Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive

Increasing fuel energy density constitutes a potential way to reduce engine exhaust carbon emission. Fenchone, a strained ring molecule, could be an interesting candidate. The present study investigates the oxidation of fenchone in a jet-stirred reactor at high pressure (10 atm) between 700 and 1180...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Boualem, L. [verfasserIn] Serinyel, Z. [verfasserIn] Nicolle, A. [verfasserIn] Lailliau, M. [verfasserIn] Dagaut, P. [verfasserIn] Dayma, G. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Fenchone Oxidation JSR Kinetic modeling

Übergeordnetes Werk:	Enthalten in: Fuel - New York, NY [u.a.] : Elsevier, 1970, 353
Übergeordnetes Werk:	volume:353

DOI / URN:	10.1016/j.fuel.2023.129183

Katalog-ID:	ELV063993295

Internformat


LEADER	01000caa a22002652 4500
001	ELV063993295
003	DE-627
005	20231017093014.0
007	cr uuu---uuuuu
008	230914s2023 xx \|\|\|\|\|o 00\| \|\|eng c
024	7		\|a 10.1016/j.fuel.2023.129183 \|2 doi
035			\|a (DE-627)ELV063993295
035			\|a (ELSEVIER)S0016-2361(23)01797-0
040			\|a DE-627 \|b ger \|c DE-627 \|e rda
041			\|a eng
082	0	4	\|a 660 \|q VZ
084			\|a 58.21 \|2 bkl
100	1		\|a Boualem, L. \|e verfasserin \|4 aut
245	1	0	\|a Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive
264		1	\|c 2023
336			\|a nicht spezifiziert \|b zzz \|2 rdacontent
337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
520			\|a Increasing fuel energy density constitutes a potential way to reduce engine exhaust carbon emission. Fenchone, a strained ring molecule, could be an interesting candidate. The present study investigates the oxidation of fenchone in a jet-stirred reactor at high pressure (10 atm) between 700 and 1180 K at constant fuel mole fraction and constant residence time of 0.1% and 0.7 s, respectively. Mole fraction profiles were obtained through sonic probe sampling, and analyzed by gas chromatography and Fourier transform infrared spectrometry. More than 30 species were identified and most of them were quantified. Also, a kinetic mechanism is developed in this study and tested against the present conditions showing good agreement. The present mechanism allows to illuminate the major reaction pathways involved in the decomposition routes of the fuel and its primary radicals as well as the formation pathways of the quantified intermediate species. During fenchone oxidation, the carbonyl group is mostly found in CO, CO2 and formaldehyde while heavier carbonyl species were identified at much lower quantities, indicating decarbonylation occurs early during the oxidation process. Aromatic compounds such as benzene and toluene are formed especially in rich conditions while some potential oxygenated pollutants like methacrolein and acetaldehyde were quantified as well.
650		4	\|a Fenchone
650		4	\|a Oxidation
650		4	\|a JSR
650		4	\|a Kinetic modeling
700	1		\|a Serinyel, Z. \|e verfasserin \|0 (orcid)0000-0003-4712-090X \|4 aut
700	1		\|a Nicolle, A. \|e verfasserin \|4 aut
700	1		\|a Lailliau, M. \|e verfasserin \|0 (orcid)0000-0002-7758-3756 \|4 aut
700	1		\|a Dagaut, P. \|e verfasserin \|0 (orcid)0000-0003-4825-3288 \|4 aut
700	1		\|a Dayma, G. \|e verfasserin \|0 (orcid)0000-0003-2761-657X \|4 aut
773	0	8	\|i Enthalten in \|t Fuel \|d New York, NY [u.a.] : Elsevier, 1970 \|g 353 \|h Online-Ressource \|w (DE-627)300898584 \|w (DE-600)1483656-7 \|w (DE-576)09555176X \|x 0016-2361 \|7 nnns
773	1	8	\|g volume:353
912			\|a GBV_USEFLAG_U
912			\|a GBV_ELV
912			\|a SYSFLAG_U
912			\|a SSG-OLC-PHA
912			\|a GBV_ILN_20
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2232
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2470
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
912			\|a GBV_ILN_4700
936	b	k	\|a 58.21 \|j Brennstoffe \|j Kraftstoffe \|j Explosivstoffe \|q VZ
951			\|a AR
952			\|d 353

