Fabrication of flexible and aqueous hybrid supercapacitors with diffusion channels contained copper cobalt bi-Metal Organic Framework nanosheets and ionic conductivity optimized semi-solid electrolyte
Metal-Organic Frameworks (MOFs) have established as important energy storage materials owing to their tunable pore diameter, high specific surface area, low density, easily accessible metal active centers, tunable morphology, and high catalytic activity. Supercapacitor electrode materials should be...
Ausführliche Beschreibung
Autor*in: |
Balamurugan, R [verfasserIn] Bose, A Chandra [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2023 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Electrochimica acta - New York, NY [u.a.] : Elsevier, 1959, 467 |
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Übergeordnetes Werk: |
volume:467 |
DOI / URN: |
10.1016/j.electacta.2023.143078 |
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Katalog-ID: |
ELV064016056 |
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520 | |a Metal-Organic Frameworks (MOFs) have established as important energy storage materials owing to their tunable pore diameter, high specific surface area, low density, easily accessible metal active centers, tunable morphology, and high catalytic activity. Supercapacitor electrode materials should be specifically needed some properties like high specific surface area, electrochemically active, and high electrical as well as ionic conductivity. Copper has high electrical conductivity, and cobalt has high electrochemical activity. Using their advantages in this work, copper and cobalt are used as metal active centers for bi-Metal Organic Framework (bMOF). The morphology of bMOF is tuned by temperature-assisted solvothermal synthesis method, and a perfect nanosheet-like structure is obtained at 140 °C. It exhibited a high specific capacity of 1049.5 C g−1 at 1 A g−1. Aqueous and flexible hybrid supercapacitor devices are fabricated using bMOF and activated carbon. Aqueous hybrid supercapacitor device provides a maximum specific energy of 91.3 W h kg−1 and a maximum specific power of 14.14 kW kg−1. For a flexible hybrid supercapacitor device (FHSD), semi-solid electrolyte's ionic conductivity is optimized by injecting water with various weight ratios. FHSD exhibits a maximum specific energy of 82.3 W h kg−1 and a maximum specific power of 16.23 kW kg−1 in an optimized semi-solid electrolyte. It retains 82.9 % of its initial specific capacity after 12,000 charge-discharge cycles. The flexibility of FHSD is investigated by cyclic bending and stretching of it during charge-discharge. | ||
650 | 4 | |a bi-Metal Organic Framework | |
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650 | 4 | |a Intercalation pseudocapacitor | |
650 | 4 | |a Ionic diffusion channel | |
700 | 1 | |a Bose, A Chandra |e verfasserin |0 (orcid)0000-0001-7016-5941 |4 aut | |
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10.1016/j.electacta.2023.143078 doi (DE-627)ELV064016056 (ELSEVIER)S0013-4686(23)01250-1 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Balamurugan, R verfasserin (orcid)0000-0003-3538-3948 aut Fabrication of flexible and aqueous hybrid supercapacitors with diffusion channels contained copper cobalt bi-Metal Organic Framework nanosheets and ionic conductivity optimized semi-solid electrolyte 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Metal-Organic Frameworks (MOFs) have established as important energy storage materials owing to their tunable pore diameter, high specific surface area, low density, easily accessible metal active centers, tunable morphology, and high catalytic activity. Supercapacitor electrode materials should be specifically needed some properties like high specific surface area, electrochemically active, and high electrical as well as ionic conductivity. Copper has high electrical conductivity, and cobalt has high electrochemical activity. Using their advantages in this work, copper and cobalt are used as metal active centers for bi-Metal Organic Framework (bMOF). The morphology of bMOF is tuned by temperature-assisted solvothermal synthesis method, and a perfect nanosheet-like structure is obtained at 140 °C. It exhibited a high specific capacity of 1049.5 C g−1 at 1 A g−1. Aqueous and flexible hybrid supercapacitor devices are fabricated using bMOF and activated carbon. Aqueous hybrid supercapacitor device provides a maximum specific energy of 91.3 W h kg−1 and a maximum specific power of 14.14 kW kg−1. For a flexible hybrid supercapacitor device (FHSD), semi-solid