

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