Indexfelder

author_variant	l b lb z s zs a n an m l ml p d pd g d gd
matchkey_str	article:00162361:2023----::xeietlnmdlnsuyfhoiainfecoehgee
hierarchy_sort_str	2023
bklnumber	58.21
publishDate	2023
allfields	10.1016/j.fuel.2023.129183 doi (DE-627)ELV063993295 (ELSEVIER)S0016-2361(23)01797-0 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Boualem, L. verfasserin aut Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Increasing fuel energy density constitutes a potential way to reduce engine exhaust carbon emission. Fenchone, a strained ring molecule, could be an interesting candidate. The present study investigates the oxidation of fenchone in a jet-stirred reactor at high pressure (10 atm) between 700 and 1180 K at constant fuel mole fraction and constant residence time of 0.1% and 0.7 s, respectively. Mole fraction profiles were obtained through sonic probe sampling, and analyzed by gas chromatography and Fourier transform infrared spectrometry. More than 30 species were identified and most of them were quantified. Also, a kinetic mechanism is developed in this study and tested against the present conditions showing good agreement. The present mechanism allows to illuminate the major reaction pathways involved in the decomposition routes of the fuel and its primary radicals as well as the formation pathways of the quantified intermediate species. During fenchone oxidation, the carbonyl group is mostly found in CO, CO2 and formaldehyde while heavier carbonyl species were identified at much lower quantities, indicating decarbonylation occurs early during the oxidation process. Aromatic compounds such as benzene and toluene are formed especially in rich conditions while some potential oxygenated pollutants like methacrolein and acetaldehyde were quantified as well. Fenchone Oxidation JSR Kinetic modeling Serinyel, Z. verfasserin (orcid)0000-0003-4712-090X aut Nicolle, A. verfasserin aut Lailliau, M. verfasserin (orcid)0000-0002-7758-3756 aut Dagaut, P. verfasserin (orcid)0000-0003-4825-3288 aut Dayma, G. verfasserin (orcid)0000-0003-2761-657X aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 353 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:353 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 353
spelling	10.1016/j.fuel.2023.129183 doi (DE-627)ELV063993295 (ELSEVIER)S0016-2361(23)01797-0 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Boualem, L. verfasserin aut Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Increasing fuel energy density constitutes a potential way to reduce engine exhaust carbon emission. Fenchone, a strained ring molecule, could be an interesting candidate. The present study investigates the oxidation of fenchone in a jet-stirred reactor at high pressure (10 atm) between 700 and 1180 K at constant fuel mole fraction and constant residence time of 0.1% and 0.7 s, respectively. Mole fraction profiles were obtained through sonic probe sampling, and analyzed by gas chromatography and Fourier transform infrared spectrometry. More than 30 species were identified and most of them were quantified. Also, a kinetic mechanism is developed in this study and tested against the present conditions showing good agreement. The present mechanism allows to illuminate the major reaction pathways involved in the decomposition routes of the fuel and its primary radicals as well as the formation pathways of the quantified intermediate species. During fenchone oxidation, the carbonyl group is mostly found in CO, CO2 and formaldehyde while heavier carbonyl species were identified at much lower quantities, indicating decarbonylation occurs early during the oxidation process. Aromatic compounds such as benzene and toluene are formed especially in rich conditions while some potential oxygenated pollutants like methacrolein and acetaldehyde were quantified as well. Fenchone Oxidation JSR Kinetic modeling Serinyel, Z. verfasserin (orcid)0000-0003-4712-090X aut Nicolle, A. verfasserin aut Lailliau, M. verfasserin (orcid)0000-0002-7758-3756 aut Dagaut, P. verfasserin (orcid)0000-0003-4825-3288 aut Dayma, G. verfasserin (orcid)0000-0003-2761-657X aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 353 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:353 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 353