electrolyte's ionic conductivity is optimized by injecting water with various weight ratios. FHSD exhibits a maximum specific energy of 82.3 W h kg−1 and a maximum specific power of 16.23 kW kg−1 in an optimized semi-solid electrolyte. It retains 82.9 % of its initial specific capacity after 12,000 charge-discharge cycles. The flexibility of FHSD is investigated by cyclic bending and stretching of it during charge-discharge. bi-Metal Organic Framework Nanosheet Semi-solid electrolyte Flexible hybrid supercapacitor device Intercalation pseudocapacitor Ionic diffusion channel Bose, A Chandra verfasserin (orcid)0000-0001-7016-5941 aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 467 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:467 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 467 |
spelling |
10.1016/j.electacta.2023.143078 doi (DE-627)ELV064016056 (ELSEVIER)S0013-4686(23)01250-1 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Balamurugan, R verfasserin (orcid)0000-0003-3538-3948 aut Fabrication of flexible and aqueous hybrid supercapacitors with diffusion channels contained copper cobalt bi-Metal Organic Framework nanosheets and ionic conductivity optimized semi-solid electrolyte 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Metal-Organic Frameworks (MOFs) have established as important energy storage materials owing to their tunable pore diameter, high specific surface area, low density, easily accessible metal active centers, tunable morphology, and high catalytic activity. Supercapacitor electrode materials should be specifically needed some properties like high specific surface area, electrochemically active, and high electrical as well as ionic conductivity. Copper has high electrical conductivity, and cobalt has high electrochemical activity. Using their advantages in this work, copper and cobalt are used as metal active centers for bi-Metal Organic Framework (bMOF). The morphology of bMOF is tuned by temperature-assisted solvothermal synthesis method, and a perfect nanosheet-like structure is obtained at 140 °C. It exhibited a high specific capacity of 1049.5 C g−1 at 1 A g−1. Aqueous and flexible hybrid supercapacitor devices are fabricated using bMOF and activated carbon. Aqueous hybrid supercapacitor device provides a maximum specific energy of 91.3 W h kg−1 and a maximum specific power of 14.14 kW kg−1. For a flexible hybrid supercapacitor device (FHSD), semi-solid electrolyte's ionic conductivity is optimized by injecting water with various weight ratios. FHSD exhibits a maximum specific energy of 82.3 W h kg−1 and a maximum specific power of 16.23 kW kg−1 in an optimized semi-solid electrolyte. It retains 82.9 % of its initial specific capacity after 12,000 charge-discharge cycles. The flexibility of FHSD is investigated by cyclic bending and stretching of it during charge-discharge. bi-Metal Organic Framework Nanosheet Semi-solid electrolyte Flexible hybrid supercapacitor device Intercalation pseudocapacitor Ionic diffusion channel Bose, A Chandra verfasserin (orcid)0000-0001-7016-5941 aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 467 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:467 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 467 |
allfields_unstemmed |
10.1016/j.electacta.2023.143078 doi (DE-627)ELV064016056 (ELSEVIER)S0013-4686(23)01250-1 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Balamurugan, R verfasserin (orcid)0000-0003-3538-3948 aut Fabrication of flexible and aqueous hybrid supercapacitors with diffusion channels contained copper cobalt bi-Metal Organic Framework nanosheets and ionic conductivity optimized semi-solid electrolyte 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Metal-Organic Frameworks (MOFs) have established as important energy storage materials owing to their tunable pore diameter, high specific surface area, low density, easily accessible metal active centers, tunable morphology, and high catalytic activity. Supercapacitor electrode materials should be specifically needed some properties like high specific surface area, electrochemically active, and high electrical as well as ionic conductivity. Copper has high electrical conductivity, and cobalt has high electrochemical activity. Using their advantages in this work, copper and cobalt are used as metal active centers for bi-Metal Organic Framework (bMOF). The morphology of bMOF is tuned by temperature-assisted solvothermal synthesis method, and a perfect nanosheet-like structure is obtained at 140 °C. It exhibited a high specific capacity of 