allfields_unstemmed	10.1016/j.fuel.2023.129183 doi (DE-627)ELV063993295 (ELSEVIER)S0016-2361(23)01797-0 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Boualem, L. verfasserin aut Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Increasing fuel energy density constitutes a potential way to reduce engine exhaust carbon emission. Fenchone, a strained ring molecule, could be an interesting candidate. The present study investigates the oxidation of fenchone in a jet-stirred reactor at high pressure (10 atm) between 700 and 1180 K at constant fuel mole fraction and constant residence time of 0.1% and 0.7 s, respectively. Mole fraction profiles were obtained through sonic probe sampling, and analyzed by gas chromatography and Fourier transform infrared spectrometry. More than 30 species were identified and most of them were quantified. Also, a kinetic mechanism is developed in this study and tested against the present conditions showing good agreement. The present mechanism allows to illuminate the major reaction pathways involved in the decomposition routes of the fuel and its primary radicals as well as the formation pathways of the quantified intermediate species. During fenchone oxidation, the carbonyl group is mostly found in CO, CO2 and formaldehyde while heavier carbonyl species were identified at much lower quantities, indicating decarbonylation occurs early during the oxidation process. Aromatic compounds such as benzene and toluene are formed especially in rich conditions while some potential oxygenated pollutants like methacrolein and acetaldehyde were quantified as well. Fenchone Oxidation JSR Kinetic modeling Serinyel, Z. verfasserin (orcid)0000-0003-4712-090X aut Nicolle, A. verfasserin aut Lailliau, M. verfasserin (orcid)0000-0002-7758-3756 aut Dagaut, P. verfasserin (orcid)0000-0003-4825-3288 aut Dayma, G. verfasserin (orcid)0000-0003-2761-657X aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 353 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:353 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 353
allfieldsGer	10.1016/j.fuel.2023.129183 doi (DE-627)ELV063993295 (ELSEVIER)S0016-2361(23)01797-0 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Boualem, L. verfasserin aut Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Increasing fuel energy density constitutes a potential way to reduce engine exhaust carbon emission. Fenchone, a strained ring molecule, could be an interesting candidate. The present study investigates the oxidation of fenchone in a jet-stirred reactor at high pressure (10 atm) between 700 and 1180 K at constant fuel mole fraction and constant residence time of 0.1% and 0.7 s, respectively. Mole fraction profiles were obtained through sonic probe sampling, and analyzed by gas chromatography and Fourier transform infrared spectrometry. More than 30 species were identified and most of them were quantified. Also, a kinetic mechanism is developed in this study and tested against the present conditions showing good agreement. The present mechanism allows to illuminate the major reaction pathways involved in the decomposition routes of the fuel and its primary radicals as well as the formation pathways of the quantified intermediate species. During fenchone oxidation, the carbonyl group is mostly found in CO, CO2 and formaldehyde while heavier carbonyl species were identified at much lower quantities, indicating decarbonylation occurs early during the oxidation process. Aromatic compounds such as benzene and toluene are formed especially in rich conditions while some potential oxygenated pollutants like methacrolein and acetaldehyde were quantified as well. Fenchone Oxidation JSR Kinetic modeling Serinyel, Z. verfasserin (orcid)0000-0003-4712-090X aut Nicolle, A. verfasserin aut Lailliau, M. verfasserin (orcid)0000-0002-7758-3756 aut Dagaut, P. verfasserin (orcid)0000-0003-4825-3288 aut Dayma, G. verfasserin (orcid)0000-0003-2761-657X aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 353 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:353 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 353
allfieldsSound	10.1016/j.fuel.2023.129183 doi (DE-627)ELV063993295 (ELSEVIER)S0016-2361(23)01797-0 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Boualem, L. verfasserin aut Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Increasing fuel energy density constitutes a potential way to reduce engine exhaust carbon emission. Fenchone, a strained ring molecule, could be an interesting candidate. The present study investigates the oxidation of fenchone in a jet-stirred reactor at high pressure (10 atm) between 700 and 1180 K at constant fuel mole fraction and constant residence time of 0.1% and 0.7 s, respectively. Mole fraction profiles were obtained through sonic probe sampling, and analyzed by gas chromatography and Fourier transform infrared spectrometry. More than 30 species were identified and most of them were quantified. Also, a kinetic mechanism is developed in this study and tested against the present conditions showing good agreement. The present mechanism allows to illuminate the major reaction pathways involved in the decomposition routes of the fuel and its primary radicals as well as the formation pathways of the quantified intermediate species. During fenchone oxidation, the carbonyl group is mostly found in CO, CO2 and formaldehyde while heavier carbonyl species were identified at much lower quantities, indicating decarbonylation occurs early during the oxidation process. Aromatic compounds such as benzene and toluene are formed especially in rich conditions while some potential oxygenated pollutants like methacrolein and acetaldehyde were quantified as well. Fenchone Oxidation JSR Kinetic modeling Serinyel, Z. verfasserin (orcid)0000-0003-4712-090X aut Nicolle, A. verfasserin aut Lailliau, M. verfasserin (orcid)0000-0002-7758-3756 aut Dagaut, P. verfasserin (orcid)0000-0003-4825-3288 aut Dayma, G. verfasserin (orcid)0000-0003-2761-657X aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 353 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:353 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 353
language	English
source	Enthalten in Fuel 353 volume:353
sourceStr	Enthalten in Fuel 353 volume:353
format_phy_str_mv	Article
bklname	Brennstoffe Kraftstoffe Explosivstoffe
institution	findex.gbv.de
topic_facet	Fenchone Oxidation JSR Kinetic modeling
dewey-raw	660
isfreeaccess_bool	false
container_title	Fuel
authorswithroles_txt_mv	Boualem, L. @@aut@@ Serinyel, Z. @@aut@@ Nicolle, A. @@aut@@ Lailliau, M. @@aut@@ Dagaut, P. @@aut@@ Dayma, G. @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	300898584
dewey-sort	3660
id	ELV063993295
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV063993295</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20231017093014.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230914s2023 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.fuel.2023.129183</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV063993295</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0016-2361(23)01797-0</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.21</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Boualem, L.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Increasing fuel energy density constitutes a potential way to reduce engine exhaust carbon emission. Fenchone, a strained ring molecule, could be an interesting candidate. The present study investigates the oxidation of fenchone in a jet-stirred reactor at high pressure (10 atm) between 700 and 1180 K at constant fuel mole fraction and constant residence time of 0.1% and 0.7 s, respectively. Mole fraction profiles were obtained through sonic probe sampling, and analyzed by gas chromatography and Fourier transform infrared spectrometry. More than 30 species were identified and most of them were quantified. Also, a kinetic mechanism is developed in this study and tested against the present conditions showing good agreement. The present mechanism allows to illuminate the major reaction pathways involved in the decomposition routes of the fuel and its primary radicals as well as the formation pathways of the quantified intermediate species. During fenchone oxidation, the carbonyl group is mostly found in CO, CO2 and formaldehyde while heavier carbonyl species were identified at much lower quantities, indicating decarbonylation occurs early during the oxidation process. Aromatic compounds such as benzene and toluene are formed especially in rich conditions while some potential oxygenated pollutants like methacrolein and acetaldehyde were quantified as well.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Fenchone</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oxidation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">JSR</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Kinetic modeling</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Serinyel, Z.</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0003-4712-090X</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Nicolle, A.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lailliau, M.</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0002-7758-3756</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Dagaut, P.</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0003-4825-3288</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Dayma, G.</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0003-2761-657X</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Fuel</subfield><subfield code="d">New York, NY [u.a.] : Elsevier, 1970</subfield><subfield code="g">353</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)300898584</subfield><subfield code="w">(DE-600)1483656-7</subfield><subfield code="w">(DE-576)09555176X</subfield><subfield code="x">0016-2361</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:353</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">58.21</subfield><subfield code="j">Brennstoffe</subfield><subfield code="j">Kraftstoffe</subfield><subfield code="j">Explosivstoffe</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">353</subfield></datafield></record></collection>
author	Boualem, L.
spellingShingle	Boualem, L. ddc 660 bkl 58.21 misc Fenchone misc Oxidation misc JSR misc Kinetic modeling Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive
authorStr	Boualem, L.
ppnlink_with_tag_str_mv	@@773@@(DE-627)300898584
format	electronic Article
dewey-ones	660 - Chemical engineering
delete_txt_mv	keep
author_role	aut aut aut aut aut aut
collection	elsevier
remote_str	true
illustrated	Not Illustrated
issn	0016-2361