1049.5 C g−1 at 1 A g−1. Aqueous and flexible hybrid supercapacitor devices are fabricated using bMOF and activated carbon. Aqueous hybrid supercapacitor device provides a maximum specific energy of 91.3 W h kg−1 and a maximum specific power of 14.14 kW kg−1. For a flexible hybrid supercapacitor device (FHSD), semi-solid electrolyte's ionic conductivity is optimized by injecting water with various weight ratios. FHSD exhibits a maximum specific energy of 82.3 W h kg−1 and a maximum specific power of 16.23 kW kg−1 in an optimized semi-solid electrolyte. It retains 82.9 % of its initial specific capacity after 12,000 charge-discharge cycles. The flexibility of FHSD is investigated by cyclic bending and stretching of it during charge-discharge. bi-Metal Organic Framework Nanosheet Semi-solid electrolyte Flexible hybrid supercapacitor device Intercalation pseudocapacitor Ionic diffusion channel Bose, A Chandra verfasserin (orcid)0000-0001-7016-5941 aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 467 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:467 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 467 |
allfieldsGer |
10.1016/j.electacta.2023.143078 doi (DE-627)ELV064016056 (ELSEVIER)S0013-4686(23)01250-1 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Balamurugan, R verfasserin (orcid)0000-0003-3538-3948 aut Fabrication of flexible and aqueous hybrid supercapacitors with diffusion channels contained copper cobalt bi-Metal Organic Framework nanosheets and ionic conductivity optimized semi-solid electrolyte 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Metal-Organic Frameworks (MOFs) have established as important energy storage materials owing to their tunable pore diameter, high specific surface area, low density, easily accessible metal active centers, tunable morphology, and high catalytic activity. Supercapacitor electrode materials should be specifically needed some properties like high specific surface area, electrochemically active, and high electrical as well as ionic conductivity. Copper has high electrical conductivity, and cobalt has high electrochemical activity. Using their advantages in this work, copper and cobalt are used as metal active centers for bi-Metal Organic Framework (bMOF). The morphology of bMOF is tuned by temperature-assisted solvothermal synthesis method, and a perfect nanosheet-like structure is obtained at 140 °C. It exhibited a high specific capacity of 1049.5 C g−1 at 1 A g−1. Aqueous and flexible hybrid supercapacitor devices are fabricated using bMOF and activated carbon. Aqueous hybrid supercapacitor device provides a maximum specific energy of 91.3 W h kg−1 and a maximum specific power of 14.14 kW kg−1. For a flexible hybrid supercapacitor device (FHSD), semi-solid electrolyte's ionic conductivity is optimized by injecting water with various weight ratios. FHSD exhibits a maximum specific energy of 82.3 W h kg−1 and a maximum specific power of 16.23 kW kg−1 in an optimized semi-solid electrolyte. It retains 82.9 % of its initial specific capacity after 12,000 charge-discharge cycles. The flexibility of FHSD is investigated by cyclic bending and stretching of it during charge-discharge. bi-Metal Organic Framework Nanosheet Semi-solid electrolyte Flexible hybrid supercapacitor device Intercalation pseudocapacitor Ionic diffusion channel Bose, A Chandra verfasserin (orcid)0000-0001-7016-5941 aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 467 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:467 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 467 |
allfieldsSound |
10.1016/j.electacta.2023.143078 doi (DE-627)ELV064016056 (ELSEVIER)S0013-4686(23)01250-1 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Balamurugan, R verfasserin (orcid)0000-0003-3538-3948 aut Fabrication of flexible and aqueous hybrid supercapacitors with diffusion channels contained copper cobalt bi-Metal Organic Framework nanosheets and ionic conductivity optimized semi-solid electrolyte 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Metal-Organic Frameworks (MOFs) have established as important energy storage materials owing to their tunable pore diameter, high specific surface area, low density, easily accessible metal active centers, tunable morphology, and high catalytic activity. Supercapacitor electrode materials should be specifically needed some properties like high specific surface area, electrochemically active, and high electrical as well as ionic conductivity. Copper has high electrical conductivity, and cobalt has high electrochemical activity. Using