topic_title	660 VZ 58.21 bkl Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive Fenchone Oxidation JSR Kinetic modeling
topic	ddc 660 bkl 58.21 misc Fenchone misc Oxidation misc JSR misc Kinetic modeling
topic_unstemmed	ddc 660 bkl 58.21 misc Fenchone misc Oxidation misc JSR misc Kinetic modeling
topic_browse	ddc 660 bkl 58.21 misc Fenchone misc Oxidation misc JSR misc Kinetic modeling
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	cr
hierarchy_parent_title	Fuel
hierarchy_parent_id	300898584
dewey-tens	660 - Chemical engineering
hierarchy_top_title	Fuel
isfreeaccess_txt	false
familylinks_str_mv	(DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X
title	Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive
ctrlnum	(DE-627)ELV063993295 (ELSEVIER)S0016-2361(23)01797-0
title_full	Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive
author_sort	Boualem, L.
journal	Fuel
journalStr	Fuel
lang_code	eng
isOA_bool	false
dewey-hundreds	600 - Technology
recordtype	marc
publishDateSort	2023
contenttype_str_mv	zzz
author_browse	Boualem, L. Serinyel, Z. Nicolle, A. Lailliau, M. Dagaut, P. Dayma, G.
container_volume	353
class	660 VZ 58.21 bkl
format_se	Elektronische Aufsätze
author-letter	Boualem, L.
doi_str_mv	10.1016/j.fuel.2023.129183
normlink	(ORCID)0000-0003-4712-090X (ORCID)0000-0002-7758-3756 (ORCID)0000-0003-4825-3288 (ORCID)0000-0003-2761-657X
normlink_prefix_str_mv	(orcid)0000-0003-4712-090X (orcid)0000-0002-7758-3756 (orcid)0000-0003-4825-3288 (orcid)0000-0003-2761-657X
dewey-full	660
author2-role	verfasserin
title_sort	experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive
title_auth	Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive
abstract	Increasing fuel energy density constitutes a potential way to reduce engine exhaust carbon emission. Fenchone, a strained ring molecule, could be an interesting candidate. The present study investigates the oxidation of fenchone in a jet-stirred reactor at high pressure (10 atm) between 700 and 1180 K at constant fuel mole fraction and constant residence time of 0.1% and 0.7 s, respectively. Mole fraction profiles were obtained through sonic probe sampling, and analyzed by gas chromatography and Fourier transform infrared spectrometry. More than 30 species were identified and most of them were quantified. Also, a kinetic mechanism is developed in this study and tested against the present conditions showing good agreement. The present mechanism allows to illuminate the major reaction pathways involved in the decomposition routes of the fuel and its primary radicals as well as the formation pathways of the quantified intermediate species. During fenchone oxidation, the carbonyl group is mostly found in CO, CO2 and formaldehyde while heavier carbonyl species were identified at much lower quantities, indicating decarbonylation occurs early during the oxidation process. Aromatic compounds such as benzene and toluene are formed especially in rich conditions while some potential oxygenated pollutants like methacrolein and acetaldehyde were quantified as well.
abstractGer	Increasing fuel energy density constitutes a potential way to reduce engine exhaust carbon emission. Fenchone, a strained ring molecule, could be an interesting candidate. The present study investigates the oxidation of fenchone in a jet-stirred reactor at high pressure (10 atm) between 700 and 1180 K at constant fuel mole fraction and constant residence time of 0.1% and 0.7 s, respectively. Mole fraction profiles were obtained through sonic probe sampling, and analyzed by gas chromatography and Fourier transform infrared spectrometry. More than 30 species were identified and most of them were quantified. Also, a kinetic mechanism is developed in this study and tested against the present conditions showing good agreement. The present mechanism allows to illuminate the major reaction pathways involved in the decomposition routes of the fuel and its primary radicals as well as the formation pathways of the quantified intermediate species. During fenchone oxidation, the carbonyl group is mostly found in CO, CO2 and formaldehyde while heavier carbonyl species were identified at much lower quantities, indicating decarbonylation occurs early during the oxidation process. Aromatic compounds such as benzene and toluene are formed especially in rich conditions while some potential oxygenated pollutants like methacrolein and acetaldehyde were quantified as well.
abstract_unstemmed	Increasing fuel energy density constitutes a potential way to reduce engine exhaust carbon emission. Fenchone, a strained ring molecule, could be an interesting candidate. The present study investigates the oxidation of fenchone in a jet-stirred reactor at high pressure (10 atm) between 700 and 1180 K at constant fuel mole fraction and constant residence time of 0.1% and 0.7 s, respectively. Mole fraction profiles were obtained through sonic probe sampling, and analyzed by gas chromatography and Fourier transform infrared spectrometry. More than 30 species were identified and most of them were quantified. Also, a kinetic mechanism is developed in this study and tested against the present conditions showing good agreement. The present mechanism allows to illuminate the major reaction pathways involved in the decomposition routes of the fuel and its primary radicals as well as the formation pathways of the quantified intermediate species. During fenchone oxidation, the carbonyl group is mostly found in CO, CO2 and formaldehyde while heavier carbonyl species were identified at much lower quantities, indicating decarbonylation occurs early during the oxidation process. Aromatic compounds such as benzene and toluene are formed especially in rich conditions while some potential oxygenated pollutants like methacrolein and acetaldehyde were quantified as well.
collection_details	GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700
title_short	Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive
remote_bool	true
author2	Serinyel, Z. Nicolle, A. Lailliau, M. Dagaut, P. Dayma, G.
author2Str	Serinyel, Z. Nicolle, A. Lailliau, M. Dagaut, P. Dayma, G.
ppnlink	300898584
mediatype_str_mv	c
isOA_txt	false
hochschulschrift_bool	false
doi_str	10.1016/j.fuel.2023.129183
up_date	2024-07-06T20:06:40.312Z
_version_	1803861518254604288
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV063993295</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20231017093014.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230914s2023 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.fuel.2023.129183</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV063993295</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0016-2361(23)01797-0</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.21</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Boualem, L.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Increasing fuel energy density constitutes a potential way to reduce engine exhaust carbon emission. Fenchone, a strained ring molecule, could be an interesting candidate. The present study investigates the oxidation of fenchone in a jet-stirred reactor at high pressure (10 atm) between 700 and 1180 K at constant fuel mole fraction and constant residence time of 0.1% and 0.7 s, respectively. Mole fraction profiles were obtained through sonic probe sampling, and analyzed by gas chromatography and Fourier transform infrared spectrometry. More than 30 species were identified and most of them were quantified. Also, a kinetic mechanism is developed in this study and tested against the present conditions showing good agreement. The present mechanism allows to illuminate the major reaction pathways involved in the decomposition routes of the fuel and its primary radicals as well as the formation pathways of the quantified intermediate species. During fenchone oxidation, the carbonyl group is mostly found in CO, CO2 and formaldehyde while heavier carbonyl species were identified at much lower quantities, indicating decarbonylation occurs early during the oxidation process. Aromatic compounds such as benzene and toluene are formed especially in rich conditions while some potential oxygenated pollutants like methacrolein and acetaldehyde were quantified as well.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Fenchone</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oxidation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">JSR</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Kinetic modeling</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Serinyel, Z.</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0003-4712-090X</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Nicolle, A.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lailliau, M.</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0002-7758-3756</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Dagaut, P.</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0003-4825-3288</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Dayma, G.</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0003-2761-657X</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Fuel</subfield><subfield code="d">New York, NY [u.a.] : Elsevier, 1970</subfield><subfield code="g">353</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)300898584</subfield><subfield code="w">(DE-600)1483656-7</subfield><subfield code="w">(DE-576)09555176X</subfield><subfield code="x">0016-2361</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:353</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">58.21</subfield><subfield code="j">Brennstoffe</subfield><subfield code="j">Kraftstoffe</subfield><subfield code="j">Explosivstoffe</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">353</subfield></datafield></record></collection>
score	7.399646

Nicht das Richtige dabei?

Schreiben Sie uns!

Experimental and modeling study of the oxidation of fenchone, a high-energy density fuel-additive

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?