their advantages in this work, copper and cobalt are used as metal active centers for bi-Metal Organic Framework (bMOF). The morphology of bMOF is tuned by temperature-assisted solvothermal synthesis method, and a perfect nanosheet-like structure is obtained at 140 °C. It exhibited a high specific capacity of 1049.5 C g−1 at 1 A g−1. Aqueous and flexible hybrid supercapacitor devices are fabricated using bMOF and activated carbon. Aqueous hybrid supercapacitor device provides a maximum specific energy of 91.3 W h kg−1 and a maximum specific power of 14.14 kW kg−1. For a flexible hybrid supercapacitor device (FHSD), semi-solid electrolyte's ionic conductivity is optimized by injecting water with various weight ratios. FHSD exhibits a maximum specific energy of 82.3 W h kg−1 and a maximum specific power of 16.23 kW kg−1 in an optimized semi-solid electrolyte. It retains 82.9 % of its initial specific capacity after 12,000 charge-discharge cycles. The flexibility of FHSD is investigated by cyclic bending and stretching of it during charge-discharge. bi-Metal Organic Framework Nanosheet Semi-solid electrolyte Flexible hybrid supercapacitor device Intercalation pseudocapacitor Ionic diffusion channel Bose, A Chandra verfasserin (orcid)0000-0001-7016-5941 aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 467 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:467 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 467 |
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Balamurugan, R |
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Balamurugan, R ddc 540 bkl 35.00 misc bi-Metal Organic Framework misc Nanosheet misc Semi-solid electrolyte misc Flexible hybrid supercapacitor device misc Intercalation pseudocapacitor misc Ionic diffusion channel Fabrication of flexible and aqueous hybrid supercapacitors with diffusion channels contained copper cobalt bi-Metal Organic Framework nanosheets and ionic conductivity optimized semi-solid electrolyte |
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540 VZ 35.00 bkl Fabrication of flexible and aqueous hybrid supercapacitors with diffusion channels contained copper cobalt bi-Metal Organic Framework nanosheets and ionic conductivity optimized semi-solid electrolyte bi-Metal Organic Framework Nanosheet Semi-solid electrolyte Flexible hybrid supercapacitor device Intercalation pseudocapacitor Ionic diffusion channel |
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ddc 540 bkl 35.00 misc bi-Metal Organic Framework misc Nanosheet misc Semi-solid electrolyte misc Flexible hybrid supercapacitor device misc Intercalation pseudocapacitor misc Ionic diffusion channel |
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ddc 540 bkl 35.00 misc bi-Metal Organic Framework misc Nanosheet misc Semi-solid electrolyte misc Flexible hybrid supercapacitor device misc Intercalation pseudocapacitor misc Ionic diffusion channel |
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Fabrication of flexible and aqueous hybrid supercapacitors with diffusion channels contained copper cobalt bi-Metal Organic Framework nanosheets and ionic conductivity optimized semi-solid electrolyte |
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Fabrication of flexible and aqueous hybrid supercapacitors with diffusion channels contained copper cobalt bi-Metal Organic Framework nanosheets and ionic conductivity optimized semi-solid electrolyte |
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Balamurugan, R Bose, A Chandra |
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fabrication of flexible and aqueous hybrid supercapacitors with diffusion channels contained copper cobalt bi-metal organic framework nanosheets and ionic conductivity optimized semi-solid electrolyte |
title_auth |
Fabrication of flexible and aqueous hybrid supercapacitors with diffusion channels contained copper cobalt bi-Metal Organic Framework nanosheets and ionic conductivity optimized semi-solid electrolyte |
abstract |
Metal-Organic Frameworks (MOFs) have established as important energy storage materials owing to their tunable pore diameter, high specific surface area, low density, easily accessible metal active centers, tunable morphology, and high catalytic activity. Supercapacitor electrode materials should be specifically needed some properties like high specific surface area, electrochemically active, and high electrical as well as ionic conductivity. Copper has high electrical conductivity, and cobalt has high electrochemical activity. Using their advantages in this work, copper and cobalt are used as metal active centers for bi-Metal Organic Framework (bMOF). The morphology of bMOF is tuned by temperature-assisted solvothermal synthesis method, and a perfect nanosheet-like structure is obtained at 140 °C. It exhibited a high specific capacity of 1049.5 C g−1 at 1 A g−1. Aqueous and flexible hybrid supercapacitor devices are fabricated using bMOF and activated carbon. Aqueous hybrid supercapacitor device provides a maximum specific energy of 91.3 W h kg−1 and a maximum specific power of 14.14 kW kg−1. For a flexible hybrid supercapacitor device (FHSD), semi-solid electrolyte's ionic conductivity is optimized by injecting water with various weight ratios. FHSD exhibits a maximum specific energy of 82.3 W h kg−1 and a maximum specific power of 16.23 kW kg−1 in an optimized semi-solid electrolyte. It retains 82.9 % of its initial specific capacity after 12,000 charge-discharge cycles. The flexibility of FHSD is investigated by cyclic bending and stretching of it during charge-discharge. |
abstractGer |
Metal-Organic Frameworks (MOFs) have established as important energy storage materials owing to their tunable pore diameter, high specific surface area, low density, easily accessible metal active centers, tunable morphology, and high catalytic activity. Supercapacitor electrode materials should be specifically needed some properties like high specific surface area, electrochemically active, and high electrical as well as ionic conductivity. Copper has high electrical conductivity, and cobalt has high electrochemical activity. Using their advantages in this work, copper and cobalt are used as metal active centers for bi-Metal Organic Framework (bMOF). The morphology of bMOF is tuned by temperature-assisted solvothermal synthesis method, and a perfect nanosheet-like structure is obtained at 140 °C. It exhibited a high specific capacity of 1049.5 C g−1 at 1 A g−1. Aqueous and flexible hybrid supercapacitor devices are fabricated using bMOF and activated carbon. Aqueous hybrid supercapacitor device provides a maximum specific energy of 91.3 W h kg−1 and a maximum specific power of 14.14 kW kg−1. For a flexible hybrid supercapacitor device (FHSD), semi-solid electrolyte's ionic conductivity is optimized by injecting water with various weight ratios. FHSD exhibits a maximum specific energy of 82.3 W h kg−1 and a maximum specific power of 16.23 kW kg−1 in an optimized semi-solid electrolyte. It retains 82.9 % of its initial specific capacity after 12,000 charge-discharge cycles. The flexibility of FHSD is investigated by cyclic bending and stretching of it during charge-discharge. |
abstract_unstemmed |
Metal-Organic Frameworks (MOFs) have established as important energy storage materials owing to their tunable pore diameter, high specific surface area, low density, easily accessible metal active centers, tunable morphology, and high catalytic activity. Supercapacitor electrode materials should be specifically needed some properties like high specific surface area, electrochemically active, and high electrical as well as ionic conductivity. Copper has high electrical conductivity, and cobalt has high electrochemical activity. Using their advantages in this work, copper and cobalt are used as metal active centers for bi-Metal Organic Framework (bMOF). The morphology of bMOF is tuned by temperature-assisted solvothermal synthesis method, and a perfect nanosheet-like structure is obtained at 140 °C. It exhibited a high specific capacity of 1049.5 C g−1 at 1 A g−1. Aqueous and flexible hybrid supercapacitor devices are fabricated using bMOF and activated carbon. Aqueous hybrid supercapacitor device provides a maximum specific energy of 91.3 W h kg−1 and a maximum specific power of 14.14 kW kg−1. For a flexible hybrid supercapacitor device (FHSD), semi-solid electrolyte's ionic conductivity is optimized by injecting water with various weight ratios. FHSD exhibits a maximum specific energy of 82.3 W h kg−1 and a maximum specific power of 16.23 kW kg−1 in an optimized semi-solid electrolyte. It retains 82.9 % of its initial specific capacity after 12,000 charge-discharge cycles. The flexibility of FHSD is investigated by cyclic bending and stretching of it during charge-discharge. |
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title_short |
Fabrication of flexible and aqueous hybrid supercapacitors with diffusion channels contained copper cobalt bi-Metal Organic Framework nanosheets and ionic conductivity optimized semi-solid electrolyte |
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|
score |
7.400032 |